Nano- and microstructured materials for in vitro studies of the physiology of vascular cells

• Alexandra M. Greiner,
• Adria Sales,
• Hao Chen,
• Sarah A. Biela,
• Dieter Kaufmann and
• Ralf Kemkemer

Beilstein J. Nanotechnol. 2016, 7, 1620–1641, doi:10.3762/bjnano.7.155

• , Faculty of Applied Chemistry, Alteburgstrasse 150, 72762 Reutlingen, Germany 10.3762/bjnano.7.155 Abstract The extracellular environment of vascular cells in vivo is complex in its chemical composition, physical properties, and architecture. Consequently, it has been a great challenge to study vascular

Biomechanics of selected arborescent and shrubby monocotyledons

• Tom Masselter,
• Tobias Haushahn,
• Samuel Fink and
• Thomas Speck

Beilstein J. Nanotechnol. 2016, 7, 1602–1619, doi:10.3762/bjnano.7.154

• plants. To date, while the variation of physical properties from top to base and centre to periphery, as well as the underlying structural features, are well known in many dicotyledonous trees [1], these property shifts are still hardly studied in tree-like monocotyledons. This knowledge deficit is

• largely caused by a lack of interest for empirical data for monocotyledon stems and is a result of their insignificance as constructional material in many (industrialized) countries with the major exception of bamboo culms [2]. Results for physical properties of dicot plants cannot be transferred to

Influence of hydrothermal synthesis parameters on the properties of hydroxyapatite nanoparticles

• Sylwia Kuśnieruk,
• Jacek Wojnarowicz,
• Agnieszka Chodara,
• Tadeusz Chudoba,
• Stanislaw Gierlotka and
• Witold Lojkowski

Beilstein J. Nanotechnol. 2016, 7, 1586–1601, doi:10.3762/bjnano.7.153

• found when comparing the properties of some types of nanostructured hydroxyapatite with natural occurring apatite found in animal bones and teeth. Keywords: hydroxyapatite; microwave hydrothermal synthesis; nanoparticle size control; physical properties of HAp NPs; room temperature synthesis

Surface roughness rather than surface chemistry essentially affects insect adhesion

• Matt W. England,
• Tomoya Sato,
• Makoto Yagihashi,
• Atsushi Hozumi,
• Stanislav N. Gorb and
• Elena V. Gorb

Beilstein J. Nanotechnol. 2016, 7, 1471–1479, doi:10.3762/bjnano.7.139

• also produce capillary forces. Inspired by this idea, artificial silicone polymer structures with underwater adhesive properties were fabricated [34]. Thus, the relationship between surface structures and the attachment of insects, in combination with their particular chemical/physical properties, has

• different surface chemical and physical properties, (see above)) were measured. Obtained force–time curves were used to estimate the maximal traction force. Experiments were performed at 23 °C temperature and 26–29% relative humidity. We tested 10 male and 10 females and carried out 160 traction tests in

• , rather than C and F concentrations, had the strongest influence upon surface wettability. Based on the surface chemical and physical properties of our samples shown above, we next examined the attachment ability of Coccinella septempunctata beetles by measuring their traction forces on these surfaces

On the pathway of cellular uptake: new insight into the interaction between the cell membrane and very small nanoparticles

• Claudia Messerschmidt,
• Daniel Hofmann,
• Anja Kroeger,
• Katharina Landfester,
• Volker Mailänder and
• Ingo Lieberwirth

Beilstein J. Nanotechnol. 2016, 7, 1296–1311, doi:10.3762/bjnano.7.121

• specific cellular endocytic mechanisms depending on the material, surface charge or size of the applied nanoparticle [32][33]. So far, less is known about the modes of uptake mediated by physical properties of nanoparticles in the diameter range below 25 nm. With our morphological observations we clearly

In situ characterization of hydrogen absorption in nanoporous palladium produced by dealloying

• Eva-Maria Steyskal,
• Christopher Wiednig,
• Norbert Enzinger and
• Roland Würschum

Beilstein J. Nanotechnol. 2016, 7, 1197–1201, doi:10.3762/bjnano.7.110

• regime. Nanoporous metals freshly prepared by dealloying are in a strongly oxidized condition, associated with particular physical properties [15][16][12][13]. By suitable treatment, i.e., repeated cyclic voltammetry (CV) in a wide potential range, the sample can be reduced until finally a metallic CV

Reasons and remedies for the agglomeration of multilayered graphene and carbon nanotubes in polymers

