Synthesis of a multicomponent cellulose-based adsorbent for tetracycline removal from aquaculture water

• Uyen Bao Tran,
• Ngoc Thanh Vo-Tran,
• Khai The Truong,
• Dat Anh Nguyen,
• Quang Nhat Tran,
• Huu-Quang Nguyen,
• Jaebeom Lee and
• Hai Son Truong-Lam

Beilstein J. Nanotechnol. 2025, 16, 728–739, doi:10.3762/bjnano.16.56

• . For instance, carboxymethyl cellulose (CMC), an anionic derivative of cellulose, is a linear polysaccharide consisting of anhydroglucose units linked by β-1,4-glycosidic bonds. The key distinction between CMC and cellulose is that some hydroxy groups in cellulose are replaced by carboxymethyl

• + ions and TC for adsorption sites, along with the ionization of hydroxy groups and the subsequent formation of hydrogen bonds with TC molecules, results in a rapid increase in adsorption capacity. Beyond pH 7, adsorption capacity decreases sharply as TC transforms into negatively charged anions, causing

• + complex and the negatively charged PGC material drives the adsorption process. Additionally, hydroxy groups may facilitate hydrogen bond formation between PGC and TC (Figure 6c). Furthermore, the aromatic ring of TC contains conjugated double bonds, while the hexagonal network of PGC contains ‒CH groups

Colloidal few layered graphene–tannic acid preserves the biocompatibility of periodontal ligament cells

• Teissir Ben Ammar,
• Naji Kharouf,
• Dominique Vautier,
• Housseinou Ba,
• Nivedita Sudheer,
• Philippe Lavalle and
• Vincent Ball

Beilstein J. Nanotechnol. 2025, 16, 664–677, doi:10.3762/bjnano.16.51

• , characterized by numerous hydroxy groups, is proposed to potentially form non-covalent interactions, such as π–π stacking, with the carbon network and oxygen atoms of graphite [16][20]. This interaction could exfoliate graphite, resulting in a stable colloidal dispersion of functionalized graphene sheets. The

• , rising from 0.17 in graphite to 0.45 in the FLG–TA material. In addition, the high-resolution C 1s and O 1s spectra of the FLG–TA composite show the presence of carbonyl, ether, and hydroxy groups (Figure 2C,D). The percentage of those moieties in the FLG–TA material increases significantly with respect

• capabilities through multiple mechanisms, namely, electron transfer, where hydroxy groups donate electrons to neutralize free radicals, and hydrogen atom transfer, where hydrogen atoms from hydroxy groups are donated to stabilize ROS [17][34]. This retained antioxidant activity could play a crucial role in

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• Au nanoparticles by LRL. On the other hand, the synthesis efficiency is even higher with glycerin. While IPA and ethanol are monovalent alcohols with a single hydroxy group, glycerin is a trivalent alcohol with three hydroxy groups. Therefore, we speculate that glycerin was able to more efficiently

Enhancing mechanical properties of chitosan/PVA electrospun nanofibers: a comprehensive review

• Nur Areisman Mohd Salleh,
• Amalina Muhammad Afifi,
• Fathiah Mohamed Zuki and
• Hanna Sofia SalehHudin

Beilstein J. Nanotechnol. 2025, 16, 286–307, doi:10.3762/bjnano.16.22

• . This process leads to a decrease in the number of hydroxy groups present on the PVA chain, resulting in the release of water molecules. Simultaneously, the remaining hydroxy groups facilitate the formation of intramolecular hydrogen bonds. Additionally, intermolecular hydrogen bonds can form between

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• -G-PEG6000-FA exhibit another novel band at 1728 and 1732 cm−1, respectively, resulting probably from C=O stretching vibrations of the ester RCOOR′ group formed between the carboxyl groups of FA and hydroxy groups of PEG6000. The bands at 1423 cm−1 in the spectrum of MWCNTs-PEG6000-FA and at 1428 cm

