Calcium fluoride based multifunctional nanoparticles for multimodal imaging

• Marion Straßer,
• Joachim H. X. Schrauth,
• Sofia Dembski,
• Daniel Haddad,
• Bernd Ahrens,
• Stefan Schweizer,
• Bastian Christ,
• Alevtina Cubukova,
• Marco Metzger,
• Heike Walles,
• Peter M. Jakob and
• Gerhard Sextl

Beilstein J. Nanotechnol. 2017, 8, 1484–1493, doi:10.3762/bjnano.8.148

• the ions in the calcium fluoride lattice (proof of principle). For a later clinical usage certainly we have to exchange terbium for a NIR dye or something similar because of the high sensitivity of living tissues towards UV light. In Figure 3 the emission spectrum of CaF2:(Tb3+,Gd3+) NPs at an

Deposition of exchange-coupled dinickel complexes on gold substrates utilizing ambidentate mercapto-carboxylato ligands

• Martin Börner,
• Laura Blömer,
• Marcus Kischel,
• Peter Richter,
• Georgeta Salvan,
• Dietrich R. T. Zahn,
• Pablo F. Siles,
• Maria E. N. Fuentes,
• Carlos C. B. Bufon,
• Daniel Grimm,
• Oliver G. Schmidt,
• Daniel Breite,
• Bernd Abel and
• Berthold Kersting

Beilstein J. Nanotechnol. 2017, 8, 1375–1387, doi:10.3762/bjnano.8.139

• avoid damage or modification of the topographic characteristics. Special ultrasharp (4–10 nm tip radius) Olympus cantilevers were employed, allowing high sensitivity measurements. Data shown in the respective Figures correspond to a 1 × 1 μm2 area, although a mapping of the topographic characteristics

Study of the correlation between sensing performance and surface morphology of inkjet-printed aqueous graphene-based chemiresistors for NO₂ detection

• F. Villani,
• C. Schiattarella,
• T. Polichetti,
• R. Di Capua,
• F. Loffredo,
• B. Alfano,
• M. L. Miglietta,
• E. Massera,
• L. Verdoliva and
• G. Di Francia

Beilstein J. Nanotechnol. 2017, 8, 1023–1031, doi:10.3762/bjnano.8.103

• , Naples, Italy CNR-SPIN UOS Napoli, Via Cintia, I-80126, Naples, Italy 10.3762/bjnano.8.103 Abstract The extremely high sensitivity to the external environment and the high specific surface area, as well as the absence of bulk phenomena that could interfere with the response signal, make graphene highly

• electronics; Introduction In the recent years, the potential of graphene for sensing applications has been largely explored because of its outstanding properties [1]: extremely high sensitivity to the external environment, excellent surface-to-volume ratio, as well as the absence of bulk phenomena that

Synthesis of coaxial nanotubes of polyaniline and poly(hydroxyethyl methacrylate) by oxidative/initiated chemical vapor deposition

• Alper Balkan,
• Efe Armagan and
• Gozde Ozaydin Ince

Beilstein J. Nanotechnol. 2017, 8, 872–882, doi:10.3762/bjnano.8.89

• oxide (AAO) track-etch membranes. The ability to control the thickness with high sensitivity using these vapor phase techniques allowed to produce coaxial nanotubes. The response of these nanotubes to the changes in humidity could be tuned by introducing the hydrogel inner layer. Results and Discussion

Measuring adhesion on rough surfaces using atomic force microscopy with a liquid probe

• Juan V. Escobar,
• Cristina Garza and
• Rolando Castillo

Beilstein J. Nanotechnol. 2017, 8, 813–825, doi:10.3762/bjnano.8.84

• the work of adhesion. It is usually assumed that the process takes place in a regime of small strains, that the materials are homogeneous, isotropic, linearly elastic, and that the tips are perfectly smooth. On this last point, previous studies [6][7][8] have demonstrated the high sensitivity of

Selective detection of Mg²⁺ ions via enhanced fluorescence emission using Au–DNA nanocomposites

• Tanushree Basu,
• Khyati Rana,
• Niranjan Das and
• Bonamali Pal

Beilstein J. Nanotechnol. 2017, 8, 762–771, doi:10.3762/bjnano.8.79

• various DNA detection schemes. The high sensitivity of the plasmon spectra towards the particle size and the local dielectric environment also offers new methods for the detection of free DNA or other biomolecules [2], where the detection signal is exclusively based on the color changes during assay or

