Beilstein J. Nanotechnol.2025,16, 155–186, doi:10.3762/bjnano.16.14
the gas separation potential of MOF-based MMMs in CO2 capture applications are highlighted.
Keywords: CO2 capture; gas separation; inorganicfiller; metal-organic framework (MOF); mixed matrix membrane (MMM); Review
1 Introduction
The continuous rise in global CO2 emissions has unfolded an era of
inorganic additive can be integrated into an organic polymer membrane simply by mixing the inorganic particles with a membrane solution of the specific polymer. This composite solution is then cast to obtain the membrane. However, the general limitation of most inorganicfiller-based MMMs is the
compatibility between the inorganicfiller and the organic membrane. Typically, the organic polymer membrane exhibits low affinity towards the inorganicfiller. Accordingly, this severely limits the potential range of the different workable composites [84]. Therefore, large efforts have been made to identify
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Figure 1:
Overview of subtopics covered in this review for the key research areas related to MOF-based MMMs f...
Beilstein J. Nanotechnol.2018,9, 2999–3012, doi:10.3762/bjnano.9.279
filler. For instance, although the inorganicfiller usually displays higher permittivity values than the polymer, the resulting nanofiller mixture in the matrix presents, at low nanofiller concentrations, a surprisingly lower dielectric constant than that of the two mixture components [10][11][12][13
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Figure 1:
Interphase detection, approach 1: schematic representation of the samples to be compared, and metho...