Synthesis and the impact of hydroxyapatite nanoparticles on the viability and activity of rhizobacteria

• Bedah Rupaedah,
• Indrika Novella,
• Atiek Rostika Noviyanti,
• Diana Rakhmawaty Eddy,
• Anna Safarrida,
• Abdul Hapid,
• Zhafira Amila Haqqa,
• Suryana Suryana,
• Irwan Kurnia and
• Fathiyah Inayatirrahmi

Beilstein J. Nanotechnol. 2025, 16, 216–228, doi:10.3762/bjnano.16.17

• state. Rhizobacteria demonstrate their ability to create transparent zones on Pikovskaya media because of their capability for phosphate solubilization. These microorganisms produce organic acids, such as citric acid and oxalic acid, which bind to phosphate via hydroxy groups and chelating cations such

TiO₂ immobilized on 2D mordenite: effect of hydrolysis conditions on structural, textural, and optical characteristics of the nanocomposites

• Marina G. Shelyapina,
• Rosario Isidro Yocupicio-Gaxiola,
• Gleb A. Valkovsky and
• Vitalii Petranovskii

Beilstein J. Nanotechnol. 2025, 16, 128–140, doi:10.3762/bjnano.16.12

• , even at temperatures above 300 °C, all samples exhibit a small peak in the DTG curves at about 400 °C, which can be attributed either to water molecules trapped in hardly accessible voids or, more probably, to a removal of specific hydroxy groups [34]. Moreover, all samples except Ti-W4h-C show a

• linear mass loss starting from 300 °C that is not reflected by DTG and can be attributed to progressive dehydroxylation (for hydroxy groups with a significant inhomogeneity) [41]. For the sample Ti-W12h-C, this effect is most pronounced and corresponds to about 7.6% of the total mass loss. The total mass

• Δw1′ and the amount of hydroxy groups, Δw2′. This points out to a strong interaction of nanoconfined water with hydroxy groups on the inner surface of mesopores, a part of which formed upon calcination [6]. Moreover, the samples obtained in 70% ethanol solution may exhibit different hydrophilic

Bioinspired nanofilament coatings for scale reduction on steel

• Siad Dahir Ali,
• Mette Heidemann Rasmussen,
• Jacopo Catalano,
• Christian Husum Frederiksen and
• Tobias Weidner

Beilstein J. Nanotechnol. 2025, 16, 25–34, doi:10.3762/bjnano.16.3

• on materials with surface chemistries with polar functional groups and particularly hydroxy groups. To coat surfaces with a layer of SNFs, samples are immersed in a solution of trichloromethylsilane (TCMS) in toluene, in the presence of trace amounts of water (see Materials Section for details

A nanocarrier containing carboxylic and histamine groups with dual action: acetylcholine hydrolysis and antidote atropine delivery

• Elina E. Mansurova,
• Andrey A. Maslennikov,
• Anna P. Lyubina,
• Alexandra D. Voloshina,
• Irek R. Nizameev,
• Marsil K. Kadirov,
• Anzhela A. Mikhailova,
• Polina V. Mikshina,
• Albina Y. Ziganshina and
• Igor S. Antipin

Beilstein J. Nanotechnol. 2025, 16, 11–24, doi:10.3762/bjnano.16.2

• resorcinarenes containing carboxylic, imidazole, and hydroxy groups on the upper rim. Similar to the esterase triad, these groups are essential for the hydrolysis of ACh [28]. Throug hydrolysis, ACh dissociates into choline (Ch) and acetic acid (AcOH). The generated AcOH breaks the boronate bonds and

Heterogeneous reactions in a HFCVD reactor: simulation using a 2D model

• Xochitl Aleyda Morán Martínez,
• José Alberto Luna López,
• Zaira Jocelyn Hernández Simón,
• Gabriel Omar Mendoza Conde,
• José Álvaro David Hernández de Luz and
• Godofredo García Salgado