• Rasheed Atif and
• Fawad Inam

Beilstein J. Nanotechnol. 2016, 7, 1174–1196, doi:10.3762/bjnano.7.109

• surfactant solution. The reactions involved are carried out in argon atmosphere [117]. A typical disorder band in Raman spectrum gives proof of the sidewall functionalization. This sidewall functionalization not only improves purity and solubility, but it also changes the physical properties. In fact, the

• improve the physical properties of hybrid nanocomposites. Sumfleth et al. doped titania into MWNT–epoxy [57]. They found enhanced CNT dispersion and synergistic effects in these multiphase nanocomposites. Ma et al. doped nanoclay into CNT–acrylonitrile butadiene styrene (ABS) system and found enhanced CNT

Manufacturing and investigation of physical properties of polyacrylonitrile nanofibre composites with SiO₂, TiO₂ and Bi₂O₃ nanoparticles

• Tomasz Tański,
• Wiktor Matysiak and
• Barbara Hajduk

Beilstein J. Nanotechnol. 2016, 7, 1141–1155, doi:10.3762/bjnano.7.106

• of a matrix of polyacrylonitrile (PAN) and a reinforcing phase in the form of SiO2/TiO2/Bi2O3 nanoparticles, by electrospinning the solution. The effect of the nanoparticles and the electrospinning process parameters on the morphology and physical properties of the obtained composite nanofibres was

• then examined. The morphology of the fibres and the dispersion of nanoparticles in their volume were examined using scanning electron microscopy (SEM). All of the physical properties, which included the band gap width, dielectric constant and refractive index, were tested and plotted against the

• same parameters of solutions and the same flow rate. 3 Analysis of the physical properties of the obtained layers 3.1 Ellipsometry studies of the produced layers An assessment of the thickness of the produced fibrous layers was carried out using ellipsometric analysis (Table 1). The polymer mats of PAN

Advanced atomic force microscopy techniques III

• Thilo Glatzel and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2016, 7, 1052–1054, doi:10.3762/bjnano.7.98

• measurements in between atoms of single molecules or molecular assemblies at positions where chemical bonds are expected [4][5][6]. However, the origin of this contrast is under intense discussion [7][8]. The extension of the technique towards other physical properties in surface science is pushed continuously

Frog tongue surface microstructures: functional and evolutionary patterns

• Thomas Kleinteich and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2016, 7, 893–903, doi:10.3762/bjnano.7.81

• on our test surface and that the amount of the mucus coverage increases with increasing contact duration. These results suggested (1) that during the initial contact formation, only small amounts of mucus are present on the tongue and (2) that besides chemical and physical properties of the mucus

• slightly protracted over the tip of the lower jaw [6][42]. However, other than during tongue projection, the tongue is not passively elongated by inertia. A more complete taxon sampling and evaluation of the physical properties of the lacunar layer in different frog tongues are needed to test if there is a

Reconstitution of the membrane protein OmpF into biomimetic block copolymer–phospholipid hybrid membranes

• Matthias Bieligmeyer,
• Franjo Artukovic,
• Stephan Nussberger,
• Thomas Hirth,
• Thomas Schiestel and
• Michaela Müller

Beilstein J. Nanotechnol. 2016, 7, 881–892, doi:10.3762/bjnano.7.80

• high potential in technical applications, for example the desalination of water using aquaporins or the controlled release of antibiotics from OmpF-functionalized nanoreactors [11][12][13][14][15]. Although the chemical and physical properties of natural phospholipid bilayers are optimized for the

The role of morphology and coupling of gold nanoparticles in optical breakdown during picosecond pulse exposures

• Yevgeniy R. Davletshin and
• J. Carl Kumaradas

Beilstein J. Nanotechnol. 2016, 7, 869–880, doi:10.3762/bjnano.7.79

• perfectly matched layer (PML) domain and an absorbing boundary condition to truncate the electromagnetic domain and reduce reflections from artificial boundaries. The red and green domains represent an aqueous environment with dielectric and physical properties of water. The green domain is used to

Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate

• Rainhard Machatschek,
• Patrick Ortmann,
• Renate Reiter,
• Stefan Mecking and
• Günter Reiter

Beilstein J. Nanotechnol. 2016, 7, 784–798, doi:10.3762/bjnano.7.70

• molecules to an insulating, smooth and crystalline substrate, we aim at creating a compact and homogeneous monolayer of semiconducting molecules. This method can be applied to many semiconducting molecules independent of their chemical structure and physical properties, provided that these molecules possess

