Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination

Maëva-Charlotte Kervarec, Thomas Braun, Mike Ahrens and Erhard Kemnitz
Beilstein J. Org. Chem. 2020, 16, 2623–2635. https://doi.org/10.3762/bjoc.16.213

Supporting Information

Supporting Information File 1: Analytical data and copies of spectra.
Format: PDF Size: 2.1 MB Download

Cite the Following Article

Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination
Maëva-Charlotte Kervarec, Thomas Braun, Mike Ahrens and Erhard Kemnitz
Beilstein J. Org. Chem. 2020, 16, 2623–2635. https://doi.org/10.3762/bjoc.16.213

How to Cite

Kervarec, M.-C.; Braun, T.; Ahrens, M.; Kemnitz, E. Beilstein J. Org. Chem. 2020, 16, 2623–2635. doi:10.3762/bjoc.16.213

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 9.4 MB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Tong, X.; Zhan, L.; Zhang, Y.; Xu, Z. Enhanced degradation of fluorinated refrigerants and resourceful conversion under external physical and chemical fields: Principle, technology and perspective. Resources, Conservation and Recycling 2024, 205, 107616. doi:10.1016/j.resconrec.2024.107616
  • Heinekamp, C.; Kneiske, S.; Guilherme Buzanich, A.; Ahrens, M.; Braun, T.; Emmerling, F. A fluorolytic sol–gel route to access an amorphous Zr fluoride catalyst: a useful tool for C–F bond activation. Catalysis Science & Technology 2024, 14, 673–680. doi:10.1039/d3cy01439h
  • Wei, X.; Sun, Y.; Jiang, J.; Wang, Z.; Zhang, W.; Liu, B.; Wang, S.; Yang, X.; Yu, W.; Zhang, J.; Han, W. Stabilizing F-Al-O active center via confinement of Al2O3 in SiC framework for conversion of 1,1-difluoroethane greenhouse gas. Journal of Fluorine Chemistry 2024, 274, 110257. doi:10.1016/j.jfluchem.2024.110257
  • Heinekamp, C.; Buzanich, A. G.; Ahrens, M.; Braun, T.; Emmerling, F. An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C-F bond activation and formation. Chemical communications (Cambridge, England) 2023, 59, 11224–11227. doi:10.1039/d3cc03164k
  • Doi, R.; Yasuda, M.; Kajita, N.; Koh, K.; Ogoshi, S. Nickel-Catalyzed Exhaustive Hydrodefluorination of Perfluoroalkyl Arenes. Journal of the American Chemical Society 2023, 145, 11449–11456. doi:10.1021/jacs.3c03471
  • Bui, M.; Hoffmann, K. F.; Braun, T.; Riedel, S.; Heinekamp, C.; Scheurell, K.; Scholz, G.; Stawski, T. M.; Emmerling, F. An Amorphous Teflate Doped Aluminium Chlorofluoride: A Solid Lewis‐Superacid for the Dehydrofluorination of Fluoroalkanes. ChemCatChem 2023, 15. doi:10.1002/cctc.202300350
  • Wang, L.; Zhang, X.; Li, C.; Cao, X.; Zhao, W.; Xiang, S. Superefficient separation of HFC-245fa/HF using extractive distillation: From computational thermodynamics to process assessment. Separation and Purification Technology 2023, 307, 122663. doi:10.1016/j.seppur.2022.122663
  • Pan, X.; Talavera, M.; Braun, T. Dehydrofluorination reactions at Lewis acidic ACF in the presence of HSnBu3. Journal of Fluorine Chemistry 2022, 263, 110046. doi:10.1016/j.jfluchem.2022.110046
  • Pan, X.; Talavera, M.; Scholz, G.; Braun, T. Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride. ChemCatChem 2022, 14. doi:10.1002/cctc.202200029
  • Talavera, M.; Braun, T. Competing C-H and C-F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step. Chemical science 2022, 13, 1130–1135. doi:10.1039/d1sc06713c
Other Beilstein-Institut Open Science Activities