Relationship between corrosion and nanoscale friction on a metallic glass

• Haoran Ma and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2022, 13, 236–244, doi:10.3762/bjnano.13.18

• surface dissolution at the interface of the two layers. The findings contribute to the understanding of mechanical contacts with metallic glasses under corrosive conditions by exploring the interrelation of microscopic corrosion mechanisms and nanoscale friction. Keywords: atomic force microscopy (AFM

• inner layer, which involves two physicochemical processes. Metal cations are generated at the interface between the inner and outer layer by the dissolution of the inner layer oxides and the metal substrate and then diffuse away from the interface. In the case of immersion, the constant small adhesion

• explain the bilayer structure found after polarization [30][31][42]. Metal cations react with water, or anions present in the solution, and form hydrated oxides and hydroxides at the interface between the outer layer and solution. These hydrates diffuse into the bulk solution, or partially transform as

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• three-dimensional metal oxide semiconductor field-effect transistors (MOSFETs) [1]. Here, formation processes of ultrathin SiO2 at the interface are considered to be quite important in determining its dielectric properties. To study procedures to fabricate gate dielectrics, it will be necessary to

• the Si 2p and O 1s core levels in detail during thermal oxidation using high-resolution X-ray photoelectron spectroscopy with synchrotron radiation [7][8][9]. Using a state-of-the-art wet oxidation procedure, we also reduced the interface trap density (Dit) at the SiO2/Si interface on the Si(113

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• products was inhibited effectively. The charge movement at the BiOBr/SnO2 p–n interface was also revealed via theoretical and experimental findings. Electrons in SnO2 transfer into BiOBr over pre-formed charge migration channels and an internal electric field at the BiOBr/SnO2 interface, which directs

• min. This enhancement of the photocatalytic activity was interpreted as the synergistic effect between the high photo-oxidation ability of SnO2 triggered by the visible light response of g-C3N4. Also, the key role of the SnO2/g-C3N4 interface in inhibiting the production of NO2 facilitates the

• noticeable impact on the structure of the SnO2 component. Still, its presence strongly enhanced energy harvesting and charge separation in the resulting composite [36]. Regarding the self-doping SnO2, Pham et al. reported on the fabrication of a SnO2−x/g-C3N4 heterojunction, inducing an S-scheme interface

Nanoscale friction and wear of a polymer coated with graphene

• Robin Vacher and
• Astrid S. de Wijn

Beilstein J. Nanotechnol. 2022, 13, 63–73, doi:10.3762/bjnano.13.4

• layers of graphene oxide and polyethylenimine. The authors showed that a transfer film of graphene on the polymer leads to lower friction. While to our knowledge there have been no numerical studies of friction on graphene-coated polymers, the graphene–polymer interface has been studied. Rissanou et al

• . [27][28] show that graphene has a strong effect on the structure and dynamics of the polymer chains near the interface. In this work, we aim to develop our understanding of the frictional behavior of a polymer coated with graphene by using molecular dynamics simulations of a single sliding asperity at

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

Topographic signatures and manipulations of Fe atoms, CO molecules and NaCl islands on superconducting Pb(111)

• Carl Drechsel,
• Philipp D’Astolfo,
• Jung-Ching Liu,
• Thilo Glatzel,
• Rémy Pawlak and
• Ernst Meyer

Beilstein J. Nanotechnol. 2022, 13, 1–9, doi:10.3762/bjnano.13.1

• (MZM), which has attracted a tremendous interest due to its non-Abelian quantum exchange statistics proposed as a key ingredient for topological quantum computing [4][5][6]. Topological superconductivity can intrinsically arise in the bulk of certain materials [7] or can be engineered at the interface

Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopy

• Kerstin Neuhaus,
• Christina Schmidt,
• Liudmila Fischer,
• Wilhelm Albert Meulenberg,
• Ke Ran,
• Joachim Mayer and
• Stefan Baumann

Beilstein J. Nanotechnol. 2021, 12, 1380–1391, doi:10.3762/bjnano.12.102

• indicated by the arrow in the upper left side in Figure 1b. The HAADF image in Figure 2a shows a CSO-FC2O interface with the left CSO grain tilted along its [001] direction. A clean surface without any significant structural defects is observed. Corresponding to the square-defined region in Figure 1a

