Electrospinning preparation and electrical and biological properties of ferrocene/poly(vinylpyrrolidone) composite nanofibers

• Ji-Hong Chai and
• Qing-Sheng Wu

Beilstein J. Nanotechnol. 2013, 4, 189–197, doi:10.3762/bjnano.4.19

• scientists because of its unique molecular structure and fascinating electronic properties and its potential applications in catalysis in organic synthesis, as functional materials, photosensitizers, stabilizers and conditioners, and in biochemistry and pharmaceuticals [13]. Fc decorated or incorporated into

• . Nevertheless, electrical communication was achieved between the electrode and the redox-active Fc molecules encapsulated inside the PVP nanofibers. It indicated that the molecular structure of Fc was not destroyed during the electrospinning process. In contrast, no redox peaks were observed on bare electrodes

Nanostructure-directed chemical sensing: The IHSAB principle and the dynamics of acid/base-interface interaction

• James L. Gole and
• William Laminack

Beilstein J. Nanotechnol. 2013, 4, 20–31, doi:10.3762/bjnano.4.3

• nanostructure surfaces but that it modifies the molecular structure and interaction as the metal-oxide deposited surface has gained considerable basic character. Initial results suggest that the nitridation process does not simply increase the basic character of the nanostructure surfaces but that it modifies

• the molecular structure and interaction, consistent with the IHSAB principle. This means that the sensitivity of the weaker metal oxides is enhanced by nitridation. Further, this process can be applied to create several potential visible-light-absorbing photocatalysts similar to TiO2−xNx [9][10]. We

Diamond nanophotonics

• Katja Beha,
• Helmut Fedder,
• Marco Wolfer,
• Merle C. Becker,
• Petr Siyushev,
• Mohammad Jamali,
• Anton Batalov,
• Christopher Hinz,
• Jakob Hees,
• Lutz Kirste,
• Harald Obloh,
• Etienne Gheeraert,
• Boris Naydenov,
• Ingmar Jakobi,
• Florian Dolde,
• Sébastien Pezzagna,
• Daniel Twittchen,
• Matthew Markham,
• Daniel Dregely,
• Harald Giessen,
• Jan Meijer,
• Fedor Jelezko,
• Christoph E. Nebel,
• Rudolf Bratschitsch,
• Alfred Leitenstorfer and
• Jörg Wrachtrup

Beilstein J. Nanotechnol. 2012, 3, 895–908, doi:10.3762/bjnano.3.100

• corresponds to the resonant optical transition (ZPL). The broad band at longer wavelength corresponds to phonon-broadened emission. The inset shows the molecular structure of the NV center in diamond consisting of a substitutional nitrogen atom with an adjacent vacancy. Plasmonic resonator geometries, field I

Dimer/tetramer motifs determine amphiphilic hydrazine fibril structures on graphite

• Loji K. Thomas,
• Nadine Diek,
• Uwe Beginn and
• Michael Reichling

Beilstein J. Nanotechnol. 2012, 3, 658–666, doi:10.3762/bjnano.3.75

• Experimental section). As the alkyl chain length is known to influence column formation in the bulk, the length of alkyl chains for both molecules is kept identical such that the focus of the study is solely on the geometry/symmetry aspect [6]. In Figure 1, a wedge shape is shown superimposed on the molecular

• structure, where the amide moieties are at the tip of the wedge and the alkoxy chains at the tail. In general, the molecular geometry of the mesogens is decisive for the generation of columnar mesophases in the bulk, i.e., the mesogens should be wedge-shaped. The wedges can form a disc with their tips all

Distribution of functional groups in periodic mesoporous organosilica materials studied by small-angle neutron scattering with in situ adsorption of nitrogen

• Monir Sharifi,
• Dirk Wallacher and
• Michael Wark

Beilstein J. Nanotechnol. 2012, 3, 428–437, doi:10.3762/bjnano.3.49

• by the scattering length b indicating neutron–nucleus interaction. The scattering length density ρSLD is defined by the sum of the scattering lengths of all atoms that are involved in the molecular structure, divided by the molecular volume: NA is the Avogadro constant, M is the mass of the used

An NC-AFM and KPFM study of the adsorption of a triphenylene derivative on KBr(001)

• Antoine Hinaut,
• Adeline Pujol,
• Florian Chaumeton,
• David Martrou,
• André Gourdon and
• Sébastien Gauthier

Beilstein J. Nanotechnol. 2012, 3, 221–229, doi:10.3762/bjnano.3.25

• adsorption. The mechanisms at work during this transformation could be of the same nature as those discussed recently in the study of the restructuring of KBr(001) steps by truxene molecules [11]. Finally, we note that when the molecular structure crosses portions of steps that are not aligned in these

Molecular-resolution imaging of pentacene on KCl(001)

• Julia L. Neff,
• Jan Götzen,
• Enhui Li,
• Michael Marz and
• Regina Hoffmann-Vogel

Beilstein J. Nanotechnol. 2012, 3, 186–191, doi:10.3762/bjnano.3.20

• surfaces, molecular growth is usually governed by strong adsorbate–substrate interactions. However, for some applications in the field of thin-film electronic devices, insulating substrates are required in order to decouple the molecular structure from the substrate. On insulators the interaction of the

Electron-beam patterned self-assembled monolayers as templates for Cu electrodeposition and lift-off