Thin SnO_x films for surface plasmon resonance enhanced ellipsometric gas sensing (SPREE)

• Daniel Fischer,
• Andreas Hertwig,
• Uwe Beck,
• Volkmar Lohse,
• Detlef Negendank,
• Martin Kormunda and
• Norbert Esser

Beilstein J. Nanotechnol. 2017, 8, 522–529, doi:10.3762/bjnano.8.56

• concepts have their respective properties. Electrochemical sensors are limited to several gas species [2]. The infrared (IR) sensor needs a certain optical path for the IR beam inside the gas volume but shows high sensitivity and selectivity [3]. Pellistors can only measure specific gases due to their

Modeling of the growth of GaAs–AlGaAs core–shell nanowires

• Qian Zhang,
• Peter W. Voorhees and
• Stephen H. Davis

Beilstein J. Nanotechnol. 2017, 8, 506–513, doi:10.3762/bjnano.8.54

• the attachment rate of Al atoms is smaller there. Keywords: core–shell nanowires; heterostructures; mechanisms; quantum dots; Findings Core–shell nanowires with heterostructures hold great promise in photonic and electronic applications because of their high sensitivity to electronic and magnetic

Advances in the fabrication of graphene transistors on flexible substrates

• Gabriele Fisichella,
• Stella Lo Verso,
• Silvestra Di Marco,
• Vincenzo Vinciguerra,
• Emanuela Schilirò,
• Salvatore Di Franco,
• Raffaella Lo Nigro,
• Fabrizio Roccaforte,
• Amaia Zurutuza,
• Alba Centeno,
• Sebastiano Ravesi and
• Filippo Giannazzo

Beilstein J. Nanotechnol. 2017, 8, 467–474, doi:10.3762/bjnano.8.50

• (Gr-FETs) can be used for flexible high frequency (RF) electronics or for high sensitivity chemical sensors. Miniaturized and flexible Gr-FET sensors would be highly advantageous for current sensors technology for in vivo and in situ applications. In this paper, we report a wafer-scale processing

Comparison of four functionalization methods of gold nanoparticles for enhancing the enzyme-linked immunosorbent assay (ELISA)

• Paula Ciaurriz,
• Fátima Fernández,
• Edurne Tellechea,
• Jose F. Moran and
• Aaron C. Asensio

Beilstein J. Nanotechnol. 2017, 8, 244–253, doi:10.3762/bjnano.8.27

• ratio at 200 ppb of IgG. Additionally, the concentration of 1 a.u. induced a higher unspecific signal. The best balance between high sensitivity and reduced utilization of AuNP probes, as well as low unspecific signal, was found at a concentration of 0.5 a.u. Moreover, this result is consistent with the

Microfluidic setup for on-line SERS monitoring using laser induced nanoparticle spots as SERS active substrate

• Oana-M. Buja,
• Ovidiu D. Gordan,
• Nicolae Leopold,
• Andreas Morschhauser,
• Jörg Nestler and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2017, 8, 237–243, doi:10.3762/bjnano.8.26

• (SERS) has been proven to be a suitable tool for rapid detection of pollutants [3][5][6][7][8], based on their specific molecular fingerprint spectra [9]. The high sensitivity of this spectroscopic technique originates from the pronounced enhancement of the inelastic scattering when the molecule is

Graphene–polymer coating for the realization of strain sensors

• Carmela Bonavolontà,
• Carla Aramo,
• Massimo Valentino,
• Giampiero Pepe,
• Sergio De Nicola,
• Gianfranco Carotenuto,
• Angela Longo,
• Mariano Palomba,
• Simone Boccardi and
• Carosena Meola

Beilstein J. Nanotechnol. 2017, 8, 21–27, doi:10.3762/bjnano.8.3

• . The high sensitivity in addition to high stability of the graphene/PMMA structure and the high thermal sensitivity in the infrared wavelength region are interesting aspects that enable us to propose this polymer/graphene supported coating as a new kind of stress sensor useful for applications in

Nanostructured SnO₂–ZnO composite gas sensors for selective detection of carbon monoxide

• Paul Chesler,
• Cristian Hornoiu,
• Susana Mihaiu,
• Cristina Vladut,
• Jose Maria Calderon Moreno,
• Mihai Anastasescu,
• Carmen Moldovan,
• Bogdan Firtat,
• Costin Brasoveanu,
• George Muscalu,
• Ion Stan and
• Mariuca Gartner