• , Figure 2b displays the EDX chemical mapping results with atomic resolution, indicating no chemical disorders except the slight enrichment of Sm at the edge of the CSO grain. Tilting FC2O along its [101] direction, Figure 2c shows another CSO-FC2O interface, where rock salt structures within several

• nanometers are located on the FC2O side as outlined by the dashed line. The enlarged interface structure in the lower-right inset shows a good agreement with the CoO and Fe3−xCoxO4 structural model, respectively. Electrical conductivity The sample composition with Sm instead of Gd used for this study shows a

Alteration of nanomechanical properties of pancreatic cancer cells through anticancer drug treatment revealed by atomic force microscopy

• Xiaoteng Liang,
• Shuai Liu,
• Xiuchao Wang,
• Dan Xia and
• Qiang Li

Beilstein J. Nanotechnol. 2021, 12, 1372–1379, doi:10.3762/bjnano.12.101

• Xiaoteng Liang Shuai Liu Xiuchao Wang Dan Xia Qiang Li School of Materials Science and Engineering, Hebei University of Technology and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Tianjin, 300130, China Key Laboratory of Colloid and Interface

Polarity in cuticular ridge development and insect attachment on leaf surfaces of Schismatoglottis calyptrata (Araceae)

• Venkata A. Surapaneni,
• Tobias Aust,
• Thomas Speck and
• Marc Thielen

Beilstein J. Nanotechnol. 2021, 12, 1326–1338, doi:10.3762/bjnano.12.98

• ][41][42]. Moreover, the amount of polysaccharide and cutin components present in the cuticle probably influences the stiffness and elastic behavior of the cuticle–cell wall interface [43] and certainly affects ridge formation. The thickened cuticle provides structural support to the growing epidermal

• underlying structure of the cuticle–cell wall interface. A better understanding of these processes might also provide insights for bioinspired growth or swelling-induced microstructures for technical applications [44]. The morphological changes in the cuticular structure of plant leaves during ontogeny have

A review on slip boundary conditions at the nanoscale: recent development and applications

• Ruifei Wang,
• Jin Chai,
• Bobo Luo,
• Xiong Liu,
• Jianting Zhang,
• Min Wu,
• Mingdan Wei and
• Zhuanyue Ma

Beilstein J. Nanotechnol. 2021, 12, 1237–1251, doi:10.3762/bjnano.12.91

• reservoirs; Introduction A basic postulate in the study and design of macroscopic fluidic systems based on the knowledge of fluid mechanics is that the no-slip boundary condition is valid at the solid–liquid interface [1]. In the last two centuries, this no-slip boundary condition has been successfully

• addition, as downsizing can result in an increased surface-to-volume ratio, the solid–liquid interfacial properties, such as wettability and surface roughness, become key factors in the determination of liquid properties near the interface of nanosized systems, and may dramatically affect the slip flow

• microscopic description. In 1823, Navier proposed the partial slip boundary condition, and the concept of slip length b was introduced to reflect the amount of liquid slip at a given surface. The slip length is the distance beyond the solid–liquid interface where the liquid velocity linearly extrapolates to

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• permission of AIP Publishing. This content is not subject to CC BY 4.0. Si/WO3 nanowires. (a–d) SEM images of Si/WO3 NWs, (e) HRTEM image of a WO3/SiNW interface, (f) XRD pattern of SiNWs and SiNWs/WO3. Dynamic responses of (g) the composite and (h) pure SiNWs to 0.5–5 ppm NO2 at room temperature

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• market as they suffer from energy losses due to total internal reflection at the emitter/air interface. Several methods have been proposed to tune the properties of LED. To that end, multiwall carbon nanotubes (MWNT) and single-wall carbon nanotubes (SWNT) have been applied to various layers in LED, such

• 44% compared to 90% of ITO. A higher transmittance is nonetheless possible by optimizing the interface between HTL and SWNT via a parylene layer, which tends to increase the transparency of SWNT. Table 2 lists the polymers and their acronyms mentioned in this study. The anode can be supplemented with

• from the device with AgNP increased by 30% compared to the device without AgNP. Choi et al. have used a scattering layer of AgNP in order to study the SPR effect, which increased the EQE by 24% in the flexible OLED [49]. Au and AgNP have also been embedded at the interface of the anode and the HTL in

A Au/CuNiCoS₄/p-Si photodiode: electrical and morphological characterization

• Adem Koçyiğit,
• Adem Sarılmaz,
• Teoman Öztürk,
• Faruk Ozel and
• Murat Yıldırım

