Current state of laser synthesis of metal and alloy nanoparticles as ligand-free reference materials for nano-toxicological assays

• Christoph Rehbock,
• Jurij Jakobi,
• Lisa Gamrad,
• Selina van der Meer,
• Daniela Tiedemann,
• Ulrike Taylor,
• Wilfried Kues,
• Detlef Rath and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2014, 5, 1523–1541, doi:10.3762/bjnano.5.165

• stemming from implant wear [6][7][8], it is a severe problem when a systematic study of nanoparticle toxicity needs to be carried out. Hence, the size of the nanoparticles needs to be precisely controlled over a wide range, while all artificial organic additives, potentially interfering with toxicity

• surfactants or ligands. Above, the presence of any organic stabilizers has been completely excluded during the size control strategies. However, organic ligands are present in all biological systems anyway so the application of additives strictly limited to this environment might be an elegant route for size

• particle concentrations. An electrostatically-controlled approach for ligand-free size control of gold nanoparticle is the in situ addition of simple inorganic electrolytes like NaCl or sodium phosphate buffer. These additives are frequently found in most biological fluids and hence are not prone to

Liquid fuel cells

• Grigorii L. Soloveichik

Beilstein J. Nanotechnol. 2014, 5, 1399–1418, doi:10.3762/bjnano.5.153

• the other side, the presence of allyl hydrogen atoms in additives reduced the overpotential. A cell with a porous Pt/PTFE anode and cathode catalysts running on decane showed a maximum power density of 21 mW/cm2 (O2 cathode) and 17 mW/cm2 (air cathode) [43]. The addition of iso-alkanes to the fuel

Self-organization of mesoscopic silver wires by electrochemical deposition

• Sheng Zhong,
• Thomas Koch,
• Stefan Walheim,
• Harald Rösner,
• Eberhard Nold,
• Aaron Kobler,
• Torsten Scherer,
• Di Wang,
• Christian Kübel,
• Mu Wang,
• Horst Hahn and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2014, 5, 1285–1290, doi:10.3762/bjnano.5.142

• fabricated from AgNO3 electrolyte via electrodeposition without the help of templates, additives, and surfactants. Although the wire growth speed is very fast due to growth under non-equilibrium conditions, the wire morphology is regular and uniform in diameter. Structural studies reveal that the wires are

• potentiostatic mode without the need to use any templates, surfactants or additives. At the same time, our method has the advantages of high deposition rate, low reaction temperature, and low cost which are traditionally associated with electrochemical deposition techniques [27]. Results and Discussion The

• the wire are rough. Conclusion We have reported a novel technique for fabricating single-crystalline silver wires by electrochemical deposition, without introducing templates, additives and surfactants. The simple experimental setup and the wide range of control parameters make this approach a

Exploring the complex mechanical properties of xanthan scaffolds by AFM-based force spectroscopy

• Hao Liang,
• Guanghong Zeng,
• Yinli Li,
• Shuai Zhang,
• Huiling Zhao,
• Lijun Guo,
• Bo Liu and
• Mingdong Dong

Beilstein J. Nanotechnol. 2014, 5, 365–373, doi:10.3762/bjnano.5.42

• cell incubation [2] and the repair of damaged tissue [3]. Xanthan, a polysaccharide which can self-associate into a scaffold structure [4][5], has been widely used in various fields, such as food additives [6] and drug delivery [7][8]. A number of tools, including NMR [9][10], circular dichroism (CD

Extracellular biosynthesis of gadolinium oxide (Gd₂O₃) nanoparticles, their biodistribution and bioconjugation with the chemically modified anticancer drug taxol

• Shadab Ali Khan,
• Sanjay Gambhir and
• Absar Ahmad

Beilstein J. Nanotechnol. 2014, 5, 249–257, doi:10.3762/bjnano.5.27

• convertor [2][3], as additives in UO2 fuel rods for nuclear reactors [2], and as an additive in ZrO2 to enhance its toughness [3][4]. Gd2O3 has several potential applications in biomedicine, too. For example, it is used in magnetic resonance imaging, since it exhibits superparamagnetism and involves T1

Oriented attachment explains cobalt ferrite nanoparticle growth in bioinspired syntheses

• Annalena Wolff,
• Walid Hetaba,
• Marco Wißbrock,
• Stefan Löffler,
• Nadine Mill,
• Katrin Eckstädt,
• Axel Dreyer,
• Inga Ennen,
• Norbert Sewald,
• Peter Schattschneider and
• Andreas Hütten

