Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• fibers, taking advantage of the high internal surface area of carbon fiber paper. The pulsed laser-grafted composites exhibited zero measurable charge transfer resistance between gold nanoparticles and the carbon support, leading to superior cathode performance over conventionally prepared electrodes for

• prepared cathode (Figure 6A). We attribute the superior performance of pulsed laser-grafted electrodes to the improved adhesion and electrical contact and concomitant absence of charge transfer resistance between the grafted gold nanoparticles and the carbon fiber paper support. Generated currents were

• normalized to the geometric area of the cathode and the mass of gold, which we obtained from digesting the electrodes in aqua regia and collecting inductively coupled plasma mass spectrometry data. We note that only gold was quantified, as carbon has a Z number that is too low for ICP-MS detection [68

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

• Hlib Lyshchuk,
• Atul Chaudhary,
• Thomas F. M. Luxford,
• Miloš Ranković,
• Jaroslav Kočišek,
• Juraj Fedor,
• Lisa McElwee-White and
• Pamir Nag

Beilstein J. Nanotechnol. 2024, 15, 797–807, doi:10.3762/bjnano.15.66

• beam is produced from a directly heated yttrium-coated iridium cathode, and a trochoidal electron monochromator is used to narrow down the electron energy distribution and to produce a quasi-monochromatic electron beam. A gas-phase effusive beam was produced by introducing the liquid Fe(CO)4MA sample

Comparative electron microscopy particle sizing of TiO₂ pigments: sample preparation and measurement

• Ralf Theissmann,
• Christopher Drury,
• Markus Rohe,
• Thomas Koch,
• Jochen Winkler and
• Petr Pikal

Beilstein J. Nanotechnol. 2024, 15, 317–332, doi:10.3762/bjnano.15.29

• , equipped with a LaB6 cathode, using the SE and STEM detectors, and VEGA3 control software version 4.2.26.0, build 1344. BET SSA measurement The SSA measurements of the E171 samples were originally performed according to an internal procedure inspired by the ISO 9277 standard as mentioned in [11]. To

CdSe/ZnS quantum dots as a booster in the active layer of distributed ternary organic photovoltaics

• Gabriela Lewińska,
• Piotr Jeleń,
• Zofia Kucia,
• Maciej Sitarz,
• Łukasz Walczak,
• Bartłomiej Szafraniak,
• Jerzy Sanetra and
• Konstanty W. Marszalek

Beilstein J. Nanotechnol. 2024, 15, 144–156, doi:10.3762/bjnano.15.14

• recombination, and increased charge transport. This was also demonstrated by Lv and co-workers [65]. The LUMO level of QD600 is lower than that of the donor P3HT, while the other QDs have higher LUMO levels. This difference in LUMO levels poses a challenge for the transportation of electrons to the cathode

In situ optical sub-wavelength thickness control of porous anodic aluminum oxide

• Aleksandrs Dutovs,
• Raimonds Popļausks,
• Oskars Putāns,
• Vladislavs Perkanuks,
• Aušrinė Jurkevičiūtė,
• Tomas Tamulevičius,
• Uldis Malinovskis,
• Iryna Olyshevets,
• Donats Erts and
• Juris Prikulis

Beilstein J. Nanotechnol. 2024, 15, 126–133, doi:10.3762/bjnano.15.12

• samples at constant 40 V potential. Platinum cathode and single crystal Al(100) (MTI Corp. mcALa101010) anode were immersed in 0.3 M oxalic acid electrolyte inside a multiwalled container with a transparent optical window. The container was placed on a magnetic stirrer and cooled to 5 °C. The reflectance

• other anodization voltages. The current flow through the Pt cathode could be established or interrupted automatically through a relay switch triggered by the thickness measurement software upon reaching the predefined threshold value. The anode current was monitored using a current-to-voltage (I/U

Nanoarchitectonics for advanced applications in energy, environment and biology: Method for everything in materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 738–740, doi:10.3762/bjnano.14.60

• also discuss coordination-assembled myricetin nanoarchitectonics [32], nanoarchitectonics for membranes with enhanced gas separation capabilities [33], nanoarchitectonics of the cathode of Li–O2 batteries [34], nanoarchitectonics in moist-electric generation [35], nanoarchitectonics for drug delivery

