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1 article(s) from Kobayashi, Kaoru

Controlling the reactivity of La@C₈₂ by reduction: reaction of the La@C₈₂ anion with alkyl halide with high regioselectivity

Yutaka Maeda,
Saeka Akita,
Mitsuaki Suzuki,
Michio Yamada,
Takeshi Akasaka,
Kaoru Kobayashi and
Shigeru Nagase

Beilstein J. Org. Chem. 2023, 19, 1858–1866, doi:10.3762/bjoc.19.138

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Scheme 1: Reaction of the La@C₂_v-C₈₂ anion with benzyl bromide derivatives.

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Figure 1: Changes in absorption spectra during the reaction of La@C₂_v-C₈₂ anion with 1a.

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Figure 2: HPLC profiles of the reaction mixture. Conditions: Buckyprep column (⌀ = 4.6 × 250 mm); eluent, tol...

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Figure 3: HPLC profiles (Buckyprep column (⌀ = 4.6 × 250 mm); eluent, toluene; flow rate, 1.0 mL/min; UV dete...

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Figure 4: Absorption spectra of 2, 3, 4, and 5 in CS₂ and absorption spectra of C14, C10, C18, and C9 in Ce@C₂...

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Figure 5: ORTEP drawing of 3a with thermal ellipsoids shown at 50% probability level. Only an independent uni...

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Figure 6: (a) Charge density of La@C₂_v-C₈₂ anion as a function of its POAV values and (b) an enlarged part vi...

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Published 11 Dec 2023

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Controlling the reactivity of La@C82 by reduction: reaction of the La@C82 anion with alkyl halide with high regioselectivity

Controlling the reactivity of La@C₈₂ by reduction: reaction of the La@C₈₂ anion with alkyl halide with high regioselectivity