Beilstein J. Nanotechnol.2023,14, 927–938, doi:10.3762/bjnano.14.76
hydroxides; layered double hydroxide; layered materials; scale-upprocess; synthesis; two-dimensional materials; Introduction
Since the discovery of graphene [1], research on two-dimensional (2D) materials has become one of the most relevant topics in physics, chemistry, and (nano)materials science [2][3][4
reactor size) and mass (increment in the reagent concentration) scale-up processes. In the mass scale-upprocess, the increment in the concentration (25-fold that of the reference condition) triggers the appereance of simonkolleite-like Co-based impurities due to phase competition during the precipitation
[30][45][56][57][58]. This has been observed in different large-scale approaches, where different phases besides hydroxides have been observed at high concentrations [59][60].
In order to provide a comprehensive understanding of the electronic and structural features resulting from the scale-up
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Scheme 1:
Right: Schematic representation of volumetric and mass scale-up approaches. Left: LDH structure hig...
Beilstein J. Nanotechnol.2014,5, 2202–2215, doi:10.3762/bjnano.5.229
processes which could be used as a scale-upprocess for patterning metal–nanotube contacts. For instance, Vazquez-Mena et al. [72] developed a stencil lithography process to fabricate metallic nanowires at the wafer level. Nanoslits with a width down to 70 nm were defined on a wafer level membrane made of