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• cost of PEMFCs depend on the materials used to construct their major components, which are anode, cathode, and polymer electrolyte membranes [3][6]. Therefore, supplying good-performance materials with controlled nanostructures to fuel cell technology is a crucial issue [7]. One solution to this

• commonly used catalyst in PEMFCs is platinum on various carbon support materials, which is used in both the anode and cathode because of its high catalytic activity toward the hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) [6][17][18][19][21][22][23][24][25]. Pt is also characterized

• dedicated to reducing the Pt loading at the cathode without performance loss of PEMFCs or to finding an alternative catalyst material [4][6][21]. The reduction of Pt loading on various carbon supports can be achieved by combining Pt with other metals [21] as well as by modifications of the various chemical

Antimicrobial and mechanical properties of functionalized textile by nanoarchitectured photoinduced Ag@polymer coating

• Jessica Plé,
• Marine Dabert,
• Helene Lecoq,
• Sophie Hellé,
• Lydie Ploux and
• Lavinia Balan

Beilstein J. Nanotechnol. 2023, 14, 95–109, doi:10.3762/bjnano.14.11

• measurements. A Bio photometer UV–vis spectrometer from Eppendorf was used to assess bacteria and yeast suspensions by OD measurements at 600 nm. Surface characterizations were carried out using transmission electron microscopy (TEM) at 200 kV on a Philips CM200 instrument (LaB6 cathode) and scanning electron

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• and reduction reactions at, respectively, the anode and cathode described by Equation 3 and Equation 4. Oxidation reaction at the anode: Reduction reaction at the cathode: Carrying out the reactions in a neutral medium also contributes to the increased durability of the electrodes. However, the lack

• of initial H+ concentration can reduce the efficiency of the H2 production. For an effective water splitting process, the oxidation reaction of OH− ions in the electrolyte needs to take place at the anode to generate e− and H+ ions along with O2. The e− current will immediately migrate to the cathode

• to perform reduction reactions. At that time, H+ will also be reduced at the cathode to form H2. The higher the efficiency of the oxidation reaction, the more e− are generated and the stronger the H+ reduction reaction will be. Preventing recombination of photo-generated e−–h+ pairs in the MoS2/TNAs

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• -electrode cell, including the photoanode and a Cu-based cathode. Hydrogen evolution at the cathode and the solar irradiance is recorded at 60 min intervals. The prepared photoelectrochemical electrode is wholly immersed in KOH electrolyte before each photoelectrochemical measurement. Only one electrode

• [46]. For the TiO2@MWCNTs nanocomposite, the TiO2 agglomerates attached to the MWCNTs are found to prevent the recombination of the h+/e− pairs and the H+/O− couples. Furthermore, excitons in the MWCNT structure can absorb visible-light irradiation and accordingly produce a sub-cathode current [8

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• the annealing temperature causes a steady decrease in the DC conductivity. Keywords: lithium cobalt oxide; lithium-ion battery; nanocrystalline powder; solution combustion synthesis; Introduction Lithium cobalt oxide (LiCoO2, LCO) of hexagonal structure () was first used as cathode material in

• lithium cells in 1979 by researchers from Oxford University [1]. The cell consisted of LCO, which was used as the cathode material, and metallic lithium, which was used as the anode material. In 1985, it was proposed to replace the Li metal in the negative electrode with the carbonaceous material graphite

• cathode and a graphite anode immersed in a lithium-ion conducting electrolyte, which is 1 M lithium hexafluorophosphate LiPF6 in a 1:1 (v/v) mixture of ethylene and dimethyl carbonate. Most commercial Li-ion cells are used to power portable devices, including mobile phones, laptops, and cameras [5][6][7

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• voltage to two spiral electrodes, the material between the electrodes generated a gradient of hydroxy groups through polarization. The cathode was reduced to generate more hydroxy groups; the anode was oxidized to generate more o-quinone structures. This asymmetry was demonstrated by the stronger hydrogen

• bonding near the cathode, measured by infrared spectroscopy (Figure 8f,g). Under moist conditions, a voltage signal could be measured in the gradient structure device, while the PDA film without polarization treatment did not produce an obvious voltage or current signal. This lateral gradient

