Ion-induced surface reactions and deposition from Pt(CO)₂Cl₂ and Pt(CO)₂Br₂

• Mohammed K. Abdel-Rahman,
• Patrick M. Eckhert,
• Atul Chaudhary,
• Johnathon M. Johnson,
• Jo-Chi Yu,
• Lisa McElwee-White and
• D. Howard Fairbrother

Beilstein J. Nanotechnol. 2024, 15, 1427–1439, doi:10.3762/bjnano.15.115

• transfer from the incident ion to adsorbed precursor molecules. This precursor decomposition step is accompanied by a decrease in the oxidation state of the Pt(II) atoms and, in IBID, represents the elementary reaction step that converts the molecular precursor into an involatile PtX2 species. Upon further

• more heterogeneous local environment as the deposit forms from the molecular precursor, although the invariant peak position indicates that there is little change in the average chemical environment surrounding the halogen atoms. Since the loss of CO from all of the Pt(CO)2X2 films can be described by

Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• molecular precursor C2H4 (purity: 99.9%) at a partial pressure of 10−5 Pa for 120 s [25][26]. Atomic-scale defects were created by bombarding graphene-covered Ir(111) with low-energy (140 eV) Ar+ ions (purity of the Ar gas: 99.999%) [27][28][29][30] at room temperature for 5 s followed by annealing (900 K

Molecular nanoarchitectonics: unification of nanotechnology and molecular/materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 434–453, doi:10.3762/bjnano.14.35

• -workers used 1,4,5,8-tetrabromonaphthalene as a molecular precursor and sequential dehalogenation reactions under mild conditions to synthesize very thin (five carbon atoms wide) armchair graphene nanoribbons on a Au(111) surface [122]. The spatial distribution of the electronic structure and other

High-responsivity hybrid α-Ag₂S/Si photodetector prepared by pulsed laser ablation in liquid

• Raid A. Ismail,
• Hanan A. Rawdhan and
• Duha S. Ahmed

Beilstein J. Nanotechnol. 2020, 11, 1596–1607, doi:10.3762/bjnano.11.142

• bromide (CTAB) surfactant-assisted hydrothermal method [15]. Zhang et al. synthesized monodisperse Ag2S NPs using thermolysis of harmless silver xanthates as a single-source molecular precursor and controlled the particle size by changing the alkyl chain length in the precursors [16]. Recently, Kang et al

Scanning tunneling microscopy and spectroscopy of rubrene on clean and graphene-covered metal surfaces

• Karl Rothe,
• Alexander Mehler,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2020, 11, 1157–1167, doi:10.3762/bjnano.11.100

• Pt(111) by exposing the heated (1300 K) surface to the molecular precursor C2H4 (purity 99.9%) at a partial pressure of 10−4 Pa for 120 s [23]. C42H28 molecules were sublimated from a powder (purity 98%), deposited in a heated (500 K) W crucible and directed towards the sample surface at room

Gram-scale synthesis of splat-shaped Ag–TiO₂ nanocomposites for enhanced antimicrobial properties

• Mohammad Jaber,
• Asim Mushtaq,
• Kebiao Zhang,
• Jindan Wu,
• Dandan Luo,
• Zihan Yi,
• M. Zubair Iqbal and
• Xiangdong Kong

Beilstein J. Nanotechnol. 2020, 11, 1119–1125, doi:10.3762/bjnano.11.96

• , magnetron sputtering, molecular precursor techniques and photo-deposition techniques have been applied to the preparation of nanocomposites [6][21][22]. However, these techniques are very sophisticated and not optimized for synthesis on a large scale. Herein, a simple hydrothermal process was employed to

Nanoporous water oxidation electrodes with a low loading of laser-deposited Ru/C exhibit enhanced corrosion stability

• Sandra Haschke,
• Dmitrii Pankin,
• Vladimir Mikhailovskii,
• Maïssa K. S. Barr,
• Adriana Both-Engel,
• Alina Manshina and
• Julien Bachmann

Beilstein J. Nanotechnol. 2019, 10, 157–167, doi:10.3762/bjnano.10.15

• −1 can be attributed to hydrous ruthenium oxide (RuO2∙nH2O) [47][48][49][50][51], whereby an overlap with Ru–C stretching modes cannot be excluded (see also the signal generated by the molecular precursor, Figure 7b). The 313 cm−1 peak originates from metallic Ru [52][53][54][55]. In the high

