Progress in metathesis chemistry III

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Editors: Prof. Karol Grela and Dr. Anna Kajetanowicz
University of Warsaw
 
The past year brought a number of important advances and scientific breakthroughs in the field of catalysis. For example, the development of even more selective catalysts, better techniques and a growing number of metathesis examples utilizing very low loading (at the part-per-million level) of catalysts and much more. At the same time much effort was invested in understanding the mechanisms of how new catalysts work and decompose, how macrocycles are formed in ring-closing metathesis etc. As with previous thematic issues, this current edition will comprise many excellent research reports and reviews summarizing current developments.
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Progress in metathesis chemistry

  • Karol Grela and
  • Anna Kajetanowicz

Beilstein J. Org. Chem. 2019, 15, 2765–2766, doi:10.3762/bjoc.15.267

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Published 15 Nov 2019

Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis

  • Tobias Fiedler,
  • Michał Barbasiewicz,
  • Michael Stollenz and
  • John A. Gladysz

Beilstein J. Org. Chem. 2018, 14, 2354–2365, doi:10.3762/bjoc.14.211

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Published 07 Sep 2018

Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex

  • Henrike Ehrhorn,
  • Janin Schlösser,
  • Dirk Bockfeld and
  • Matthias Tamm

Beilstein J. Org. Chem. 2018, 14, 2425–2434, doi:10.3762/bjoc.14.220

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Published 18 Sep 2018

Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps

  • Sambasivarao Kotha,
  • Milind Meshram and
  • Chandravathi Chakkapalli

Beilstein J. Org. Chem. 2018, 14, 2468–2481, doi:10.3762/bjoc.14.223

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Published 21 Sep 2018

Design and synthesis of C3-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence

  • Sambasivarao Kotha,
  • Saidulu Todeti and
  • Vikas R. Aswar

Beilstein J. Org. Chem. 2018, 14, 2537–2544, doi:10.3762/bjoc.14.230

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Published 01 Oct 2018

Ring-opening metathesis of some strained bicyclic systems; stereocontrolled access to diolefinated saturated heterocycles with multiple stereogenic centers

  • Zsanett Benke,
  • Melinda Nonn,
  • Márton Kardos,
  • Santos Fustero and
  • Loránd Kiss

Beilstein J. Org. Chem. 2018, 14, 2698–2707, doi:10.3762/bjoc.14.247

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Published 24 Oct 2018
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Published 25 Oct 2018

Synthesis of a tyrosinase inhibitor by consecutive ethenolysis and cross-metathesis of crude cashew nutshell liquid

  • Jacqueline Pollini,
  • Valentina Bragoni and
  • Lukas J. Gooßen

Beilstein J. Org. Chem. 2018, 14, 2737–2744, doi:10.3762/bjoc.14.252

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Published 31 Oct 2018

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

  • Daniel F. Sauer,
  • Johannes Schiffels,
  • Takashi Hayashi,
  • Ulrich Schwaneberg and
  • Jun Okuda

Beilstein J. Org. Chem. 2018, 14, 2861–2871, doi:10.3762/bjoc.14.265

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Published 19 Nov 2018

The influence of the cationic carbenes on the initiation kinetics of ruthenium-based metathesis catalysts; a DFT study

  • Magdalena Jawiczuk,
  • Angelika Janaszkiewicz and
  • Bartosz Trzaskowski

Beilstein J. Org. Chem. 2018, 14, 2872–2880, doi:10.3762/bjoc.14.266

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Published 20 Nov 2018

MoO3 on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis

  • Hynek Balcar,
  • Martin Kubů,
  • Naděžda Žilková and
  • Mariya Shamzhy

Beilstein J. Org. Chem. 2018, 14, 2931–2939, doi:10.3762/bjoc.14.272

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Published 27 Nov 2018

Stereodivergent approach in the protected glycal synthesis of L-vancosamine, L-saccharosamine, L-daunosamine and L-ristosamine involving a ring-closing metathesis step

  • Pierre-Antoine Nocquet,
  • Aurélie Macé,
  • Frédéric Legros,
  • Jacques Lebreton,
  • Gilles Dujardin,
  • Sylvain Collet,
  • Arnaud Martel,
  • Bertrand Carboni and
  • François Carreaux

