Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• Fullerene (C60) has been deposited in ultrahigh vacuum on top of a zinc tetraphenylporphyrin (ZnTPP) monolayer self-assembled on a Fe(001)–p(1 × 1)O substrate. The nanoscale morphology and the electronic properties of the C60/ZnTPP/Fe(001)–p(1 × 1)O heterostructure have been investigated by scanning

• materials possessing antithetic electronic and structural properties. In this frame, the molecule–metal interaction arising at the interface plays a crucial role in determining the morphology and the electronic properties of the hybrid organic/inorganic system. With regard to the structural aspects, a

• aspect is the electronic coupling between the molecules and the metallic substrate. In this case, the key parameter is the adsorption energy (Ea), which is defined as the energy required to desorb a molecule from the surface. A high Ea is characteristic of molecules chemisorbed on the substrate, where a

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• angles were ≈2° and ≈18°. The relaxation of the electronic subsystem was monitored by the relative change in the reflection coefficient (∆R/R). Ultrafast dynamics of the magnetization was analyzed by the deviation of the angle of rotation of the polarization plane of the probing light from the

• reflection coefficient of the Pd and Pd0.962Fe0.038 films at the lowest temperature, a minimum of four is required for the Pd0.94Fe0.06 film and only three for Pd0.92Fe0.08. Thus, with an increase in the iron concentration x in a Pd1−xFex system, the photoinduced dynamics of the electronic subsystem changes

• our attention at the components of the ultrafast responses of the electronic (reflectivity) and magnetic (Kerr rotation angle) subsystems, which demonstrate a clear correlation with the establishment of the long-range magnetic order in Pd1–xFex films. In the ΔR/R(Δt) dependences of the alloys, the

Ideal Kerker scattering by homogeneous spheres: the role of gain or loss

• Qingdong Yang,
• Weijin Chen,
• Yuntian Chen and
• Wei Liu

Beilstein J. Nanotechnol. 2022, 13, 828–835, doi:10.3762/bjnano.13.73

• Qingdong Yang Weijin Chen Yuntian Chen Wei Liu School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R. China Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• , on the one hand, and their non-toxicity and low vapor pressure, on the other hand. Room-temperature-liquid Ga-based alloys are considered for direct writing and printing stretchable and flexible electronic devices, such as antennas or wires [5][6][7]. Such applications and the related processing of

Optimizing PMMA solutions to suppress contamination in the transfer of CVD graphene for batch production

• Chun-Da Liao,
• Andrea Capasso,
• Tiago Queirós,
• Telma Domingues,
• Fatima Cerqueira,
• Nicoleta Nicoara,
• Jérôme Borme,
• Paulo Freitas and
• Pedro Alpuim

Beilstein J. Nanotechnol. 2022, 13, 796–806, doi:10.3762/bjnano.13.70

• ), in evident contrast with the scattered values obtained in non-optimized devices (about 30% of which showed values above 1 MΩ). These results prove that the optimized PMMA solution unlock the production of reproducible electronic devices at the batch scale, which is the key to industrial production

• ) and 1860 Ω (FWHM = 567 Ω), respectively, proving that the optimized PMMA mixture enables the production of reproducible arrays of electronic devices with consistent properties. Experimental Graphene growth Single-crystal and large-area graphene were obtained on Cu foil via catalyst-assisted growth in

Efficient liquid exfoliation of KP₁₅ nanowires aided by Hansen's empirical theory

• Zhaoxuan Huang,
• Zhikang Jiang,
• Nan Tian,
• Disheng Yao,
• Fei Long,
• Yanhan Yang and
• Danmin Liu

Beilstein J. Nanotechnol. 2022, 13, 788–795, doi:10.3762/bjnano.13.69

• Zhaoxuan Huang Zhikang Jiang Nan Tian Disheng Yao Fei Long Yanhan Yang Danmin Liu School of Materials Science and Engineering, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient

• response of exfoliated KP15. Funding This work was supported by the National Natural Science Foundation of China under the grant (51972006), Guangxi Key Laboratory of Optical and Electronic Materials and Devices (20AA-19), Guilin University of Technology research fund (GUTQDJJ2019031), Guangxi Young and

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• Lingling Xia Qinyue Wang Ming Hu Engineering Research Center for Nanophotonics and Advanced Instrument (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China 10.3762/bjnano.13.67 Abstract Various kinds of monocrystalline coordination polymers are

• polymer matches with the surface of the substrate, triggering isotropic or preferential growth of the monocrystalline coordination polymers [121]. Epitaxial growth is significant for future application of the coordination polymers, particularly for electronic applications [122]. The key prerequisite is to

• nanosheets are confined by each other. The electronic structures of the molecules in the colloids should be strongly alternated, leading to functional solids. Conclusion In this review, we introduced recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly. The

