Supporting Information
Supporting Information features EPR spectral simulations for quintet dinitrenes 15–17 and septet trinitrene 18 as individual species and for the mixtures of quintet molecules with EQ/DQ = 0.039/0.209, 0.038/0.213 and 0.036/0.221 at different molar ratios as well as EPR spectral simulations for nitrenes 15, 16 and 18 at different values of the line-broadening parameter Γ(E).
| Supporting Information File 1: EPR spectral simulations. | ||
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Cite the Following Article
High-spin intermediates of the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine
Sergei V. Chapyshev, Denis V. Korchagin, Patrik Neuhaus and Wolfram Sander
Beilstein J. Org. Chem. 2013, 9, 733–742.
https://doi.org/10.3762/bjoc.9.83
How to Cite
Chapyshev, S. V.; Korchagin, D. V.; Neuhaus, P.; Sander, W. Beilstein J. Org. Chem. 2013, 9, 733–742. doi:10.3762/bjoc.9.83
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Scholarly Works
- Chapyshev, S. V.; Korchagin, D. V.; Costa, P.; Sander, W. The powder X-band electron paramagnetic resonance spectroscopy of septet pyridyl-2,4,6-trinitrene. Magnetic resonance in chemistry : MRC 2022, 60, 829–835. doi:10.1002/mrc.5269
- Chapyshev, S. V.; Korchagin, D. V.; Misochko, E. Y. Recent advances in chemistry of high-spin nitrenes. Russian Chemical Reviews 2021, 90, 39–69. doi:10.1070/rcr4965
- Chapyshev, S. V.; Mendez-Vega, E.; Sander, W. Molecular Magnets: The Synthesis and Characterization of High-Spin Nitrenes. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 27, 1258–1269. doi:10.1002/chem.202002234
- Chapyshev, S. V.; Korchagin, D. V.; Grote, D.; Sander, W. EPR spectroscopy of multicomponent, multispin molecular system obtained by the photolysis of 2,4,6-triazido-3-cyano-5-fluoropyridine in solid argon. Magnetic resonance in chemistry : MRC 2019, 57, 472–478. doi:10.1002/mrc.4877
- Chapyshev, S. V.; Korchagin, D. V.; Costa, P.; Sander, W. Photochemical generation of high-spin nitrenes from 4,6-diazido-N-(4,6-diazido-1,3,5-triazin-2-yl)-1,3,5-triazin-2-amine in solid argon. Journal of Photochemistry and Photobiology A: Chemistry 2019, 377, 207–213. doi:10.1016/j.jphotochem.2019.03.052
- Chapyshev, S. V.; Korchagin, D. V.; Chernyak, A. V.; Aldoshin, S. M. Synthesis and structure of 3,4,5-triazidopyridine-2,6-dicarbonitrile possessing the record positive heat of formation. Mendeleev Communications 2017, 27, 116–118. doi:10.1016/j.mencom.2017.03.002
- Chapyshev, S. V. Six-Membered Aromatic Polyazides: Synthesis and Application. Molecules (Basel, Switzerland) 2015, 20, 19142–19171. doi:10.3390/molecules201019142
- Akimov, A. V.; Masitov, A. A.; Korchagin, D. V.; Chapyshev, S. V.; Misochko, E. Y.; Savitsky, A. W-band EPR studies of high-spin nitrenes with large spin-orbit contribution to zero-field splitting. The Journal of chemical physics 2015, 143, 084313. doi:10.1063/1.4929589
- Misochko, E. Y.; Masitov, A. A.; Akimov, A. V.; Korchagin, D. V.; Chapyshev, S. V. Heavy atom effect on magnetic anisotropy of matrix-isolated monobromine substituted septet trinitrene. The journal of physical chemistry. A 2014, 119, 2413–2419. doi:10.1021/jp508470m
- Chapyshev, S. V.; Ushakov, E. N.; Neuhaus, P.; Sander, W. Matrix Isolation, Zero-Field Splitting Parameters, and Photoreactions of Septet 2,4,6-Trinitrenopyrimidines. The Journal of organic chemistry 2014, 79, 6047–6053. doi:10.1021/jo500677g
- Chapyshev, S. V.; Chernyak, A. V. Triazidation of 2,4,6-trifluorobenzenes. Journal of Fluorine Chemistry 2013, 156, 303–306. doi:10.1016/j.jfluchem.2013.07.009
