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1 article(s) from Lipka, Bradley M

Quantifying the ability of the CF₂H group as a hydrogen bond donor

Matthew E. Paolella,
Daniel S. Honeycutt,
Bradley M. Lipka,
Jacob M. Goldberg and
Fang Wang

Beilstein J. Org. Chem. 2025, 21, 189–199, doi:10.3762/bjoc.21.11

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Figure 1: Examples of solid state structures exhibiting CF₂H group-mediated hydrogen bond interactions [16,18,21]. Hydr...

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Figure 2: Hydrogen bond donors investigated in this study. For all cationic species, the counteranion is BF₄⁻...

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Figure 3: Hydrogen bond donation ability determined by UV–vis spectroscopy titration. A) Formation of HB comp...

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Figure 4: A) HB complex formation between a donor and tri-n-butylphosphine oxide. B) ¹H NMR spectra of 2b (5....

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Figure 5: Hydrogen bond donation ability of various donors as quantified by the dissociation constant (K_d) of...

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Figure 6: A) Linear correlation between ΔG_exp and ΔG_calc. ΔG_exp and ΔG_calc values are shown in Figure 5. B) Linear co...

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Published 20 Jan 2025

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Quantifying the ability of the CF2H group as a hydrogen bond donor

Quantifying the ability of the CF₂H group as a hydrogen bond donor