• electrodes for (1) the anode and (2) the cathode. (f) Infrared spectra of g-PDA near (1) the anode and (2) the cathode. (g) High-resolution C 1s spectra of the g-PDA film for (1) the anode and (2) the cathode. Figure 8e–g were reprinted with permission from [84], Copyright 2019 American Chemical Society

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• AgCuCo (0.6:1.5:1.5, 2:1:1, and 6:1:1) oxide NPs supported on a reduced graphene oxide (rGO) matrix. Morphology, composition, and functional groups were methodically analysed using various microscopic and spectroscopic techniques. The as-prepared electrocatalysts were employed as cathode substrates for

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• single crystals could also serve as templates to derive microporous CoSe2@C, which was used as cathode for aluminum-ion batteries [119]. The connected macropores could facilitate the diffusion of large chloroaluminate anions and provide more exposed active sites, thus, showing excellent rate capacity

Nanoarchitectonics of the cathode to improve the reversibility of Li–O₂ batteries

• Hien Thi Thu Pham,
• Jonghyeok Yun,
• So Yeun Kim,
• Sang A Han,
• Jung Ho Kim,
• Jong-Won Lee and
• Min-Sik Park

Beilstein J. Nanotechnol. 2022, 13, 689–698, doi:10.3762/bjnano.13.61

• Institute for Innovative Materials, University of Wollongong, Squires Way, North Wollongong, NSW 2500, Australia 10.3762/bjnano.13.61 Abstract The strategic design of the cathode is a critical feature for high-performance and long-lasting reversibility of an energy storage system. In particular, the round

• electrical conductivity further, ultimately leading to better electrochemical stability in the cathode. As a result, the optimized bimetallic ZIF–carbon/CNT composite exhibits a high discharge capacity of 16,000 mAh·g−1, with a stable cycling performance of up to 137 cycles. This feature is also beneficial

• for lowering the overpotential of the cathode during cycling, even at the high current density of 2,000 mA·g−1. Keywords: cathode composition; electrochemistry; Li–O2 battery; metal–organic framework; nanoarchitectonics; zeolitic imidazolate framework; Introduction Recently, lithium–oxygen batteries

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• and respectable efficiency [1]. This promising third generation of solar cells contains a dye-adsorbed TiO2 photoanode, an iodide/triiodide electrolyte, and a platinum-based cathode, also known as the counter electrode (CE). However, the high cost of platinum has prevented the real-world application of

• DSSCs, which has led researchers to explore efficient cathode materials for DSSCs beyond platinum. To date, Pt replacement materials are divided into three categories, namely carbonaceous materials [2][3][4][5], conductive polymers [5], and transition metal compounds [6][7][8]. Transition metal

• /cathode peak potentials (EpOx1, EpRed1), peak-to-peak voltage separation (Epp), and anode/cathode peak current densities (JOx1, JRed1) were calculated and presented in Table 1. The Epp value for MoS2 CEs was slightly larger than that of Pt CE confirming their excellent electrocatalytic activity. The JRed1

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• protection based on GR NEM switch structures can be integrated into the back end of the substrate, as shown in Figure 7. The anode and cathode of the switches are connected to input/output pads and ground pad on a chip, respectively. When electrostatic discharge occurs, the suspended graphene will be pulled

The effect of metal surface nanomorphology on the output performance of a TENG

• Yiru Wang,
• Xin Zhao,
• Yang Liu and
• Wenjun Zhou

Beilstein J. Nanotechnol. 2022, 13, 298–312, doi:10.3762/bjnano.13.25

• during electrodeposition. The sample after electrodeposition was dried in a Geruida GRD220H oven. After obtaining 16 groups of experimental samples, PTFE (purchased from Bukraun) was used as the anode, and the experimental sample was used as the cathode to fabricate the TENGs. The open-circuit voltage

• the electrolyte. The deposition area was set to 9 cm2 by adjusting the position of the anode copper sheet and the cathode copper sheet immersed in the electrolyte. The distance between the anode and cathode plates was fixed at 5 cm to avoid the impact of plate spacing on the nanomorphology of the

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• , the cathode of the system. A typical vacuum chamber used for coating deposition by sputtering is presented in Figure 3a where the key elements are presented: the negatively biased cathode covered by the target, that is, the source of atoms, the sample to be coated, the pumping system, the pressure