Beilstein J. Nanotechnol. 2016, 7, 2045–2056, doi:10.3762/bjnano.7.195

• , cross-response and recovery characteristics of the analyzed materials are reported. The high sensitivity (RS = 1.21) to low amounts of CO (5 ppm) was reported for the sensor containing a composite sensitive film with ZnO (98 wt %)–SnO2 (2 wt %). This sensor response to CO was five times higher as

• technologies, low power requirements, quick response times (seconds), high sensitivity to small concentrations of a specific gas, complete sensor recovery, lightweight, and long term stability. More recently, sensors were fabricated with reduced dimensions (miniaturization or microelectronic processing) [2][3

Layered composites of PEDOT/PSS/nanoparticles and PEDOT/PSS/phthalocyanines as electron mediators for sensors and biosensors

• Celia García-Hernández,
• Cristina García-Cabezón,
• Fernando Martín-Pedrosa,
• José Antonio De Saja and
• María Luz Rodríguez-Méndez

Beilstein J. Nanotechnol. 2016, 7, 1948–1959, doi:10.3762/bjnano.7.186

• character which is an intrinsic semiconductor) [9][16][17][18]. On the other hand, enzymatic electrochemical biosensors based on phenol oxidases are a good alternative to analyze phenols due to their high sensitivity and selectivity. Tyrosinase oxidizes monophenols and o-diphenols to the corresponding

• of 10−6 mol·L−1. Conclusion Owing to their unique electrochemical properties, layered composite PEDOT/PSS/EM and PEDOT/PSS/EM-Enz electrodes offer efficient electron transfer, low detection limit, high sensitivity and good reproducibility toward the oxidation of catechol and hydroquinone. Furthermore

Monolayer graphene/SiC Schottky barrier diodes with improved barrier height uniformity as a sensing platform for the detection of heavy metals

• Ivan Shtepliuk,
• Jens Eriksson,
• Volodymyr Khranovskyy,
• Tihomir Iakimov,
• Anita Lloyd Spetz and
• Rositsa Yakimova

Beilstein J. Nanotechnol. 2016, 7, 1800–1814, doi:10.3762/bjnano.7.173

• characteristics of the devices and their sensitivity. A simpler solution is to use Schottky diode sensors, which can be grown more easily, have no gate insulator and a high sensitivity in the reverse and forward diode regimes. During the last decade the thermal decomposition of silicon carbide (SiC) in argon

• the selectivity toward cadmium and mercury (Figure 10). It can be explained by the fact that the graphene has a greater binding affinity for lead atoms than for other heavy metal atoms. Because of the high sensitivity of the work function of graphene to adsorbates (in our case, heavy metal atoms), as

• selectively detect Pb atoms in the concentration range up to 67.2 wt % (2 Pb atoms per 16 carbon atoms) with a high sensitivity. Our findings expectedly offer a new reliable strategy to develop portable and real-time environmental sensors based on uniform self-organized graphene/SiC Schottky diodes. Sketch of

Nanostructured TiO₂-based gas sensors with enhanced sensitivity to reducing gases

• Wojciech Maziarz,
• Anna Kusior and
• Anita Trenczek-Zajac

Beilstein J. Nanotechnol. 2016, 7, 1718–1726, doi:10.3762/bjnano.7.164

• selectivity to CO(CH3)2 after sensitization by SnO2 nanoparticles. The sensor response time was of the order of several seconds. Their fast response, high sensitivity to selected gas species, improved selectivity and stability suggest that the SnO2-decorated flower-like 3D nanostructures are a promising

Nanoanalytics for materials science

• Thilo Glatzel and
• Tom Wirtz

Beilstein J. Nanotechnol. 2016, 7, 1674–1675, doi:10.3762/bjnano.7.159

• high-sensitivity chemical information at the nanoscale are of utmost importance for future developments [1]. One of the possible approaches is based on bimodal or even multimodal nanoanalysis, which was increasingly developed during the last decade. Other important aspects that have to be considered

Graphene-enhanced plasmonic nanohole arrays for environmental sensing in aqueous samples

• Christa Genslein,
• Peter Hausler,
• Eva-Maria Kirchner,
• Rudolf Bierl,
• Antje J. Baeumner and
• Thomas Hirsch

Beilstein J. Nanotechnol. 2016, 7, 1564–1573, doi:10.3762/bjnano.7.150

• environmental monitoring providing important features such as real time measurements, high sensitivity and label-free assay [8]. The detection of highly diluted concentrations and small molecules (<200 Da) remains challenging within SPR sensing [9]. For (bio)analytical applications the sensitivity needs to be