Beilstein J. Nanotechnol. 2021, 12, 984–994, doi:10.3762/bjnano.12.74

• increasing light intensity can be attributed to the increasing of the current at the interface at forward biases [20]. The RR value as function of the illumination power density is displayed in the inset of Figure 4. The fabricated Au/CuNiCoS4/p-Si photodiode exhibited almost linear growth of the current

• values with increasing illumination power density due to enhancing number of charge carriers at the interface at reverse biases. A photocurrent value 1000 times higher than the dark current was obtained, owing to the existence of the interfacial CuNiCoS4 layer and the semiconductor p-Si [21][22]. The

• increase of the current at zero bias voltage from dark to 20 mW/cm2 light power illumination intensity can be attributed to the increasing number of carriers at the interface of the Au/CuNiCoS4/p-Si device due to illumination. The depletion region between the metal and semiconductor can cause a current in

Is the Ne operation of the helium ion microscope suitable for electron backscatter diffraction sample preparation?

• Annalena Wolff

Beilstein J. Nanotechnol. 2021, 12, 965–983, doi:10.3762/bjnano.12.73

Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• efficiently electronically decouple further organic layers from a metal surface. The decoupling strategy with organic layers relies on both an increased separation between the organic layer of interest and the metal as well as the different electronic gaps of the organic interface layer and following ones [29

• electronically decoupled single molecules and molecular assemblies on surfaces. Several decoupling strategies at the solid–vacuum and solid–liquid interface were explored to elucidate structural, electronic, vibronic, and chemical properties of decoupled molecular structures. Physical decoupling by molecular

• molecular design, the built-in functionality of the active part of the molecule can be preserved upon adsorption on a surface. An example of the preservation of catalytic properties is demonstrated for the redox behavior of manganese porphyrins at the solid–liquid interface. Redox reactions at the axial

Self-assembly of Eucalyptus gunnii wax tubules and pure ß-diketone on HOPG and glass

• Miriam Anna Huth,
• Axel Huth and
• Kerstin Koch

Beilstein J. Nanotechnol. 2021, 12, 939–949, doi:10.3762/bjnano.12.70

• interface, covers all aerial non-lignified parts of higher plants [1]. It is an extracellular membrane of epidermal cells, consisting of a matrix of the polymer cutin and a mixture of hydrophobic compounds, the cuticular waxes [2][3]. This interface is a multifunctional surface optimized by evolution to

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• toxic and considered biologically inert [44][57][58]. Numerous in vitro studies carried out using high-throughput techniques such as microscopic techniques, TEM, and ICP-MS revealed the fate of nanoparticles and their interaction at the interface between the metal surface and cell membrane. Electron

• cellulose biomass [77]. Although the applications of DESs mentioned above lie at the interface of material and biological science, the following section will only discuss application of DESs in nanomaterial synthesis. As mentioned earlier, the high solubility of metal salts in DESs makes them an ideal

Effects of temperature and repeat layer spacing on mechanical properties of graphene/polycrystalline copper nanolaminated composites under shear loading

• Chia-Wei Huang,
• Man-Ping Chang and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2021, 12, 863–877, doi:10.3762/bjnano.12.65

• series of studies on three-dimensional nanolaminated graphene–metal composites have been carried out. Several studies revealed that the graphene interface provides a barrier to impede the propagation of dislocations, and simultaneously enhances the mechanical properties of the composites [22][23][24][25

• ]. The competition between interface and matrix in deformation and failure of a nanolayered polycrystalline Cu–graphene material has been reported [26]. In 2018, Weng et al. reported the potential strengthening mechanism of graphene/copper composites under compression. The results show that the

• incorporation of single-layer graphene enhances the mechanical properties of the composites [27]. Shin et al. indicated that there are several factors that would affect the reinforcement of the composite material, including the geometric/spatial characteristics of the reinforcement and the interface [28]. In

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

• continuous sonication is applied in which a continuous flow of both the inner gas and the shell precursor material are simultaneously sonicated in a uniform tank [156]. Microfluidic systems have recently been used as a method for MB production based on an interface between a liquid flow and a gas flow. T

