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Beilstein J. Org. Chem. 2025, 21, 670–679, doi:10.3762/bjoc.21.53
Graphical Abstract
Figure 1: Chemical structures of phenacenes studied in this work.
Scheme 1: Synthesis of building blocks 10, 13, and 15. Reagents and conditions: a) NaBH4, MeOH, THF, reflux; ...
Scheme 2: Synthesis of F8PIC, F8FUL, and F87PHEN. Reagents and conditions: a) KOH, 18-crown-6, CH2Cl2, reflux...
Figure 2: UV–vis and fluorescence spectra of F8PIC (a), F8FUL (b), and F87PHEN (c) (red lines) and the corres...
Figure 3: Photoluminescence spectra of F8PIC (a), F8FUL (b), and F87PHEN (c) in toluene at 77 K.
Figure 4: Electronic spectra of F8PIC (a), F8FUL (b), and F87PHEN (c) (red lines) and the corresponding paren...
Figure 5: (a) The MO diagrams of the parent and fluorinated phenacenes (B3LYP/6-31+G(d,p)). H and L, respecti...