Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• massive guidance in synthesizing an efficient photocatalyst for CH4 conversion under mild conditions. Keywords: photocatalysis; photocatalytic CH4 oxidation; p–n heterojunction; TiO2/SiNWs; Introduction Methane (CH4), which can take the form of liquefied natural gas, is one of the crucial sources of

A visible-light photodetector based on heterojunctions between CuO nanoparticles and ZnO nanorods

• Doan Nhat Giang,
• Nhat Minh Nguyen,
• Duc Anh Ngo,
• Thanh Trang Tran,
• Le Thai Duy,
• Cong Khanh Tran,
• Thi Thanh Van Tran,
• Phan Phuong Ha La and
• Vinh Quang Dang

Beilstein J. Nanotechnol. 2023, 14, 1018–1027, doi:10.3762/bjnano.14.84

• responsivity, photoconductive gain, detectivity, and sensitivity with maximum values of 1.38 A·W−1, 4.33, 2.58 × 1011 Jones, and 1934.5% at a bias of 2 V, respectively. The sensing mechanism of the p–n heterojunction of CuO/ZnO is also explored. Overall, this study indicates that the heterostructure of CuO

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• semiconductor heterojunction, tetracycline and RhB were degraded using visible light. Better photocatalytic activity can be achieved with BiOI/Bi2O2CO3 photocatalysts instead of just using BiOI alone. This is because in BiOI/Bi2O2CO3 photocatalysts, an electric field emerges at the p–n heterojunction, which in

• interlayer contacts. This caused the photocatalytic reaction sites to boost, the light response to broaden, and the separation of photoinduced charge to improve. Lv et al. [99] fabricated a p–n heterojunction-based novel CuS/Bi2WO6 semiconductor photocatalyst with 2D interfacial connections of CuS over the

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• resistance due to the decrease of hole density within the p-type film [18]. In the case of the hybrid structures, a p–n heterojunction is formed between polyaniline and n-type nanostructures such as ZnO, WO3, In2O3, or fullerene [19]. The protons from polyaniline are transferred to the NH3 molecules. This

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• organic semiconductors such as graphitic carbon nitride (g-C3N4) [71]. When acting as an auxiliary photocatalyst, SnO2 promotes the photocatalytic activity of the primary material [38][70][75][76]. Wu et al. reported the visible-light-driven elimination of NO over hydrothermally synthesized BiOBr/SnO2 p–n

• heterojunction photocatalysts. The as-prepared BiOBr/SnO2 photocatalayst with a molar ratio of 2:5 between SnO2 NPs and BiOBr microspheres shows an enhanced NOx photocatalytic removal of 50.3%, at an initial NO concentration of 600 ppb, and a great stability after four cycles. The generation of toxic NO2

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• forms a p–n heterojunction, which improves the gas sensing abilities significantly [25]. Carbon-based materials are also promising gas sensors, because of their high surface area and high chemical and thermal stability [26][27]. Pristine graphene is a good conductor but rather inactive for gas sorption

Preparation, characterization and photocatalytic performance of heterostructured CuO–ZnO-loaded composite nanofiber membranes

• Wei Fang,
• Liang Yu and
• Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 631–650, doi:10.3762/bjnano.11.50

• narrow direct bandgap of 1.2–1.79 eV [14]. Because of that, CuO is usually used in combination with large-bandgap semiconductors, such as ZnO and TiO2, in order to improve their photocatalytic activity under solar light irradiation [15]. It was reported that the p–n heterojunction between ZnO and CuO has

Selective gas detection using Mn₃O₄/WO₃ composites as a sensing layer

• Yongjiao Sun,
• Zhichao Yu,
• Wenda Wang,
• Pengwei Li,
• Gang Li,
• Wendong Zhang,
• Lin Chen,
• Serge Zhuivkov and
• Jie Hu

Beilstein J. Nanotechnol. 2019, 10, 1423–1433, doi:10.3762/bjnano.10.140

• region and higher resistance in the atmosphere of air, which will facilitate an increased response (Figure 12c). Secondly, when p-type Mn3O4 is attached on the surface of n-type WO3, the p–n heterojunction is formed, which contributes to the increase of the resistance in air due to the thicker depletion

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• of the p–n heterojunction is shown in Figure 1, Ec and Ev are the energies of conduction band and valence band of the two components, respectively, while the Fermi level energy (Ef) is between these two bands. It can be seen from Figure 1 that the work function of rGO is lower than that of SnO2

Cr(VI) remediation from aqueous environment through modified-TiO₂-mediated photocatalytic reduction

• Rashmi Acharya,
• Brundabana Naik and
• Kulamani Parida

Beilstein J. Nanotechnol. 2018, 9, 1448–1470, doi:10.3762/bjnano.9.137

• carriers is not only suppressed but also the spectral response of TiO2 is extended to the visible spectrum by combining these metal oxides [159][161]. Moreover, formation of a p–n heterojunction is another strategy to facilitate the effective separation of electron–hole pairs and to extend light absorption

Facile synthesis of a ZnO–BiOI p–n nano-heterojunction with excellent visible-light photocatalytic activity

• Mengyuan Zhang,
• Jiaqian Qin,
• Pengfei Yu,
• Bing Zhang,
• Mingzhen Ma,
• Xinyu Zhang and
• Riping Liu

Beilstein J. Nanotechnol. 2018, 9, 789–800, doi:10.3762/bjnano.9.72

• well as the high specific area. Keywords: BiOI; photocatalytic degradation; p–n heterojunction; ZnO; Introduction The development of semiconductor photocatalysis has opened a new horizon for environmental pollution remediation and provides a potential solution to the global energy problem given the

• oxide to a p-type BiOX to form a p–n heterojunction is an effective method to optimize the photocatalytic activity (summarized in Table S1, Supporting Information File 1). By now, several works have been published in this area. In 2009, Zhang et al. reported a low-temperature route to prepare TiO2/BiOI

• of ZnO/BiOI nanocomposites was greatly improved due to the p–n heterojunction structure between ZnO and BiOI. Further insight into the mechanism is illustrated as follow. Figure 7a shows the simplified energy band structure of BiOI and ZnO. The valence band maximum energies of BiOI and ZnO as

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

• nanocomposite heterojunctions can drastically enhance the photocatalytic efficiency by enhanced light absorption in combination with narrow band gap semiconductors, cocatalytic effect, which results in and the formation of a p–n heterojunction or Schottky junction, which can effectively suppress the

Current–voltage characteristics of manganite–titanite perovskite junctions

• Benedikt Ifland,
• Patrick Peretzki,
• Birte Kressdorf,
• Philipp Saring,
• Andreas Kelling,
• Michael Seibt and
• Christian Jooss

Beilstein J. Nanotechnol. 2015, 6, 1467–1484, doi:10.3762/bjnano.6.152

• can be written as Here the partial voltage decrease over semiconductor 1 and 2 is given by V1 and V2. If we consider a p–n heterojunction, where Vbi,1 > ΔEC, there is no barrier for the charge carriers in semiconductor 1 to reach the semiconductor 2 and the equation can be reformulated as with Here