Supporting Information
Full experimental details, 1H and 13C NMR spectra of new compounds, and M062X/6-311+G** computational studies are presented as Supporting Information.
| Supporting Information File 1: Experimental details and 1H and 13C NMR spectra of new compounds. | ||
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| Supporting Information File 2: M062X/6-611+G** calculated structures, energies, and Cartesian coordinates for carbocations and transition states. | ||
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Cite the Following Article
The cyclopropylcarbinyl route to γ-silyl carbocations
Xavier Creary
Beilstein J. Org. Chem. 2019, 15, 1769–1780.
https://doi.org/10.3762/bjoc.15.170
How to Cite
Creary, X. Beilstein J. Org. Chem. 2019, 15, 1769–1780. doi:10.3762/bjoc.15.170
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- Long, P.-W.; He, T.; Klare, H. F. T.; Oestreich, M. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions. Synlett 2023, 35, 941–951. doi:10.1055/a-2188-1842
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- Hari, D. P.; Abell, J. C.; Fasano, V.; Aggarwal, V. K. Ring-Expansion Induced 1,2-Metalate Rearrangements: Highly Diastereoselective Synthesis of Cyclobutyl Boronic Esters. Journal of the American Chemical Society 2020, 142, 5515–5520. doi:10.1021/jacs.0c00813
- Roy, A.; Bonetti, V.; Wang, G.; Wu, Q.; Klare, H. F. T.; Oestreich, M. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes. Organic letters 2020, 22, 1213–1216. doi:10.1021/acs.orglett.0c00173
