Beilstein J. Nanotechnol.2010,1, 55–59, doi:10.3762/bjnano.1.7
NPs [19] and spherical shape is the energetically favourable configuration. Evidence of NPs melting has been also reported for irradiated Au NPs [15][30].
Bulk CoPt alloy has a phasetransition at 825 °C between the L10 ordered structure at low temperature and the disordered FCC structure at high
temperature. As previously reported [9], this phasetransition temperature decreases with particle size; however, such a size effect only occurs in sub-3 nm CoPt NPs. It can then be considered that the phasetransition temperature for NPs larger than 10 nm is similar to the bulk phasetransition temperature
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Figure 1:
Schematic representation of the experimental setup: the sample is placed behind the back focal plan...