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Beilstein J. Org. Chem. 2024, 20, 2567–2576, doi:10.3762/bjoc.20.215
Graphical Abstract
Figure 1: Triazatriangulenium cations 1a+ and 1b+.
Figure 2: Synthesis of triazatriangulenium ion pairs 2+-X− (X− = BF4−, PF6−, B(C6F5)4−, and PCCp−).
Figure 3: Single-crystal X-ray structures of (a) 2+-Cl−, (b) 2+-BF4−, (c) 2+-PF6−, (d) 2+-B(C6F5)4−, and (e) 2...
Figure 4: Hirshfeld surface analysis mapped with dnorm of closely contacted two 2+ in (a) 2+-BF4− and (b) 2+-...
Figure 5: Hirshfeld surface analysis mapped with dnorm of closely contacted ion pairs: (a) 2+-Cl−, (b) 2+-BF4−...
Figure 6: (i) Single-crystal X-ray structures and (ii) interaction energies for the pairs (a) 2+-Cl−, (b) 2+-...
Figure 7: Hirshfeld surface analysis mapped with dnorm of closely contacted ion pairs: (a) 2+-B(C6F5)4− and (...
Figure 8: (i) Single-crystal X-ray structures and (ii) interaction energies for the pairs for (a) 2+-B(C6F5)4−...