Beilstein J. Nanotechnol. 2024, 15, 1627–1638, doi:10.3762/bjnano.15.128

• and surface hydroxy groups, which leads to deposition. They are also responsible for the incorporation of Si–OH bonds into the silicon oxide matrix. The •H and •OH species attack unsaturated surface species with dangling bonds. Oxidation of surface hydrogens is the predominant reaction for O to

Green synthesis of carbon dot structures from Rheum Ribes and Schottky diode fabrication

• Muhammed Taha Durmus and
• Ebru Bozkurt

Beilstein J. Nanotechnol. 2024, 15, 1369–1375, doi:10.3762/bjnano.15.110

• that the prepared CDs exhibited comparable amounts of the two carbon species [19]. In addition, the surface charge of the CDs was found to be −5.77 mV by zeta potential measurements. This value shows that there are more negatively charged carboxyl and hydroxy groups on the surface of the CDs than

Interaction of graphene oxide with tannic acid: computational modeling and toxicity mitigation in C. elegans

• Romana Petry,
• James M. de Almeida,
• Francine Côa,
• Felipe Crasto de Lima,
• Diego Stéfani T. Martinez and
• Adalberto Fazzio

Beilstein J. Nanotechnol. 2024, 15, 1297–1311, doi:10.3762/bjnano.15.105

• processes is missing. Tannic acid (TA) is an environmentally abundant and commercially available polyphenol with relevant industrial and technological applications [17][18][19][20]. TA’s structure comprises five digallic acid units ester-linked to a glucose core. These pyrogallol hydroxy groups participate

• defects, one of the armchair edges presents hydroxy groups and one of the zigzag edges presents a broken epoxy site. Figure 3 presents the dynamics of a representative configuration of TA interacting with GO flake. Comparing the evolution of the TA’s configurations in the different simulations, the

Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties

• Cristina Maria Vlăduț,
• Crina Anastasescu,
• Silviu Preda,
• Oana Catalina Mocioiu,
• Simona Petrescu,
• Jeanina Pandele-Cusu,
• Dana Culita,
• Veronica Bratan,
• Ioan Balint and
• Maria Zaharescu

Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104

• powders, leading to a mass loss of roughly 35% for SG and 40% for MW. This process is exothermic and observed around 309 °C. During the third phase, between 350 and 500 °C, structural hydroxy groups are removed, and any remaining organic material is burned off, resulting in a mass loss of approximately 11

• crystallization, consistent with the results from XRD and SEM analyses. Additionally, bands at 3437 and 1613 cm−1 correspond to the vibrational modes of hydroxy groups (OH) bonded to the surface of the ZnO powders. X-ray diffraction The crystalline structure of the samples thermally treated at 500 °C was analyzed

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• modified alginate materials for mucoadhesive drug delivery. Scientists combined the alginate hydroxy groups with maleimid-terminated PEG. This novel mucoadhesive biopolymer exhibited polymer–mucus glycoprotein interactions. The results showed that the new alginate-based mucoadhesive matrix can enhance the

• alginate present, PABA covalently attached to the hydroxy groups of alginates to form a PABA-SA semi-interpenetrating network on which AgNPs were concurrently deposited (Figure 5). As a result, very stable polymer-based AgNPs were formed. The Ag@PABA-SA nanogel was tested as a colorimetric probe for

Radiofrequency enhances drug release from responsive nanoflowers for hepatocellular carcinoma therapy

• Yanyan Wen,
• Ningning Song,
• Yueyou Peng,
• Weiwei Wu,
• Qixiong Lin,
• Minjie Cui,
• Rongrong Li,
• Qiufeng Yu,
• Sixue Wu,
• Yongkang Liang,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2024, 15, 569–579, doi:10.3762/bjnano.15.49

• above suspension for 3 min. The resulting mixture was subsequently sonicated for 4 h. Under the effect of TEA, the hydroxy groups on CUR and HPS became activated and replaced the chlorine atoms on HCCP, which led to the coassembly of the coating structure on the surface of Fe3O4 NCs. The generated CUR

