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Beilstein J. Org. Chem. 2024, 20, 1677–1683, doi:10.3762/bjoc.20.149
Graphical Abstract
Figure 1: Overview of common non-iodine-based (left) and iodine-based (right) oxidizing reagents for the gene...
Figure 2: NHIs investigated for the oxidation of benzylic alcohols and the crystal structure (ORTEP drawing) ...
Figure 3: 1H NMR spectra of the time-dependent formation of a) an alkoxy-NHI which is causing a significant d...
Figure 4: Oxidation of 3a to 4a using different iodine(III) reagents with AlCl3 as an additive. Conditions: T...
Figure 5: Substrate scope of aldehydes and ketones synthesized from the corresponding alcohols. Isolated yiel...
Scheme 1: Possible reaction mechanisms via the formation of a) a Cl(I) species and b) the formation of an alk...
Beilstein J. Org. Chem. 2024, 20, 12–16, doi:10.3762/bjoc.20.2
Scheme 1: Examples for direct syntheses of N-acyl heteroaromatic compounds.
Scheme 2: Scope of amides. aIsolated yields, 200 µmol scale, all reactions carried out in p-xylene, with 1.00...
Scheme 3: Scope of iodanes. aIsolated yields, 200 µmol scale, all reactions carried out in p-xylene, with 1.0...
Beilstein J. Org. Chem. 2023, 19, 317–324, doi:10.3762/bjoc.19.27
Figure 1: Nitrogen-containing iodolium and iodonium salts.
Figure 2: Synthesis of a set of azoiodazinium salts 5. Method A: Iodoarene 4 (200 µmol) and mCPBA (1.1 equiv)...
Figure 3: Single crystal structures (ORTEP drawing with 50% probability) of the pyrazole-coordinated salt 5bb...
Scheme 1: Derivatizations of the iodonium salt 5aa. a) Ac2O, CuSO4·5H2O, NaOAc, AcOH, 120 °C, 5 h; b) S8/Se/T...
Scheme 2: Post-functionalization of mono- and dicationic iodonium salts under preservation of the hypervalent...