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Beilstein J. Org. Chem. 2024, 20, 2442–2454, doi:10.3762/bjoc.20.208
Graphical Abstract
Figure 1: Synthesis of trihalogenated pyrans: a) Chiron approach to multivicinal inter-halide derived from al...
Scheme 1: Synthesis of halogenated talopyranose analogues 13–15, and 17 that include a 2,3-cis, 3,4-cis relat...
Figure 2: Direct comparison of 19F resonances of halogenated talose analogues 12–15 (19F NMR; 470 MHz, CDCl3)....
Figure 3: X-ray analysis of compound 13–15, 17, and α-ᴅ-talose 18. ORTEP diagram showing 50% thermal ellipsoi...
Figure 4: Packing arrangement of compound compound 15; a) View down the b axis; b) proposed intermolecular in...
Beilstein J. Org. Chem. 2020, 16, 2880–2887, doi:10.3762/bjoc.16.237
Figure 1: Previously described synthesis of 2,3,4-trifluorinated analogues of galactose 6, glucose 7, mannose ...
Figure 2: Typical 19F NMR spectrum (470 MHz, CDCl3) of the crude reaction mixture using Et3N·3HF/Et3N (entry ...
Figure 3: Fluorination at C4 of 1,6-anhydro-2,3-difluorohexopyranose analogues. a) Reactions on triflates 13, ...
Scheme 1: Synthesis of polyfluorinated alditols from levoglucosan 1: a) difluoroglucitol analogue 22; b) trif...