Beilstein J. Nanotechnol.2024,15, 797–807, doi:10.3762/bjnano.15.66
probable reasons are its availability (it is a common precursor for iron-containing compounds in organometallicsynthesis), ease of handling (it is a volatile liquid at standard conditions), and relatively simple structure, which allows for advanced theoretical description. The ligand loss from Fe(CO)5 in
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Figure 1:
(a) Structure of iron tetracarbonyl methyl acrylate and (b) optimized geometry of iron tetracarbony...
Beilstein J. Nanotechnol.2010,1, 108–118, doi:10.3762/bjnano.1.13
corresponding to the large hyperfine fields with large isomer shifts are indeed characteristic of surface atoms.
Keywords: iron nanoparticles; magnetic properties; organometallicsynthesis; size effects; structure; Introduction
Progress in both experimental techniques and theoretical calculations over the
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Figure 1:
WAXS diagram (top) and the related RDF (bottom). Black: experimental spectra of Fe NPs taken at roo...