Beilstein J. Nanotechnol.2015,6, 1065–1071, doi:10.3762/bjnano.6.107
voltammetry; FOX assay; fulleropeptideesters; scanning electron microscopy; Introduction
Their highly π-conjugated, spherically shaped, hydrophobic character and their unique physicochemical, electronic and magnetic properties make fullerenes attractive building blocks for chemical modifications, providing
essential antioxidant capacity, which is mainly attributed to the electron-accepting properties of the fullerene unit.
The self-assembly characteristics of fulleropeptideesters 2–12 were studied by SEM on the samples prepared by a drop–drying process [2] and on the solid samples. In order to examine the
, Figure 3F). Additionally, SEM micrographs (Supporting Information File 1, Figure S1, insets) have clearly revealed network-like structures of three fulleropeptideesters, 9, 11, and 12, obtained at this concentration, indicating the morphology dependence of the investigated compounds on the peptide
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Figure 1:
Structures of studied fullereropyrrolidinic (Fp) ester 1 [24] and Fp–peptides 2–12 [27].