• ]. Importantly, the absence of carbonyl stretching vibrations around 1950–2190 cm−1 rules out any remnants of molecular precursor Ru3(CO)12 (Figure 7b [52][62]). X-ray photoelectron spectroscopy (XPS, Figure 8) is used to differentiate between the oxidation states of ruthenium at its surface and in its inner

Electron interactions with the heteronuclear carbonyl precursor H₂FeRu₃(CO)₁₃ and comparison with HFeCo₃(CO)₁₂: from fundamental gas phase and surface science studies to focused electron beam induced deposition

• Ragesh Kumar T P,
• Paul Weirich,
• Lukas Hrachowina,
• Marc Hanefeld,
• Ragnar Bjornsson,
• Helgi Rafn Hrodmarsson,
• Sven Barth,
• D. Howard Fairbrother,
• Michael Huth and
• Oddur Ingólfsson

Beilstein J. Nanotechnol. 2018, 9, 555–579, doi:10.3762/bjnano.9.53

• formation. Two- and three-dimensional structures of FEBID-derived magnetic nanostructures have been prepared, [16][53][56][57][69][70][71] but alternative precursors are desired to predefine different compositions and increase spatial resolution of deposits. The structures of molecular precursor species are

The role of ligands in coinage-metal nanoparticles for electronics

• Ioannis Kanelidis and
• Tobias Kraus

Beilstein J. Nanotechnol. 2017, 8, 2625–2639, doi:10.3762/bjnano.8.263

• depending on their binding affinity on different facets. They cover the nuclei as they form from the molecular precursor and prevent their aggregation [63]. Once the nuclei have grown into structurally well-defined seeds, the ligands can lead to preferential capping, hindering or promoting the growth of

A single-source precursor route to anisotropic halogen-doped zinc oxide particles as a promising candidate for new transparent conducting oxide materials

• Daniela Lehr,
• Markus R. Wagner,
• Johanna Flock,
• Julian S. Reparaz,
• Clivia M. Sotomayor Torres,
• Alexander Klaiber,
• Thomas Dekorsy and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2015, 6, 2161–2172, doi:10.3762/bjnano.6.222

• selected-area energy dispersive X-ray spectroscopy (EDX) (Figure 2b) and X-ray photoelectron spectroscopy (Figure 2c). The maximum concentration of Cl in the ZnO lattice we could reach via this method is 3.6 atom % (≡ZnO0.964Cl0.036). The low chlorine values compared to the molecular precursor shows that

• growth rate could be confirmed by preparing a series of ZnO1−xClx samples differing systematically in chlorine content. The materials were prepared from molecular precursor mixtures of [EtZnOiPr]4 and [ClEt3Zn4(OiPr)4], the required doping concentration was adjusted via the precursor composition (see

• )2Zn4(Ot-Bu)4]+ (m/z = 710.9). (a) TGA traces (black) and its first derivative (grey) of the thermal decomposition of the molecular precursor compound [Cl(Et)3Zn4(OiPr)4] in nitrogen atmosphere (squares) and artificial air (circles), heating rate: 5 K/min. The dashed grey line indicates the remaining

Alternative types of molecule-decorated atomic chains in Au–CO–Au single-molecule junctions

• Zoltán Balogh,
• Péter Makk and
• András Halbritter

Beilstein J. Nanotechnol. 2015, 6, 1369–1376, doi:10.3762/bjnano.6.141

• pure Au monoatomic junctions and atomic chains. We identify molecular precursor configurations with somewhat higher conductance, which are formed prior to single-molecule junctions. According to detailed length analysis two distinct types of molecule-affected chain-formation processes are observed, and

Microwave assisted synthesis and characterisation of a zinc oxide/tobacco mosaic virus hybrid material. An active hybrid semiconductor in a field-effect transistor device

• Shawn Sanctis,
• Rudolf C. Hoffmann,
• Sabine Eiben and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2015, 6, 785–791, doi:10.3762/bjnano.6.81

• was employed to synthesize stable zinc oxide (ZnO) nanoparticles, employing a molecular precursor. Insightful studies of the decomposition of the precursor were done using NMR spectroscopy and material characterization of the hybrid material derived from the decomposition was achieved using dynamic

