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Beilstein J. Org. Chem. 2024, 20, 2261–2269, doi:10.3762/bjoc.20.194
Graphical Abstract
Figure 1: gem-Difluorination of carbon–carbon triple bonds. Selected examples from (1) to (5), and this work ...
Scheme 1: gem-Difluorination promoted by electrogenerated acids (method B).
Scheme 2: Generation and accumulation of EGA followed by the reaction with 1a for 2a.
Scheme 3: Plausible reaction mechanism.
Beilstein J. Org. Chem. 2022, 18, 1116–1122, doi:10.3762/bjoc.18.114
Scheme 1: Formations of 1,2,3-trialkyl cyclopropanetricarboxylates. Previous reports (reactions 1–3) and this...
Scheme 2: Plausible reaction mechanism. EGB = electrogenerated base.