Beilstein J. Nanotechnol. 2014, 5, 210–218, doi:10.3762/bjnano.5.23

• the signals shown as gray areas in the figures. Schematic of the oriented attachment process that occurs in the presence of organic additives. (a) Nuclei grow into primary building blocks, which are displayed in (b). These primary building blocks reorganize and form a mesocrystal (c). The primary

Exploring the retention properties of CaF₂ nanoparticles as possible additives for dental care application with tapping-mode atomic force microscope in liquid

• Matthias Wasem,
• Joachim Köser,
• Sylvia Hess,
• Enrico Gnecco and
• Ernst Meyer

Beilstein J. Nanotechnol. 2014, 5, 36–43, doi:10.3762/bjnano.5.4

• nanoparticles are candidates for additives in dental care products as they could serve as fluorine-releasing containers preventing caries during a cariogenic acid attack on the teeth. We show that the adherence of the nanoparticles is increased on the enamel substrate compared to mica, independently of the

Synthesis and electrochemical performance of Li₂Co_1−xM_xPO₄F (M = Fe, Mn) cathode materials

• Nellie R. Khasanova,
• Oleg A. Drozhzhin,
• Stanislav S. Fedotov,
• Darya A. Storozhilova,
• Rodion V. Panin and
• Evgeny V. Antipov

Beilstein J. Nanotechnol. 2013, 4, 860–867, doi:10.3762/bjnano.4.97

• glucose to the initial mixtures of reagents resulted in multiphase samples that contained large amounts of metallic Co (>10%), which can be explained by the strongly reductive conditions that appeared at elevated temperatures (>700 °С) because of the presence of C-containing additives. Therefore, for the

Optimization of solution-processed oligothiophene:fullerene based organic solar cells by using solvent additives

• Gisela L. Schulz,
• Marta Urdanpilleta,
• Roland Fitzner,
• Eduard Brier,
• Elena Mena-Osteritz,
• Egon Reinold and
• Peter Bäuerle

Beilstein J. Nanotechnol. 2013, 4, 680–689, doi:10.3762/bjnano.4.77

• devices typically display much better performances in photovoltaic cells. Keywords: active layer morphology; comparison vacuum-processed solar cells; maximum solubility; oligothiophene; solar cells; solution-processed bulk heterojunction; solvent additives; Introduction The demand for the development of

• BHJSCs. To date, there have been many reports of polymer-based solar cells, which have demonstrated significant increases in efficiencies with the use of solvent additives [22][23][24][25][26][27][28], however, there are only a handful of examples in which oligomer-based donors were used [15][16][17][29

• (vide infra) demonstrate that the DCV5T-Bu4:PC61BM devices generate a photocurrent in the range of 400 to 700 nm and display maximum conversion at 580 nm. The EQE at 580 nm was measured to 40% and 36% for solar cells made with and without solvent additives, respectively. Further information regarding

Effect of spherical Au nanoparticles on nanofriction and wear reduction in dry and liquid environments

• Dave Maharaj and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2012, 3, 759–772, doi:10.3762/bjnano.3.85

• Dave Maharaj Bharat Bhushan Nanoprobe Laboratory for Bio- & Nanotechnology and Biomimetics (NLBB), The Ohio State University, 201 W. 19th Avenue, Columbus, Ohio 43210-1142, USA 10.3762/bjnano.3.85 Abstract Nano-object additives are used in tribological applications as well as in various

• contact with each other and surfaces present in their working environment, is necessary. Nano-object additives have proven to be successful in macroscale studies in reducing friction and wear when added to solid materials and base-liquid lubricants and are expected to provide similar benefits on the micro

• testers [26]. In these studies, glycerol was also combined with water to lower the viscosity, which may be feasible for micro/nanoscale applications. Dodecane has been used as a base fluid with ZnS nanorod additives [27], which also resulted in a reduction in the coefficient of friction and wear. Tests

Focused electron beam induced deposition: A perspective

• Michael Huth,
• Fabrizio Porrati,
• Christian Schwalb,
• Marcel Winhold,
• Roland Sachser,
• Maja Dukic,
• Jonathan Adams and
• Georg Fantner

