Multi-faceted reactivity of N-fluorobenzenesulfonimide (NFSI) under mechanochemical conditions: fluorination, fluorodemethylation, sulfonylation, and amidation reactions

José G. Hernández, Karen J. Ardila-Fierro, Dajana Barišić and Hervé Geneste
Beilstein J. Org. Chem. 2022, 18, 182–189. https://doi.org/10.3762/bjoc.18.20

Supporting Information

Supporting Information File 1: Experimental details, characterization data and copies of spectra.
Format: PDF Size: 1.0 MB Download

Cite the Following Article

Multi-faceted reactivity of N-fluorobenzenesulfonimide (NFSI) under mechanochemical conditions: fluorination, fluorodemethylation, sulfonylation, and amidation reactions
José G. Hernández, Karen J. Ardila-Fierro, Dajana Barišić and Hervé Geneste
Beilstein J. Org. Chem. 2022, 18, 182–189. https://doi.org/10.3762/bjoc.18.20

How to Cite

Hernández, J. G.; Ardila-Fierro, K. J.; Barišić, D.; Geneste, H. Beilstein J. Org. Chem. 2022, 18, 182–189. doi:10.3762/bjoc.18.20

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 7.6 MB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Bai, L.; Tu, D.; Deng, P.; Chen, Y.; Tang, Q. Electrophilic aromatic substitution of electron-rich arenes with N-fluorobenzenesulfonimide (NFSI) as an electrophile. RSC advances 2024, 14, 34811–34815. doi:10.1039/d4ra07008a
  • Li, Z.; Zhang, C.; Zheng, Y.; Deng, P.; Yu, Y. Mechanochemical synthesis of biphenyl-derived organic fluorescent materials via solvent-free and ligand-free oxidative homocoupling reactions. New Journal of Chemistry 2024, 48, 7356–7361. doi:10.1039/d4nj00886c
  • Behera, S.; Kanti Bera, S.; Basoccu, F.; Cuccu, F.; Caboni, P.; De Luca, L.; Porcheddu, A. Application of Bertagnini's Salts in a Mechanochemical Approach Toward Aza‐Heterocycles and Reductive Aminations via Imine Formation. Advanced Synthesis & Catalysis 2024, 366, 2035–2043. doi:10.1002/adsc.202301407
  • Borodkin, G. I. Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view. Russian Chemical Reviews 2023, 92, RCR5091. doi:10.59761/rcr5091
  • Zhang, Y.; Xu, X.; Qing, F. Practical Synthesis of NFSI Derivatives through ArSO2NHF without F2. Chinese Journal of Chemistry 2022, 40, 2956–2962. doi:10.1002/cjoc.202200537
  • Borchardt, L.; Hernández, J. G. Dissecting Mechanochemistry III. Beilstein journal of organic chemistry 2022, 18, 1454–1456. doi:10.3762/bjoc.18.150
  • Min, S.; Park, B.; Nedsaengtip, J.; Hyeok Hong, S. Mechanochemical Direct Fluorination of Unactivated C(sp3)−H Bonds. Advanced Synthesis & Catalysis 2022, 364, 1975–1981. doi:10.1002/adsc.202200206
Other Beilstein-Institut Open Science Activities