A nonenzymatic reduced graphene oxide-based nanosensor for parathion

• Sarani Sen,
• Anurag Roy,
• Ambarish Sanyal and
• Parukuttyamma Sujatha Devi

Beilstein J. Nanotechnol. 2022, 13, 730–744, doi:10.3762/bjnano.13.65

• , enhanced electron transport facility, excellent mechanical, thermal, and electrical stability [11][25][26][27]. The electronic structure and surface physicochemistry of graphene are beneficial for electron transfer. Several graphene-based nanocomposites based on complex synthesis processes are reported as

• GO. The SEM micrograph of ERGO (Figure 3G) also shows graphene sheet exfoliated layers compared to GO (Figure 3F). The FESEM image also depicts the flaked nanostructure of RGO (Figure 3H). Electrochemical characterization of the modified electrode The electronic properties of graphene materials

Modeling a multiple-chain emeraldine gas sensor for NH₃ and NO₂ detection

• Hana Sustkova and
• Jan Voves

Beilstein J. Nanotechnol. 2022, 13, 721–729, doi:10.3762/bjnano.13.64

• resistance [6]. In the work of Kroutil et al. [7], a polyaniline gas sensor setup was used for measuring NH3, NO2, and other gases. Ammonia should be, according to these results, the gas that most affects the polyaniline resistance; nitrogen dioxide moderately affects the resistance. Many electronic and

Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• , Giheung-gu, Yongin 17104, Republic of Korea Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Hyeonpung-eup, Dalseong-gun, Daegu 42988, Republic of Korea Institute for Superconducting and Electronic Materials, Australian

• which the highly porous ZnxCoy–C particles are beneficial for facilitating the electrochemical reactions between Li+ and O2. Moreover, CNT networks allow for sufficient electronic conduction as well as diffusion pathways for O2 and electrolyte in the composites. The atomic ratios of Zn and in the Zn1Co4

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• -dependent scattering. In contrast, we treat spin mixing of arbitrary strength exactly. The distribution of spin mixing angles (δφn, n is the channel index) along the transport channels is the only unknown in the theory. This distribution can be probed directly in a fully electronic experiment, measuring the

Sodium doping in brookite TiO₂ enhances its photocatalytic activity

• Boxiang Zhuang,
• Honglong Shi,
• Honglei Zhang and
• Zeqian Zhang

Beilstein J. Nanotechnol. 2022, 13, 599–609, doi:10.3762/bjnano.13.52

• brookite TiO2 changes with the preparing details is still unclear. The varied local structures of brookite can affect its electronic structure and hence its photocatalytic performance. Here, we report that Na-doped brookite NaxTi1−xO2 was synthesized by a hydrothermal reaction of tetrabutyl titanate

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• fascinating optical and electronic properties [1]. In particular, the optical absorption, direct bandgap, and broken inversion symmetry of 2D transition-metal dichalcogenide (2D-TMDC) monolayers make these materials promising candidates for light-emitting diodes, photodetectors, field-effect transistors

• effects strongly influence the optical and electronic properties of 2D-TMDC materials. Optical second harmonic generation (SHG) spectroscopy has been recently used to study the presence of mid-gap states in the electronic band structure of WS2 flakes, which are induced by sulfur vacancies [14]. In

• defect-induced band bending of the conduction band at K and Q states in few-layer MoS2 [9][10]. All in all, structural irregularities play a crucial role in the modification of the electron band structure in 2D-TMDCs, further ruling their optical and electronic properties. Therefore, the relationship

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• on semiconductors decorated with noble metals, or vice versa, has been proposed. These hybrid nanostructures show enhanced optical and electronic properties due to the coupling between the noble metal and the semiconductor [10][11][13]. Various fabrication techniques have been employed to develop

• chemical enhancement from the electronic interaction between the analyte and the nanosurface [59]. The electromagnetic enhancement factor (EF) can reach up to eleven orders of magnitude in the “hot spots” of the nanosubstrate [60][61], while the chemical EF usually has a value between 10 and 103. Since the

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• collision, rotational or vibrational transitions, electron attachment, electronic excitation, and ionization [4][5]. Oriented molecular layers on surfaces are particularly well suited for such studies as surface analytical tools, such as scanning tunneling microscopy (STM), allow for detailed observations

• create ultrathin carbon nanomembranes (CNMs) [25][26]. Depending on the precursor molecules and the exposure conditions, thickness [27], mechanical stiffness [28], and electronic transport characteristics [29][30] of CNMs can be tailored. Carbon nanomembranes have been applied as electron microscopy

• initiates a reaction with an adjacent molecule and generates another new radical carbon center, which may react with other molecules. According to Amiaud et al. [53], the formation of first radicals can be caused either by electronic rearrangement or dissociative electron attachment of the negative ion

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• (MTUCI), 111024 Moscow, Russia Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia Lobachevsky State University of Nizhni Novgorod Faculty of Physics, 603950 Nizhny Novgorod, Russia Dukhov All-Russia Research Institute of Automatics, 101000 Moscow, Russia Institute of Electronic