• limited number of variable parameters. Customized vacuum chambers dedicated to the detailed study and development of this particular type of PVD process are also available in research laboratories. Sputtering has become industry-relevant since permanent magnets were set inside the cathode body, underneath

• the target, to generate a magnetic field in the target vicinity thus promoting magnetron sputtering (MS) cathode systems. Typical MS cathodes consist of a magnet placed at the center of the target and magnets with opposite poles on the target periphery. This configuration is schematically presented in

The effect of cobalt on morphology, structure, and ORR activity of electrospun carbon fibre mats in aqueous alkaline environments

• Markus Gehring,
• Tobias Kutsch,
• Osmane Camara,
• Alexandre Merlen,
• Hermann Tempel,
• Hans Kungl and
• Rüdiger-A. Eichel

Beilstein J. Nanotechnol. 2021, 12, 1173–1186, doi:10.3762/bjnano.12.87

• overall performance [3]. The lack of discharge performance is attributed to the sluggish kinetics of the oxygen reduction reaction (ORR) at the air cathode [4], which reduces the practical power density. Further improvements of the cathode are essential for the long-term success of metal–air batteries

• , especially the lithium and silicon systems, on account of their different mechanism involving the cathode as an explicit reaction site of the metal redox chemistry [7][8][9]. From a scientific point of view, in aqueous systems, an air electrode needs to allow gas to diffuse in appropriate amounts towards the

• ). The open-circuit potential is an indicator for the cell potential of a full cell system. In the ORR case, a higher potential is sought for the air cathode, to increase the overall cell potential. The current density of the system is of relevance to the desired application in terms of available power

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• as the emissive layer (EML), the hole transport layers (HTL), the electron transport layers (ETL), the cathode, and the anode [17][18][19][20][21]. Enhancement in LED properties via surface plasmon resonance (SPR) of metal nanoparticles (MNP) such as Au and Ag have also been reported [22][23]. This

• , EML, ETL, and cathode) is analyzed. Subsequently, various characteristics of LED containing carbon nanostructures and plasmonic NP are discussed in terms of EQE, internal quantum efficiency, luminance, EL, and current–voltage (I–V) characteristics. A list of various abbreviations employed in this

• should be injected from the low-work-function metal cathode surface. Therefore, HTL should possess excellent charge mobility and maintain morphological stability. Moreover, it should have an appropriate highest occupied molecular level (HOMO), ensuring a low energy barrier for hole injection from the

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• , Na dendrite growth, and slow reaction kinetics by nanostructuring both the sulfur cathode and the Na anode. Moreover, a survey of recent patents on room temperature (RT) Na–S batteries revealed that nanostructured sulfur and sodium electrodes are still in the minority, which suggests that much

• available anode and cathode materials are sought. Table 1 lists some abundant metals as anode materials with high capacity and reduction potential values that are explored in metal-ion batteries [7][8][9]. Besides sodium as alternative anode material, also sulfur as abundant cathode material has emerged due

• batteries. As a result of scientific investigations and technological innovations, room-temperature sodium–sulfur (RT Na–S) batteries have been gaining importance since the mid-2000s [3][10][14]. A lot of effort is focused on the development of different cathode materials in order to produce commercial high

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• surface coating with nanoparticles through electrodeposition. A general electrodeposition setup consists of three electrodes, that is cathode, anode, and a reference electrode [78]. The solvation property and the conductivity of DESs also play a critical role in determining the physical structure, yield

Electromigration-induced formation of percolating adsorbate islands during condensation from the gaseous phase: a computational study

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2021, 12, 694–703, doi:10.3762/bjnano.12.55

• neighboring vacancies in the direction of electron flow leading to an accumulation of atoms at the anode and vacancies at the cathode [1][2]. Current trends in computer technology, namely, reducing the size of integrated circuits, increasing their power, and increasing the density of elements, have led to an

• between anode and cathode); e is the electron charge. The direction of the force Fel is defined by the effective valence Z, which is negative for most metals. Thus, the adsorbed atoms move in the opposite direction to the electric field. In the general case if the electric field is applied across the

• induced by an electric field: ±kem∇xx(r), where it is taken into account that the electric field is directed along the direction x, and the sign ± is determined by the relative position of the cathode and anode. The rate of directed motion kem is proportional to the strength E of the electric field. A