• Zhe She,
• Andrea DiFalco,
• Georg Hähner and
• Manfred Buck

Beilstein J. Nanotechnol. 2012, 3, 101–113, doi:10.3762/bjnano.3.11

• exposure to electrons (positive-resist behaviour), in contrast to aromatic SAMs in which the molecular structure of the SAM is essentially preserved [40] apart from the cross-linking of the aromatic moieties. The rather ill-defined electron-induced degradation of aliphatic SAMs makes it very difficult to

Direct-write polymer nanolithography in ultra-high vacuum

• Woo-Kyung Lee,
• Minchul Yang,
• Arnaldo R. Laracuente,
• William P. King,
• Lloyd J. Whitman and
• Paul E. Sheehan

Beilstein J. Nanotechnol. 2012, 3, 52–56, doi:10.3762/bjnano.3.6

• impact on the observed molecular film thickness. Conclusion In conclusion, we have developed a method for direct, additive deposition of polymer in UHV using thermal dip-pen nanolithography. The molecular structure of the written PDDT monolayer nanostructure films depends on the chemistry of the silicon

When “small” terms matter: Coupled interference features in the transport properties of cross-conjugated molecules

• Gemma C. Solomon,
• Justin P. Bergfield,
• Charles A. Stafford and
• Mark A. Ratner

Beilstein J. Nanotechnol. 2011, 2, 862–871, doi:10.3762/bjnano.2.95

• nonzero, and obviously these through-space terms will change if the molecular structure is varied in such a way that modifies these distances. The transmission through the smallest system (1cc) was published previously [19] and agrees well with the Hückel model calculations [44]. When we consider 2cc

An MCBJ case study: The influence of π-conjugation on the single-molecule conductance at a solid/liquid interface

• Wenjing Hong,
• Hennie Valkenier,
• Gábor Mészáros,
• David Zsolt Manrique,
• Artem Mishchenko,
• Alexander Putz,
• Pavel Moreno García,
• Colin J. Lambert,
• Jan C. Hummelen and
• Thomas Wandlowski

Beilstein J. Nanotechnol. 2011, 2, 699–713, doi:10.3762/bjnano.2.76

• molecular conformation [13][16] and as well as of the anchoring group and of the contacting leads [17][18] was studied to develop correlations between charge-transport characteristics and molecular structure. Furthermore, π-conjugation plays an essential role in charge transport through single molecular

• a molecular junction, we calculated the junction formation probability from the plateau-length analysis and obtained the following values: 33% out of all traces for AC, 32% for AH and 14% for AQ. Clearly, the molecular structure of each of the three OPE-type species influences the bonding of the

Self-organizing bioinspired oligothiophene–oligopeptide hybrids

• Alexey K. Shaytan,
• Eva-Kathrin Schillinger,
• Elena Mena-Osteritz,
• Sylvia Schmid,
• Pavel G. Khalatur,
• Peter Bäuerle and
• Alexei R. Khokhlov

Beilstein J. Nanotechnol. 2011, 2, 525–544, doi:10.3762/bjnano.2.57

• theoretical considerations of the experimentally observed nanofibers, the molecular structure of the molecule was constructed. Our theoretical research methodology consists of four main steps schematically depicted in Figure 11. First, the available experimental data, including available X-ray structural data

Towards a scalable and accurate quantum approach for describing vibrations of molecule–metal interfaces

• David M. Benoit,
• Bruno Madebene,
• Inga Ulusoy,
• Luis Mancera,
• Yohann Scribano and
• Sergey Chulkov

Beilstein J. Nanotechnol. 2011, 2, 427–447, doi:10.3762/bjnano.2.48

• ; vibrational theory; Introduction The study of molecular vibrations has been a topic of continued interest in chemistry for over a century, starting with the work of William Coblenz in 1905. The main driving force behind these studies has been the correlation that exists between molecular structure and

Characterization of protein adsorption onto FePt nanoparticles using dual-focus fluorescence correlation spectroscopy

• Pauline Maffre,
• Karin Nienhaus,
• Faheem Amin,
• Wolfgang J. Parak and
• G. Ulrich Nienhaus

Beilstein J. Nanotechnol. 2011, 2, 374–383, doi:10.3762/bjnano.2.43

• three proteins gave rise to a well-defined increase in NP size upon binding. The thickness of the protein corona can be related to a particular orientation of the protein, based on the knowledge of its molecular structure. For apolipoproteins, this result is rather intriguing because they are very

• charge on the protein that preferentially interact with the negatively charged NP surface. In this subsection, we discuss the thickness of the corona in relation to the molecular shapes and electrostatic properties of the adsorbed proteins. Figure 3a (left) shows a cartoon representation of the molecular

• structure of HSA, a protein with a molecular mass of 67 kDa [18]. It can be approximated by an equilateral triangular prism, with sides of ~8 nm and a height of ~3 nm (Figure 3a, middle). The ~3 nm radius increase upon adsorption of HSA, observed with 2fFCS (Figure 2a), completely agrees with our previous

Superhydrophobicity in perfection: the outstanding properties of the lotus leaf

• Hans J. Ensikat,
• Petra Ditsche-Kuru,
• Christoph Neinhuis and
• Wilhelm Barthlott

Beilstein J. Nanotechnol. 2011, 2, 152–161, doi:10.3762/bjnano.2.19

• contact with water [20] and to prove the theories such as those of Wenzel or Cassie and Baxter. For precise modelling of the behaviour of natural water repellent surfaces, an exact knowledge of the chemical composition and molecular structure are essential. Resistance against environmental stress The