Beilstein J. Nanotechnol. 2012, 3, 597–619, doi:10.3762/bjnano.3.70

• the growth of diamond-like carbon (DLC) films with metal additives can be stated [11]. A distinct difference between FEBID and DLC thin-film research is of course that, in most instances, attempts are made to tune the FEBID process such that carbon inclusion in the deposit can be avoided, whereas in

Directed deposition of silicon nanowires using neopentasilane as precursor and gold as catalyst

• Britta Kämpken,
• Verena Wulf,
• Norbert Auner,
• Marcel Winhold,
• Michael Huth,
• Daniel Rhinow and
• Andreas Terfort

Beilstein J. Nanotechnol. 2012, 3, 535–545, doi:10.3762/bjnano.3.62

• process of nanoparticles often requires other reagents, e.g., for micelle nanolithography or chemisorption at surface-attached organic monolayers [24][25]. These organic additives (stabilizer/monolayer) might disturb the growth process of the silicon NWs and lead to contaminations, thus they need to be

Low-temperature synthesis of carbon nanotubes on indium tin oxide electrodes for organic solar cells

• Andrea Capasso,
• Luigi Salamandra,
• Aldo Di Carlo,
• John M. Bell and
• Nunzio Motta

Beilstein J. Nanotechnol. 2012, 3, 524–532, doi:10.3762/bjnano.3.60

• , such as thermal [8] and solvent annealing [9], or the use of additives in the blend preparation [10]. Along with fullerenes, carbon nanotubes (CNTs) have also been suggested as promising materials to boost solar cell PCE, thanks to their excellent electrical properties and to a favorable aspect ratio

Functionalised zinc oxide nanowire gas sensors: Enhanced NO₂ gas sensor response by chemical modification of nanowire surfaces

• Eric R. Waclawik,
• Jin Chang,
• Andrea Ponzoni,
• Isabella Concina,
• Dario Zappa,
• Elisabetta Comini,
• Nunzio Motta,
• Guido Faglia and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2012, 3, 368–377, doi:10.3762/bjnano.3.43

• catalyst nanoparticle additives, and decreasing the crystallite (grain) sizes or intercrystallite neck dimensions to the nanometre scale. Chemical functionalisation as an approach to modify the response of semiconductor surfaces towards different gases has not been examined to anywhere near the same level

Electron-beam patterned self-assembled monolayers as templates for Cu electrodeposition and lift-off

• Zhe She,
• Andrea DiFalco,
• Georg Hähner and
• Manfred Buck

Beilstein J. Nanotechnol. 2012, 3, 101–113, doi:10.3762/bjnano.3.11

• contribution to the roughness must be significantly smaller. There is scope for further improvement, as the optimisation of parameters, such as nucleation potential, time, growth potential, and the use of additives [45], was not systematically investigated. Furthermore, the lift-off process has not been

Synthesis and catalytic applications of combined zeolitic/mesoporous materials

• Jarian Vernimmen,
• Vera Meynen and
• Pegie Cool

Beilstein J. Nanotechnol. 2011, 2, 785–801, doi:10.3762/bjnano.2.87

• catalysts [1][2][3][4][5][11], drying agents [5][12], adsorbers [5][13], sensors [14][15], controlled-drug-release agents [6][8], column-packing material [16], food additives [17], etc. According to IUPAC (International Union of Pure and Applied Chemistry) nomenclature, nanoporous materials are classified

Approaches to nanostructure control and functionalizations of polymer@silica hybrid nanograss generated by biomimetic silica mineralization on a self-assembled polyamine layer

• Jian-Jun Yuan and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2011, 2, 760–773, doi:10.3762/bjnano.2.84

• additives, mediators or templates [13][14]. This is completely different from the conventional silica deposition, which requires nonideal conditions, such as elevated temperature, extreme pH, and the presence of either a large amount of surfactants and/or organic cosolvents [15][16][17][18]. Moreover, it is

Highly efficient ZnO/Au Schottky barrier dye-sensitized solar cells: Role of gold nanoparticles on the charge-transfer process

• Tanujjal Bora,
• Htet H. Kyaw,
• Soumik Sarkar,
• Samir K. Pal and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2011, 2, 681–690, doi:10.3762/bjnano.2.73

• electrolyte-exposed part of the metal oxide film by means of different additives in the electrolyte [10][11][12][13] or by using the core-shell structure of various metal oxides [14][15][16][17][18] have been reported. In this work we discuss the use of Au nanoparticles in a DSSC based on ZnO nanorods to