Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• ], and/or carbon shells on the nanoparticle surface [7]. These carbon shells are either amorphous or graphitic [7][8][30], while doping of the shells [31] is also possible. Besides carbon formation, the choice of organic solvent influences the properties of the generated nanoparticles and process

• of gold in acetone did not lead to carbon shells, whereas the formation of carbon shells during the LAL of copper in acetone has been reported [35]. This observation was discussed to be linked to the catalytic activity of copper for C–C bond formation [53][54]. Accordingly, a stronger carbon

• formation is to be expected during the ablation of copper compared to gold and silver, which leads to a decreased polarity of the formed nanoparticles and potentially a higher affinity to less polar solvents. However, the base metals (iron, aluminum, and titanium) show a different behavior during LAL in

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• polyynes can be found in the recent review article by Marabotti and coworkers [64]. Solid carbon formation and nanoparticle surface modification While the oxidation of nanoparticles formed by LSPC can be attributed to redox reactions that result in water splitting [50][51], the mechanism for the carbon

Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone

• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Ni Luh Wulan Septiani and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61

• temperature of the high-HAB region (above 10 mm) is lower because of the relatively faster carbon formation process due to the abundance of carbon sources and the adequate temperature, specifically within the fuel stream flow. Contrarily, in the low-HAB region (below 9 mm), there is no growth within the fuel

Understanding the performance and mechanism of Mg-containing oxides as support catalysts in the thermal dry reforming of methane

• Nor Fazila Khairudin,
• Mohd Farid Fahmi Sukri,
• Mehrnoush Khavarian and
• Abdul Rahman Mohamed

Beilstein J. Nanotechnol. 2018, 9, 1162–1183, doi:10.3762/bjnano.9.108

• catalyst surface, which consequently facilitates high catalytic activity and low catalyst deactivation. The mechanism of DRM and carbon formation and reduction are reviewed. This work further explores how different constraints, such as the synthesis method, metal loading, pretreatment, and operating

• conditions, influence the dry reforming reactions and product yields. In this review, different strategies for enhancing catalytic activity and the effect of metal dispersion on Mg-containing oxide catalysts are highlighted. Keywords: carbon formation; catalyst development; dry reforming of methane

• , and Ir, exhibit high activity and resistance toward carbon formation [19][20][21]. However, these noble metals are associated with high cost and low availability, so non-noble metals, such as Ni [18][22][23][24], Fe [25][26][27][28], and Co [29][30] are most often used. Among the non-noble metals, Ni