• . Keywords: field-effect transistor; microwave synthesis; molecular precursor; thin film transistor; tobacco mosaic virus; zinc oxide; Introduction In recent years, the synthesis and fabrication of bio-inorganic nanostructures have gained tremendous importance for the fabrication of nanoscale devices with

• of molecular precursor complexes, with a low decomposition temperature and volatile and well defined byproducts ensures the formation of a resultant zinc oxide material with high purity. Additionally, microwave assisted decomposition of this class of precursors in solution has shown to yield stable

Classical molecular dynamics investigations of biphenyl-based carbon nanomembranes

• Andreas Mrugalla and
• Jürgen Schnack

Beilstein J. Nanotechnol. 2014, 5, 865–871, doi:10.3762/bjnano.5.98

• ]. The product is a membrane, whose thickness, homogeneity and surface chemistry are related to the molecular precursor. So far several classes of precursors have been exploited [3]. One of the major unsolved questions is the internal structure of these membranes, since the structure cannot be determined

Fabrication of carbon nanomembranes by helium ion beam lithography

• Xianghui Zhang,
• Henning Vieker,
• André Beyer and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2014, 5, 188–194, doi:10.3762/bjnano.5.20

• approaches have been used to exploit the capabilities of HIM, such as ion milling [21], scanning helium ion beam lithography (SHIBL) [22], and helium ion beam induced deposition (HIBID) [20]. Here we used 4'-nitro-1,1'-biphenyl-4-thiol (NBPT) as a molecular precursor to form SAMs on a Au substrate and

Dimer/tetramer motifs determine amphiphilic hydrazine fibril structures on graphite

• Loji K. Thomas,
• Nadine Diek,
• Uwe Beginn and
• Michael Reichling

Beilstein J. Nanotechnol. 2012, 3, 658–666, doi:10.3762/bjnano.3.75

• tetramers interweaved to form tubes with a fixed diameter. It follows that the large-scale morphologies at the liquid/solid interface are determined at the molecular/precursor level. Despite the compounds being specially designed as symmetric and asymmetric molecules, no inference is immediately discernible

Focused electron beam induced deposition: A perspective

• Michael Huth,
• Fabrizio Porrati,
• Christian Schwalb,
• Marcel Winhold,
• Roland Sachser,
• Maja Dukic,
• Jonathan Adams and
• Georg Fantner

Beilstein J. Nanotechnol. 2012, 3, 597–619, doi:10.3762/bjnano.3.70

• ) is receiving strongly increasing attention as a direct-writing technique for nanostructures due to its great versatility. In FEBID a previously adsorbed molecular precursor is dissociated in the focus of an electron beam provided by a scanning or transmission electron microscope (SEM/TEM). By and

• review of the fundamentals FEBID in a nutshell: The FEBID process is based on the electron-induced dissociation of a molecular precursor previously adsorbed on a substrate surface and constantly replenished by a gas-supply system. In most instances the gas-supply or gas-injection system consists of a

Radiation-induced nanostructures: Formation processes and applications

• Michael Huth

Beilstein J. Nanotechnol. 2012, 3, 533–534, doi:10.3762/bjnano.3.61

• technique a previously adsorbed molecular precursor is dissociated by the electron beam, leaving behind a permanent deposit of an amorphous, nanogranular [6][7] or polycrystalline microstructure with a minimum feature size well below 10 nm. Selected aspects of this technique and its application are reviewed

Studies towards synthesis, evolution and alignment characteristics of dense, millimeter long multiwalled carbon nanotube arrays

• Pitamber Mahanandia,
• Jörg J. Schneider,
• Martin Engel,
• Bernd Stühn,
• Somanahalli V. Subramanyam and
• Karuna Kar Nanda

Beilstein J. Nanotechnol. 2011, 2, 293–301, doi:10.3762/bjnano.2.34

• , India 10.3762/bjnano.2.34 Abstract We report the synthesis of aligned arrays of millimeter long carbon nanotubes (CNTs), from benzene and ferrocene as the molecular precursor and catalyst respectively, by a one-step chemical vapor deposition technique. The length of the grown CNTs depends on the

• molecular precursor and catalyst respectively, employing a single step, atmospheric pressure, CVD technique, which requires no additional carrier (e.g., Ar) or process gas (e.g., H2), and no oxygen containing compound as oxidant, for growing mm long CNT arrays. In addition, we show that SAXS is a valuable