• layers supports the superconducting order parameter and increases the efficiency of the spin valve effect [58]. Here, we propose a development of this approach, allowing one to significantly increase the effective variations in the kinetic inductance. We study proximity effect and electronic transport in

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• ]. However, the potential of such electronic nose systems varies according to the implemented classification system. Only between two and four different statistical analysis and classification algorithms were used in the cited literature [22][23][24][25]. In this work, we developed a robust system with seven

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• Teng Cai Yuming Fang Yingli Fang Ruozhou Li Ying Yu Mingyang Huang College of Electronic and Optical Engineering & College of Microelectronics, Nanjing University of Posts and Telecommunications, Nanjing, China National and Local Joint Engineering Laboratory of RF Integration and Micro-Assembly

• Technology, Nanjing University of Posts and Telecommunications, Nanjing, China 10.3762/bjnano.13.32 Abstract The electrostatic pull-in effect is a common phenomenon and a key parameter in the design of microscale and nanoscale devices. Flexible electronic devices based on the pull-in effect have attracted

• more and more difficult for traditional electronic devices made of rigid substrates to meet the needs of flexible and low-cost applications in complex environments. Flexible electronics have great potential for applications such as portable displays, electronic skin, and wearable healthcare. With the

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• : aluminium zinc oxide; magnetron sputtering; thin film; transparent conducting oxide; transparent electronics; Introduction Aluminium-doped zinc oxide (AZO) is a potential alternative to indium tin oxide (ITO) for transparent conducting oxide (TCO) electrodes in transparent electronic and photovoltaic

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• , 52074 Aachen, Germany Faculty of Medical Engineering and Applied Mathematics, FH Aachen, University of Applied Science, 52428 Jülich, Germany 10.3762/bjnano.13.16 Abstract The performance of nanoelectronic and molecular electronic devices relies strongly on the employed functional units and their

• addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands

• . Molecular engineering is required to design and assemble molecules or supramolecular systems with specific functions and to ensure the device performance. Favorable molecular systems are capable of performing electronic operations such as data storage, rectification, sensing or switching. In this regard

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• , and low toxicity [1]. TiO2 nanomaterials can be applied in a host of applications, including biomedical, optical, electronic, mechanical, and chemical fields, amongst other scenarios [2]. The application of titania nanomaterials in the pharmaceutical field has brought revolutionary changes by

Low-energy electron interaction and focused electron beam-induced deposition of molybdenum hexacarbonyl (Mo(CO)₆)

• Po-Yuan Shih,
• Maicol Cipriani,
• Christian Felix Hermanns,
• Jens Oster,
• Klaus Edinger,
• Armin Gölzhäuser and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2022, 13, 182–191, doi:10.3762/bjnano.13.13

• in hexacarbonyls [18] from one electronic state. The contributions at 1.65, 2.14 and 3.29 eV are assigned to the higher lying 3t2u, 8eg and 6t2g orbitals, respectively. These assignments are based on Xα calculations and the authors explicitly point out that the assignments of the peaks observed are

Thermal oxidation process on Si(113)-(3 × 2) investigated using high-temperature scanning tunneling microscopy

• Hiroya Tanaka,
• Shinya Ohno,
• Kazushi Miki and
• Masatoshi Tanaka

Beilstein J. Nanotechnol. 2022, 13, 172–181, doi:10.3762/bjnano.13.12

• ) has been used as the ideal tool to investigate reaction dynamics on surfaces. In our previous studies, we applied our VT-STM to investigate hydrogen diffusion [5] and titanium silicide formation [6] on Si(001). In our previous studies of oxidation on Si(113), we investigated the electronic states of

Theoretical understanding of electronic and mechanical properties of 1T′ transition metal dichalcogenide crystals

• Seyedeh Alieh Kazemi,
• Sadegh Imani Yengejeh,
• Vei Wang,
• William Wen and
• Yun Wang

Beilstein J. Nanotechnol. 2022, 13, 160–171, doi:10.3762/bjnano.13.11

• of layered 1T′ TMD crystals have rarely been studied. As TMD monolayers do not have interlayer interactions, their physicochemical properties will differ from those of layered TMD materials. In this study, the electronic and mechanical characteristics of a range of 1T′ TMDs are systematically

• from catalysis to energy storage and electronic devices [1][2][3][4][5][6]. Generally, each TMD layer can be described as a sandwich type of structure (X–TM–X), where TM and X are transition metal cations (e.g., Mo and W) and chalcogen anions (e.g., S and Se). Individual layers are bound via

• that the performance of 1T′ TMDs is strongly determined by their electronic and mechanical characteristics [11][12][13][14][15][16][17][18][19][20][21]. A lot of work has been devoted to the understanding of the properties of two-dimensional (2D) TMD monolayers [22][23][24][25][26][27]. Multilayered

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• oxide (not to be confused with stannous oxide with tin in the oxidation state of 2+ [13], also known as cassiterite [14]. SnO2 materials have many interesting properties. For instance, the structure and electronic structure can be manipulated easily due to the highly tunable valence state and oxygen