Supporting Information
CCDC 1850924−1850926 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif.
| Supporting Information File 1: Experimental section, NMR spectra, catalysis procedure and product characterization, crystallographic details for W2F3·(NHMe2), W2F3 and WPhF3. | ||
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Cite the Following Article
Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex
Henrike Ehrhorn, Janin Schlösser, Dirk Bockfeld and Matthias Tamm
Beilstein J. Org. Chem. 2018, 14, 2425–2434.
https://doi.org/10.3762/bjoc.14.220
How to Cite
Ehrhorn, H.; Schlösser, J.; Bockfeld, D.; Tamm, M. Beilstein J. Org. Chem. 2018, 14, 2425–2434. doi:10.3762/bjoc.14.220
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- Ge, Y.; Hu, Y.; Duan, G.; Jin, Y.; Zhang, W. Advances and challenges in user-friendly alkyne metathesis catalysts. Trends in Chemistry 2022, 4, 540–553. doi:10.1016/j.trechm.2022.03.004
- Zier, M. L.; Colombel-Rouen, S.; Ehrhorn, H.; Bockfeld, D.; Trolez, Y.; Mauduit, M.; Tamm, M. Catalytic Alkyne and Diyne Metathesis with Mixed Fluoroalkoxy-Siloxy Molybdenum Alkylidyne Complexes. Organometallics 2021, 40, 2008–2015. doi:10.1021/acs.organomet.1c00290
- Melcher, D.; Àrias, Ò.; Freytag, M.; Jones, P. G.; Tamm, M. Synthesis of Alkyne Metathesis Catalysts from Tris(dimethylamido)tungsten Precursors. European Journal of Inorganic Chemistry 2020, 2020, 4454–4464. doi:10.1002/ejic.202000835
- Cui, M.; Bai, W.; Sung, H. H. Y.; Williams, I. D.; Jia, G. Robust Alkyne Metathesis Catalyzed by Air Stable d2 Re(V) Alkylidyne Complexes. Journal of the American Chemical Society 2020, 142, 13339–13344. doi:10.1021/jacs.0c06581
- Hauser, P. M.; van der Ende, M.; Groos, J.; Frey, W.; Wang, D.; Buchmeiser, M. R. Cationic Tungsten Alkylidyne N-Heterocyclic Carbene Complexes: Synthesis and Reactivity in Alkyne Metathesis. European Journal of Inorganic Chemistry 2020, 2020, 3070–3082. doi:10.1002/ejic.202000503
- Lee, D.; Volchkov, I.; Yun, S. Y. doi:10.1002/0471264180.or102.02
- Dragutan, V.; Dragutan, I.; Demonceau, A.; Delaude, L. Combining enyne metathesis with long-established organic transformations: a powerful strategy for the sustainable synthesis of bioactive molecules. Beilstein journal of organic chemistry 2020, 16, 738–755. doi:10.3762/bjoc.16.68
- Herndon, J. W. The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2018. Coordination Chemistry Reviews 2019, 401, 213051. doi:10.1016/j.ccr.2019.213051
- Ehrhorn, H.; Bockfeld, D.; Freytag, M.; Bannenberg, T.; Kefalidis, C. E.; Maron, L.; Tamm, M. Studies on Molybdena- and Tungstenacyclobutadiene Complexes Supported by Fluoroalkoxy Ligands as Intermediates of Alkyne Metathesis. Organometallics 2019, 38, 1627–1639. doi:10.1021/acs.organomet.9b00068
- Ehrhorn, H.; Tamm, M. Well‐Defined Alkyne Metathesis Catalysts: Developments and Recent Applications. Chemistry (Weinheim an der Bergstrasse, Germany) 2018, 25, 3190–3208. doi:10.1002/chem.201804511
- Àrias, Ò.; Ehrhorn, H.; Härdter, J.; Jones, P. G.; Tamm, M. Synthesis of Ether-Functionalized and Sterically Demanding Molybdenum Alkylidyne Complexes. Organometallics 2018, 37, 4784–4800. doi:10.1021/acs.organomet.8b00783