Facile synthesis of water-soluble carbon nano-onions under alkaline conditions

• Gaber Hashem Gaber Ahmed,
• Rosana Badía Laíño,
• Josefa Angela García Calzón and
• Marta Elena Díaz García

Beilstein J. Nanotechnol. 2016, 7, 758–766, doi:10.3762/bjnano.7.67

• -onions (C-onions) are another kind of carbon nanoparticles that exhibit outstanding chemical and physical properties. C-onions are spherical carbon shells enclosed within one another (multi-layered fullerenes) with diameters ranging from 3 to 50 nm [9], depending on the method of synthesis. C-onions have

Magnetic switching of nanoscale antidot lattices

• Ulf Wiedwald,
• Joachim Gräfe,
• Kristof M. Lebecki,
• Maxim Skripnik,
• Felix Haering,
• Gisela Schütz,
• Paul Ziemann,
• Eberhard Goering and
• Ulrich Nowak

Beilstein J. Nanotechnol. 2016, 7, 733–750, doi:10.3762/bjnano.7.65

• ; magnetic nanostructures; magnetic switching; micromagnetic simulations; plasma etching; spin ice; X-ray microscopy; Introduction In nanotechnology, a widely used approach for tailoring physical properties on the nanometre length scale is the introduction of practically circular holes – so-called antidots

Microwave solvothermal synthesis and characterization of manganese-doped ZnO nanoparticles

• Jacek Wojnarowicz,
• Roman Mukhovskyi,
• Elzbieta Pietrzykowska,
• Sylwia Kusnieruk,
• Jan Mizeracki and
• Witold Lojkowski

Beilstein J. Nanotechnol. 2016, 7, 721–732, doi:10.3762/bjnano.7.64

• -doped zinc oxide nanoparticles; microwave solvothermal synthesis (MSS); characterization techniques of nanomaterials; physical properties of Mn2+-doped ZnO nanoparticles; Introduction Nanotechnology has triggered a new global industrial revolution of the 21st century [1]. At present it is the leading

• [2]. It enables the use of nanomaterials for creating innovative products, devices and complex systems that employ the properties of materials on the nanoscale [3]. Current research of the applications of nanotechnology in optoelectronics focuses on the control of the physical properties of metal

Tight junction between endothelial cells: the interaction between nanoparticles and blood vessels

• Yue Zhang and
• Wan-Xi Yang

Beilstein J. Nanotechnol. 2016, 7, 675–684, doi:10.3762/bjnano.7.60

• key kinases in the phosphorylation of TJ core proteins; (2) disruption of the oxidative status and oxidative stress around the TJ barrier; (3) changing the shear stress of the blood flow through the physical properties of the NPs. Recent research showed the interaction between the exposure to NPs and

Novel roles for well-known players: from tobacco mosaic virus pests to enzymatically active assemblies

• Claudia Koch,
• Fabian J. Eber,
• Carlos Azucena,
• Alexander Förste,
• Stefan Walheim,
• Thomas Schimmel,
• Alexander M. Bittner,
• Holger Jeske,
• Hartmut Gliemann,
• Sabine Eiben,
• Fania C. Geiger and
• Christina Wege

Beilstein J. Nanotechnol. 2016, 7, 613–629, doi:10.3762/bjnano.7.54

• chemical and physical properties, based on the combination of a multitude of synthetic and inorganic compounds with virus assemblies [5][7][68][69][89][90]. Application of TMV-/tobamovirus-based structures In these recent developments, TMV with its rigid, self-assembling nucleoprotein capsid continues to

Invariance of molecular charge transport upon changes of extended molecule size and several related issues

• Ioan Bâldea

Beilstein J. Nanotechnol. 2016, 7, 418–431, doi:10.3762/bjnano.7.37

• description based on the small molecule or on an extended molecule, all the physical properties (e.g., transmission, current, local density of states, charge densities) should be identical. The proof that these properties indeed coincide, which represents an important sanity test for theory, will be given

• gradually include (in addition to sites from the left electrode also) sites belonging to the right electrode (l0 = 1, 2,... in Equation 12). Demonstration that the representations based on the small molecule and minimally extended molecule yield identical physical properties In the following, the quantities

• three-piece partitioning in an extended molecule linked to the left and right side of semi-infinite electrodes is a mental construct that is inherently arbitrary and should by no means affect the current and other physical properties. This is a minimal mandatory requirement for any valid theoretical

Efficiency improvement in the cantilever photothermal excitation method using a photothermal conversion layer

