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Beilstein J. Org. Chem. 2024, 20, 2254–2260, doi:10.3762/bjoc.20.193
Graphical Abstract
Figure 1: (a) Typical example of stable aromatic hydrocarbon radicals with 9-anthryl units. (b) Tail-to-tail ...
Figure 2: (a) The structure of DAntM radical (left) and its spin delocalization on two anthryl units. (b) Pla...
Scheme 1: Synthetic route to the DAntM radical.
Figure 3: (a) ESR spectrum of the DAntM radical (black line, Exp.) and its simulated pattern (red line, Sim.)...
Figure 4: (a) ESR spectrum of anthroxyl radical 5 (black line, Exp.) and its simulated pattern (red line, Sim...
Scheme 2: Decomposition pathway of the DAntM radical under air conditions.
Figure 5: Cyclic voltammogram (CV) of DAntM cation. (a) CV measured with scan rate at 3.0 V s−1. (b) Scan rat...
Figure 6: UV–vis–NIR spectra of (a) DAntM radical in toluene, (b) DAntM cation in TFA.