Beilstein J. Org. Chem. 2018, 14, 2949–2955, doi:10.3762/bjoc.14.274

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Published 29 Nov 2018

The activity of indenylidene derivatives in olefin metathesis catalysts

  • Maria Voccia,
  • Steven P. Nolan,
  • Luigi Cavallo and
  • Albert Poater

Beilstein J. Org. Chem. 2018, 14, 2956–2963, doi:10.3762/bjoc.14.275

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Published 30 Nov 2018

Ring-closing-metathesis-based synthesis of annellated coumarins from 8-allylcoumarins

  • Christiane Schultze and
  • Bernd Schmidt

Beilstein J. Org. Chem. 2018, 14, 2991–2998, doi:10.3762/bjoc.14.278

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Published 05 Dec 2018

A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts

  • Daniel S. Müller,
  • Olivier Baslé and
  • Marc Mauduit

Beilstein J. Org. Chem. 2018, 14, 2999–3010, doi:10.3762/bjoc.14.279

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Published 07 Dec 2018

Cross metathesis-mediated synthesis of hydroxamic acid derivatives

  • Shital Kumar Chattopadhyay,
  • Subhankar Ghosh and
  • Suman Sil

Beilstein J. Org. Chem. 2018, 14, 3070–3075, doi:10.3762/bjoc.14.285

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Published 17 Dec 2018

Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands

  • Veronica Paradiso,
  • Chiara Costabile and
  • Fabia Grisi

Beilstein J. Org. Chem. 2018, 14, 3122–3149, doi:10.3762/bjoc.14.292

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Published 28 Dec 2018

Selective ring-opening metathesis polymerization (ROMP) of cyclobutenes. Unsymmetrical ladderphane containing polycyclobutene and polynorbornene strands

  • Yuan-Zhen Ke,
  • Shou-Ling Huang,
  • Guoqiao Lai and
  • Tien-Yau Luh

Beilstein J. Org. Chem. 2019, 15, 44–51, doi:10.3762/bjoc.15.4

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Published 03 Jan 2019

Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation

  • Łukasz Gułajski,
  • Andrzej Tracz,
  • Katarzyna Urbaniak,
  • Stefan J. Czarnocki,
  • Michał Bieniek and
  • Tomasz K. Olszewski

Beilstein J. Org. Chem. 2019, 15, 160–166, doi:10.3762/bjoc.15.16

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Published 17 Jan 2019

Catalysis of linear alkene metathesis by Grubbs-type ruthenium alkylidene complexes containing hemilabile α,α-diphenyl-(monosubstituted-pyridin-2-yl)methanolato ligands

  • Tegene T. Tole,
  • Johan H. L. Jordaan and
  • Hermanus C. M. Vosloo

Beilstein J. Org. Chem. 2019, 15, 194–209, doi:10.3762/bjoc.15.19

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Published 22 Jan 2019

Olefin metathesis in multiblock copolymer synthesis

  • Maria L. Gringolts,
  • Yulia I. Denisova,
  • Eugene Sh. Finkelshtein and
  • Yaroslav V. Kudryavtsev

Beilstein J. Org. Chem. 2019, 15, 218–235, doi:10.3762/bjoc.15.21

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Published 24 Jan 2019

Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

  • Patrycja Żak and
  • Cezary Pietraszuk

Beilstein J. Org. Chem. 2019, 15, 310–332, doi:10.3762/bjoc.15.28

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Published 04 Feb 2019

Aqueous olefin metathesis: recent developments and applications

  • Valerio Sabatino and
  • Thomas R. Ward

Beilstein J. Org. Chem. 2019, 15, 445–468, doi:10.3762/bjoc.15.39

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Published 14 Feb 2019

Synthesis of polydicyclopentadiene using the Cp2TiCl2/Et2AlCl catalytic system and thin-layer oxidation of the polymer in air

  • Zhargolma B. Bazarova,
  • Ludmila S. Soroka,
  • Alex A. Lyapkov,
  • Мekhman S. Yusubov and
  • Francis Verpoort

Beilstein J. Org. Chem. 2019, 15, 733–745, doi:10.3762/bjoc.15.69

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Published 20 Mar 2019

Hoveyda–Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable, industrially scalable, highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors

  • Kirill B. Polyanskii,
  • Kseniia A. Alekseeva,
  • Pavel V. Raspertov,
  • Pavel A. Kumandin,
  • Eugeniya V. Nikitina,
  • Atash V. Gurbanov and
  • Fedor I. Zubkov

Beilstein J. Org. Chem. 2019, 15, 769–779, doi:10.3762/bjoc.15.73

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Published 22 Mar 2019
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