Beilstein J. Nanotechnol.2011,2, 15–27, doi:10.3762/bjnano.2.2
verification of KFM operations. The same is true for metal alloys because their surface potentials are directly defined by workfunction [8].
At the beginning we compare KFM imaging in the non-contact and intermittent contact modes. When the AFM probe, which is driven into an oscillation at its resonant
related to the strength and orientation of the molecular dipole, as is the case in fluoroalkanes self-assemblies. In other materials surface potential correlates to the surface workfunction of metals, the doping level of semiconductors, the strength and orientation of molecular dipoles, and the presence
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Figure 1:
Sketch illustrating implementation of Kelvin force microscopy in the AM–FM mode. Two servo-loops, w...
Beilstein J. Nanotechnol.2011,2, 1–14, doi:10.3762/bjnano.2.1
force microscopy; scanning tunneling microscopy; thin films; workfunction; Review
Introduction
The chemical properties of many crystal surfaces, especially oxides, are significantly influenced by defects in the perfectly ordered structure [1][2][3][4][5]. These defects can be impurities in the surface
material with the lower workfunction (here tip) flow to the material with the higher workfunction. The Fermi levels align and an electrical field is built up [21]. The contact potential ΔΦ is then given by the difference in workfunction of the tip and of the sample surface, which may contain the studied
single point defects or single adsorbates, instead of integrating over a square millimeter range. However, absolute values of the workfunction cannot be measured directly, only workfunction differences.
Point defects
Oxygen vacancies, also known as color centers, are electron trapping point defects and
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Figure 1:
Model of a binary oxide surface. Point defects such as color centers, which are preferably situated...