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Beilstein J. Org. Chem. 2025, 21, 473–482, doi:10.3762/bjoc.21.34
Graphical Abstract
Scheme 1: Previous work.
Scheme 2: Hypothesis, retro-Michael reaction, and its application in kinetic resolution.
Scheme 3: Model reaction.
Scheme 4: Kinetic resolution of the Michael adduct 1.
Scheme 5: Chemical correlation of 3 with 19.
Scheme 6: Epimerization of the anti-1 adduct promoted by A.