Beilstein J. Nanotechnol.2010,1, 142–154, doi:10.3762/bjnano.1.17
measurements, and each microcoil held 5–10 μl of sample. In the second-generation μNMR, we changed our design to solenoidal coils [15][16], as such geometry provides higher signal-to-noiseratio (SNR) by producing more homogeneous radio-frequency magnetic fields for sample excitation. The SNR could be further
factor, better signal-to-noiseratio, and reduced sample volume requirement to ~1 μL. (c) The latest 0.1 kg “palm” DMR system is 20× lighter and 30× smaller than previous generations. To achieve this significant size reduction, a small 0.56 T magnet was used. To compensate for the signal reduction from
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Figure 1:
DMR assay configurations with magnetic nanoparticles (MNPs). (a) Magnetic relaxation switching (MRS...
Beilstein J. Nanotechnol.2010,1, 24–47, doi:10.3762/bjnano.1.5
for the XPS spectra. For example, to arrive at a reasonable signal-to-noiseratio for the Co-2p peaks, a data acquisition time of 12 h is required. Even under UHV conditions such a long exposure of a sample surface to X-rays results in the built-up of a small amount of carbon contamination, which, by
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Scheme 1:
Preparation of NPs by a reverse micelle technique. PS-b-P2VP or PS-b-P4VP is dispersed in anhydrous...