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• nanomaterials with more hydroxy groups in the stoichiometric composition generally tend to exhibit higher CAT activity because hydroxy groups enhance ion exchange on the surface of nanomaterials by providing active sites [35][36]. The CAT-like activity was also investigated in copper-based nanomaterials by

Fluorescent bioinspired albumin/polydopamine nanoparticles and their interactions with Escherichia coli cells

• Eloïse Equy,
• Jordana Hirtzel,
• Sophie Hellé,
• Béatrice Heurtault,
• Eric Mathieu,
• Morgane Rabineau,
• Vincent Ball and
• Lydie Ploux

Beilstein J. Nanotechnol. 2023, 14, 1208–1224, doi:10.3762/bjnano.14.100

• KE diad (e.g., catestatin) [13]. During the formation process, hydroxy groups of dopamine form hydrogen bonds with carboxylic groups (COO−) of glutamate (pKa = 4.3), whereas protonated amino groups (NH3+) of lysine (pKa = 10.5) further stabilize the aggregate by cation–π interactions with the

• oxidation (Supporting Information File 1, Figure S2c). This may result from the conjugation and electronic density changes induced during the reaction with H2O2, during which hydroxy groups were oxidized into ketones. Eventually, the large majority of polydopamine functional groups are expected to be

• ketones with only a few remaining of hydroxy groups (Supporting Information File 1, Figure S2a). In addition, labelling of pristine BSA/PDA NPs with FITC and RhBITC dyes led to an obvious change in color of the suspension, from brown (Supporting Information File 1, Figure S3a) to yellow and red

Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity

• Nguyen Thi Thanh Tu,
• T. Lan-Anh Vo,
• T. Thu-Trang Ho,
• Kim-Phuong T. Dang,
• Van-Dung Le,
• Phan Nhat Minh,
• Chi-Hien Dang,
• Vinh-Thien Tran,
• Van-Su Dang,
• Tran Thi Kim Chi,
• Hieu Vu-Quang,
• Radek Fajgar,
• Thi-Lan-Huong Nguyen,
• Van-Dat Doan and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64

• have shown significant improvement in stabilization because of the hydroxy groups in the sugar molecules of the polysaccharide chain, which can form strong associations with AgNPs [13][14][15]. Previous studies have reported that metallic nanoparticles can be easily incorporated into polysaccharides by

Carboxylic acids and light interact to affect nanoceria stability and dissolution in acidic aqueous environments

• Matthew L. Hancock,
• Eric A. Grulke and
• Robert A. Yokel

Beilstein J. Nanotechnol. 2023, 14, 762–780, doi:10.3762/bjnano.14.63

• molecular configurations required for nanoceria complexation. The remaining three acids (glyceric, lactic, and α-hydroxybutyric acid) do not contain a second carboxylic acid group. Furthermore, citric, malic, and isocitric acid molecules all have higher ratios of carboxylic acid and hydroxy groups to

• rate than any other acid in the dark. TEM imaging of nanoceria in citric and β-hydroxybutyric acid supported the DLS results. Relating the carboxylic acid composition (number of carboxylic acid groups, total number of carbons, aliphatic carbons, and hydroxy groups and their molecular ratios) to the

• influence nanoceria agglomeration, the number of carboxylic acid groups and total number of carbons, aliphatic carbons, and hydroxy groups in each carboxylic acid were counted. The molecular ratios of the number of carboxylic acid groups to the total number of carbons and aliphatic carbons, and of the

Humidity-dependent electrical performance of CuO nanowire networks studied by electrochemical impedance spectroscopy

• Jelena Kosmaca,
• Juris Katkevics,
• Jana Andzane,
• Raitis Sondors,
• Liga Jasulaneca,
• Raimonds Meija,
• Kiryl Niherysh,
• Yelyzaveta Rublova and
• Donats Erts