Recent progress in actuation technologies of micro/nanorobots

• Ke Xu and
• Bing Liu

Beilstein J. Nanotechnol. 2021, 12, 756–765, doi:10.3762/bjnano.12.59

• conductive materials into a micro/nanorobot and then adjusting the surface charge of the robot or the electrochemical reaction on the interface through electric fields can also yield actuation. Zhang et al. [29] proposed an interdigital microelectrode system. When an AC electric field is applied, metal

• robot in 2002. The terminal of this micro/nanorobot was equipped with a platinum-plated porous glass filter, which can generate a large amount of oxygen through decomposition of H2O2 on the platinum surface and generate an actuation force at the interface between H2O2 solution and air to push the robot

Recent progress in magnetic applications for micro- and nanorobots

• Ke Xu,
• Shuang Xu and
• Fanan Wei

Beilstein J. Nanotechnol. 2021, 12, 744–755, doi:10.3762/bjnano.12.58

• trigger drug release. The fabrication method of Chen’s team yielded not only easily adjustable length and diameter of the nanowires, but also excellent interface coupling between the piezoelectric and magnetostrictive phases. It enabled precise magnetic manipulation on patterned surfaces and 3D swimming

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

• YBCO. Moreover, significant lateral scatter of the helium ions in the LSCO thin film was observed, even for the lower doses, exacerbated by ion backscatter from the substrate interface. However, in the case of another high-temperature superconductor, MgB2, the creation of high-quality Josephson

Nanoporous and nonporous conjugated donor–acceptor polymer semiconductors for photocatalytic hydrogen production

• Zhao-Qi Sheng,
• Yu-Qin Xing,
• Yan Chen,
• Guang Zhang,
• Shi-Yong Liu and
• Long Chen

Beilstein J. Nanotechnol. 2021, 12, 607–623, doi:10.3762/bjnano.12.50

• also adsorb H+ in water to form the polymer/water interface. Tian et al. [70] prepared several BT-based polymer dots (Pdots) with functionalized polystyrene (PS-PEG-COOH) (Figure 5) to improve the wettability of polymers. In contrast to the pristine BT-based polymers (P49–P51) (Figure 5), the Pdots

• ][91]. Researchers have also attempted to use heterojunctions as photocatalysts for PHP. For example, Wang et al. combined a pyrene-based polymer (P75) (Figure 10) with g-C3N4 to form a heterojunction [92]. The interface between P75 and g-C3N4 restrained charge recombination and promoted proton

Impact of GaAs(100) surface preparation on EQE of AZO/Al₂O₃/p-GaAs photovoltaic structures

• Piotr Caban,
• Rafał Pietruszka,
• Jarosław Kaszewski,
• Monika Ożga,
• Bartłomiej S. Witkowski,
• Krzysztof Kopalko,
• Piotr Kuźmiuk,
• Katarzyna Gwóźdź,
• Ewa Płaczek-Popko,
• Krystyna Lawniczak-Jablonska and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 578–592, doi:10.3762/bjnano.12.48

• /interface needs to be properly prepared. In the experiments described here we examined eight different paths of GaAs surface treatment (cleaning, etching, passivation) which resulted in different external quantum efficiency (EQE) values of the tested photovoltaic (PV) cells. Atomic force microscopy (AFM

• ) and scanning electron microscopy (SEM) examinations were conducted to obtain structural details of the devices. X-ray photoelectron spectroscopy (XPS) with depth profiling was used to examine interface structure and changes in the elemental content and chemical bonds. The photoluminescence (PL

• negative impact on the performance of GaAs-based microelectronic and optoelectronic devices [10][11]. Therefore, in order to take advantage of the properties of gallium arsenide [12], its interface with a dielectric or other semiconductor partner must be carefully prepared. This can be obtained either by

Properties of graphene deposited on GaN nanowires: influence of nanowire roughness, self-induced nanogating and defects

• Jakub Kierdaszuk,
• Piotr Kaźmierczak,
• Justyna Grzonka,
• Aleksandra Krajewska,
• Aleksandra Przewłoka,
• Wawrzyniec Kaszub,
• Zbigniew R. Zytkiewicz,
• Marta Sobanska,
• Maria Kamińska,
• Andrzej Wysmołek and
• Aneta Drabińska

Beilstein J. Nanotechnol. 2021, 12, 566–577, doi:10.3762/bjnano.12.47

• a deep understanding of the phenomena occurring on such interface. One of the most common experimental techniques for studying properties of graphene is Raman spectroscopy [10]. Non-invasive measurements of inelastic light scattering give an insight into the phonon structure of graphene. The