• of 5–60 nm [14][15]. An enhancement of local electromagnetic fields and intense absorption bands due to excitations of electrons at the nano-structures, results in a high sensitivity towards local changes of the refractive index [16]. A variety of nanostructured substrates, such as nanostructured

Dynamic of cold-atom tips in anharmonic potentials

• Tobias Menold,
• Peter Federsel,
• Carola Rogulj,
• Hendrik Hölscher,
• József Fortágh and
• Andreas Günther

Beilstein J. Nanotechnol. 2016, 7, 1543–1555, doi:10.3762/bjnano.7.148

• particle interactions and anharmonic motion have a significant impact on the tip dynamics. Conclusion: Our findings will be crucial for the realization of high-sensitivity force spectroscopy with cold-atom tips and could possibly allow for the development of advanced spectroscopic techniques such as Q

A composite structure based on reduced graphene oxide and metal oxide nanomaterials for chemical sensors

• Vardan Galstyan,
• Elisabetta Comini,
• Iskandar Kholmanov,
• Andrea Ponzoni,
• Veronica Sberveglieri,
• Nicola Poli,
• Guido Faglia and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2016, 7, 1421–1427, doi:10.3762/bjnano.7.133

• ][6]. During the last decades, different types of sensors were fabricated for environmental and health monitoring. Among the different detection systems, chemical sensors based on metal oxide nanomaterials are highly demanded because of their high sensitivity, small size, low cost and low power

Ammonia gas sensors based on In₂O₃/PANI hetero-nanofibers operating at room temperature

• Qingxin Nie,
• Zengyuan Pang,
• Hangyi Lu,
• Yibing Cai and
• Qufu Wei

Beilstein J. Nanotechnol. 2016, 7, 1312–1321, doi:10.3762/bjnano.7.122

• even death [5][6][7]. So, there is an urgent need to develop a kind of gas sensor with high sensitivity and selectivity to detect NH3 at room temperature. Metal oxide semiconductors can be applied as sensing materials for monitoring NH3. Ammonia sensors based on In2O3 [8], TiO2 [9], SnO2 [10], ZnO [11

An ellipsometric approach towards the description of inhomogeneous polymer-based Langmuir layers

• Falko O. Rottke,
• Burkhard Schulz,
• Klaus Richau,
• Karl Kratz and
• Andreas Lendlein

Beilstein J. Nanotechnol. 2016, 7, 1156–1165, doi:10.3762/bjnano.7.107

• , e.g., thickness at the nm scale. In the present work only Δ-maps were recorded because of their high sensitivity towards thickness variations, even at ultrathin film conditions [6]. The complications and theoretical problems of estimating extremely small dispersions of Ψ for ultrathin films is known

Experimental and simulation-based investigation of He, Ne and Ar irradiation of polymers for ion microscopy

• Lukasz Rzeznik,
• Yves Fleming,
• Tom Wirtz and
• Patrick Philipp

Beilstein J. Nanotechnol. 2016, 7, 1113–1128, doi:10.3762/bjnano.7.104

• . Keywords: Helium ion microscopy; irradiation; polymers; preferential sputtering; secondary ion mass spectrometry; simulations; Introduction Progress in materials and life sciences requires sample characterisation with high lateral resolution and high sensitivity. A technique which allows for both is

Voltammetric determination of polyphenolic content in pomegranate juice using a poly(gallic acid)/multiwalled carbon nanotube modified electrode

• Refat Abdel-Hamid and
• Emad F. Newair

Beilstein J. Nanotechnol. 2016, 7, 1104–1112, doi:10.3762/bjnano.7.103

• transfer on bare GCE or MWCNT/GCE. Thus the modification enhances the redox peak current and could be used with high sensitivity. Recently, the use of nanomaterials for electrode modification has grown exponentially, owing to their advantageous electrochemical properties. Carbon nanotubes are the main

NO gas sensing at room temperature using single titanium oxide nanodot sensors created by atomic force microscopy nanolithography

• Li-Yang Hong and
• Heh-Nan Lin

Beilstein J. Nanotechnol. 2016, 7, 1044–1051, doi:10.3762/bjnano.7.97

• attractive than conventional devices [9]. The advantages include high sensitivity, high stability, fast detection and recovery, low power consumption, relatively low cost, and small size [9][10]. These advantages enable semiconducting metal oxide sensors to be implemented on integrated circuits for portable