Beilstein J. Nanotechnol. 2023, 14, 683–691, doi:10.3762/bjnano.14.54

• with the adsorbed oxygen and Cu sites on the surface also neutralize holes: [30]. Hence, the impedance can increase with increasing RH (up to about 50% in our system) because of the affected electronic transport inside the material. Simultaneously, as the hydroxy groups begin to form clusters on the

• physisorption of the second layer, that is, H2O molecules forming hydrogen bonds with the hydroxy groups [23][29][32]. This enables the formation of H+ and H3O+ ions, for example, when a proton is transferred from a hydroxy group to a water molecule [33]. A further increase of humidity up to ca. 90% causes the

ZnO-decorated SiC@C hybrids with strong electromagnetic absorption

• Liqun Duan,
• Zhiqian Yang,
• Yilu Xia,
• Xiaoqing Dai,
• Jian’an Wu and
• Minqian Sun

Beilstein J. Nanotechnol. 2023, 14, 565–573, doi:10.3762/bjnano.14.47

• graphene) may be easier because of the abundance of oxygen functional groups (e.g., carboxyl or hydroxy groups) on the carbon surface [26][31][32], in comparison to pure SiC. The introduction of carbon may help to further adjust the electromagnetic parameters and performance of SiC@ZnO nanocomposites

• amorphous state (Figure 2e). The carbon shell may have a positive effect on the nucleation of ZnO particles. This is because oxygen-containing functional groups (such as carboxyl and hydroxy groups) and structural defects are generated on the SiC@C surface during the in situ carbonization [24], which both

• hybrids can be adjusted by changing the dosage of ZnNO3·6H2O. The amorphous carbon shell has a significant effect on the nucleation of crystalline ZnO particles, possibly due to oxygen-containing functional groups (such as carboxyl and hydroxy groups) and defects on the SiC@C surface, which both provide

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

• Polina M. Kalachikova,
• Anastasia E. Goldt,
• Eldar M. Khabushev,
• Timofei V. Eremin,
• Timofei S. Zatsepin,
• Elena D. Obraztsova,
• Konstantin V. Larionov,
• Liubov Yu. Antipina,
• Pavel B. Sorokin and
• Albert G. Nasibulin

Beilstein J. Nanotechnol. 2022, 13, 1564–1571, doi:10.3762/bjnano.13.130

• SWCNTs occurs due to the adsorption of π-conjugated isoalloxazine moieties on the surface of small-diameter nanotubes and interactions between hydroxy groups of ribityl chains with water. During the SWCNT extraction, specific adsorption of riboflavin to SWCNTs leads to the minimization of interactions

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• , in which the TiO2 particles are uniformly attached to CNTs by layer-by-layer coating or sol–gel methods [15][16][17]. Notably, the defects on the wall surface of MWCNTs, which enable π–π interactions, could be the active sites to generate the TiO2 agglomerations via hydroxy groups and, thus, enhance

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• . 1-TNA and 3-MPEA may induce the SA peptide chain to stretch and the aromatic heterocyclic hydrophobic groups of Trp residues and Tyr residues to be exposed, which weaken hydrophobic interactions and strengthen n–π* and π–π* interactions. For 2-OT and MEL cases, their hydroxy groups (−OH) may form

• QCM electrodes for chiral sensing. Cyclodextrin derivatives. Cyclodextrins (CDs) are a class of oligomers composed of glucose units. They possess hollow truncated cones with a lipophilic inner cavity and a hydrophilic edge. The hydroxy groups at the edge can undergo different chemical reactions, which

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• the fraction of hydroxy groups on the output power. The was a generally positive correlation. However, an excess of hydroxy group content as shown in Figure 7f may affect the stability of the nanostructure and lead to the collapse of the structure. Cellulose materials have great application potential

• voltage to two spiral electrodes, the material between the electrodes generated a gradient of hydroxy groups through polarization. The cathode was reduced to generate more hydroxy groups; the anode was oxidized to generate more o-quinone structures. This asymmetry was demonstrated by the stronger hydrogen