Reactive intermediates – carbocations
Dr. Stephanie R. Hare, University of Bristol
Stereochemical investigations on the biosynthesis of achiral (Z)-γ-bisabolene in Cryptosporangium arvum
- Jan Rinkel and
- Jeroen S. Dickschat
Beilstein J. Org. Chem. 2019, 15, 789–794, doi:10.3762/bjoc.15.75
Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
- Qichao Zhang,
- Jian Lv and
- Sanzhong Luo
Beilstein J. Org. Chem. 2019, 15, 1304–1312, doi:10.3762/bjoc.15.129
Cyclobutane dication, (CH2)42+: a model for a two-electron four-center (2e-4c) Woodward–Hoffmann frozen transition state
- G. K. Surya Prakash and
- Golam Rasul
Beilstein J. Org. Chem. 2019, 15, 1475–1479, doi:10.3762/bjoc.15.148
Different reactivity of phosphorylallenes under the action of Brønsted or Lewis acids: a crucial role of involvement of the P=O group in intra- or intermolecular interactions at the formation of cationic intermediates
- Stanislav V. Lozovskiy,
- Alexander Yu. Ivanov and
- Aleksander V. Vasilyev
Beilstein J. Org. Chem. 2019, 15, 1491–1504, doi:10.3762/bjoc.15.151
Superelectrophilic carbocations: preparation and reactions of a substrate with six ionizable groups
- Sean H. Kennedy,
- Makafui Gasonoo and
- Douglas A. Klumpp
Beilstein J. Org. Chem. 2019, 15, 1515–1520, doi:10.3762/bjoc.15.153
Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings
- Manuel Pedrón,
- Laura Legnani,
- Maria-Assunta Chiacchio,
- Pierluigi Caramella,
- Tomás Tejero and
- Pedro Merino
Beilstein J. Org. Chem. 2019, 15, 1552–1562, doi:10.3762/bjoc.15.158
Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement
- Gabrielle R. Hammersley,
- Meghan F. Nichol,
- Helena C. Steffens,
- Jose M. Delgado,
- Gesine K. Veits and
- Javier Read de Alaniz
Beilstein J. Org. Chem. 2019, 15, 1569–1574, doi:10.3762/bjoc.15.160
The cyclopropylcarbinyl route to γ-silyl carbocations
- Xavier Creary
Beilstein J. Org. Chem. 2019, 15, 1769–1780, doi:10.3762/bjoc.15.170
Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade
- Hajime Sato,
- Takaaki Mitsuhashi,
- Mami Yamazaki,
- Ikuro Abe and
- Masanobu Uchiyama
Beilstein J. Org. Chem. 2019, 15, 1890–1897, doi:10.3762/bjoc.15.184
Characterization of two new degradation products of atorvastatin calcium formed upon treatment with strong acids
- Jürgen Krauß,
- Monika Klimt,
- Markus Luber,
- Peter Mayer and
- Franz Bracher
Beilstein J. Org. Chem. 2019, 15, 2085–2091, doi:10.3762/bjoc.15.206
Acid-catalyzed rearrangements in arenes: interconversions in the quaterphenyl series
- Sarah L. Skraba-Joiner,
- Carter J. Holt and
- Richard P. Johnson
Beilstein J. Org. Chem. 2019, 15, 2655–2663, doi:10.3762/bjoc.15.258
Understanding the role of active site residues in CotB2 catalysis using a cluster model
- Keren Raz,
- Ronja Driller,
- Thomas Brück,
- Bernhard Loll and
- Dan T. Major
Beilstein J. Org. Chem. 2020, 16, 50–59, doi:10.3762/bjoc.16.7