• Natsumi Inada,
• Hitoshi Asakawa,
• Taiki Kobayashi and
• Takeshi Fukuma

Beilstein J. Nanotechnol. 2016, 7, 409–417, doi:10.3762/bjnano.7.36

• ; dynamic mode; photothermal conversion; photothermal excitation; Introduction Atomic force microscopy (AFM) [1] is an analytical technique to investigate nanoscale surface structures and local physical properties of various samples. Dynamic-mode AFM has attracted considerable interests in various fields

• coating of a PTC layer improves the phase response obtained by the photothermal excitation method. Table 1 and Table 2 show the physical properties of PPP-NCHAuD and AC55 cantilevers before and after coating with a PTC layer. The resonance frequency (f0), Q-factor and spring constant (k) of the

• cantilevers were estimated from cantilever thermal vibration spectra obtained in water. We found that the PTC layers coating had little influence on the physical properties of these two types of cantilevers. Thus, a PTC layer should not change cantilever performance, such as force sensitivity. Relationship

Early breast cancer screening using iron/iron oxide-based nanoplatforms with sub-femtomolar limits of detection

• Dinusha N. Udukala,
• Hongwang Wang,
• Sebastian O. Wendel,
• Aruni P. Malalasekera,
• Thilani N. Samarakoon,
• Asanka S. Yapa,
• Gayani Abayaweera,
• Matthew T. Basel,
• Pamela Maynez,
• Raquel Ortega,
• Yubisela Toledo,
• Leonie Bossmann,
• Colette Robinson,
• Katharine E. Janik,
• Olga B. Koper,
• Ping Li,
• Massoud Motamedi,
• Daniel A. Higgins,
• Gary Gadbury,
• Gaohong Zhu,
• Deryl L. Troyer and
• Stefan H. Bossmann

Beilstein J. Nanotechnol. 2016, 7, 364–373, doi:10.3762/bjnano.7.33

• and FRET quenching. Notable exceptions are MMPs 1 (Figure 5) and 7 (Figure 4) where significant matrix effects were detected. As noted in Table S1 in Supporting Information File 1, the physical properties (isoelectric point and hydrophobicity index) of the consensus sequences plus peptide linkers

Hemolysin coregulated protein 1 as a molecular gluing unit for the assembly of nanoparticle hybrid structures

• Tuan Anh Pham,
• Andreas Schreiber,
• Elena V. Sturm (née Rosseeva),
• Stefan Schiller and
• Helmut Cölfen

Beilstein J. Nanotechnol. 2016, 7, 351–363, doi:10.3762/bjnano.7.32

• short linear chains are feasible by this approach using understoichiometric Hcp1_cys3 concentrations and all larger structures contain branches. Nevertheless, the physical properties of these structures and the surface plasmon resonance still correspond to that of a linear structure and network

• structure. Therefore, assembly of NPs with defined interparticle distances using the toroidal cysteine-modified protein Hcp1_cys3 as a gluing unit is a promising approach towards different metallic NP chains and to explore their physical properties. Experimental The Au NP, magnetite and the cobalt ferrite

Synthesis and applications of carbon nanomaterials for energy generation and storage

• Marco Notarianni,
• Jinzhang Liu,
• Kristy Vernon and
• Nunzio Motta

Beilstein J. Nanotechnol. 2016, 7, 149–196, doi:10.3762/bjnano.7.17

• 250 crystalline forms [153]. A large family of similar crystalline forms can be catalogued in particular structures called polytypes, which all present different physical properties. All the polytypes show a similar local chemical environment for both the carbon and silicon species. Specifically, each

Dependence of lattice strain relaxation, absorbance, and sheet resistance on thickness in textured ZnO@B transparent conductive oxide for thin-film solar cell applications

• Kuang-Yang Kou,
• Yu-En Huang,
• Chien-Hsun Chen and
• Shih-Wei Feng

Beilstein J. Nanotechnol. 2016, 7, 75–80, doi:10.3762/bjnano.7.9

• ]. The variation in the physical properties of nanostructures drastically influences the optoelectronic properties of ZnO [11][12][13]. X-ray-excited optical luminescence of ZnO nanoneedles shows a sharp band gap emission and a broad red emission related to surface defects, while that of ZnO

Self-organization of gold nanoparticles on silanated surfaces

• Htet H. Kyaw,
• Salim H. Al-Harthi,
• Azzouz Sellai and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2015, 6, 2345–2353, doi:10.3762/bjnano.6.242

• physical properties such as enthalpy, mechanical modulus, dielectric constant and specific volume [31]. The migration of AuNPs observed here was due to the changes in its physical properties. Upon annealing under vacuum, sample substrates reached to transition temperature, though due to the absence of