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1 article(s) from He, Jiao

Efficient synthesis of fluorinated triphenylenes with enhanced arene–perfluoroarene interactions in columnar mesophases

Yang Chen,
Jiao He,
Hang Lin,
Hai-Feng Wang,
Ping Hu,
Bi-Qin Wang,
Ke-Qing Zhao and
Bertrand Donnio

Beilstein J. Org. Chem. 2024, 20, 3263–3273, doi:10.3762/bjoc.20.270

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Graphical Abstract

Figure 1: Fluorotriphenylene derivatives and their nonfluorinated homologs obtained by S_NFAr from 2,2'-dilith...

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Scheme 1: Synthesis, yields, and nomenclature of 1,2,4-trifluoro-6,7,10,11-tetraalkoxy-3-(perfluorophenyl)tri...

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Figure 2: Single crystal structure of 1,2,4-trifluoro-3-(perfluorophenyl)triphenylene (F) viewed along the ma...

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Figure 3: POM textures, observed between crossed polarizers of Janus and dimer, F6, F12, G66, and G48, respec...

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Figure 4: Comparative bar graph summarizing the thermal behavior of Fn, BTP6, and PHn derivatives (2nd heatin...

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Figure 5: Representative S/WAXS patterns of Fn and Gnm compounds.

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Figure 6: Absorption (a) and emission (b) spectra of F6 and G66, measured in different solvents at a concentr...

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Figure 7: DFT calculated frontier molecular orbitals and optimized molecular structures for F1 and G11.

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Published 16 Dec 2024

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