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Beilstein J. Org. Chem. 2024, 20, 2234–2241, doi:10.3762/bjoc.20.191
Graphical Abstract
Figure 1: Previously reported regioselective double azide addition to DBA with hexyloxy substituents and mole...
Scheme 1: Synthesis of DBA 5.
Figure 2: (a) Strain-promoted azide–alkyne cycloaddition between DBA 5 and benzyl azide and (b) 1H NMR spectr...
Figure 3: Arrhenius plots of the rate constants for the reaction between 5 and benzyl azide in CDCl3.
Figure 4: Proposed reaction mechanism for the formation of compound 6a. Free energy profiles (ΔG298 in kJ mol...
Figure 5: Absorption (blue) and fluorescence (red) spectra of 6a (2 × 10−5 M) in CH2Cl2.
Figure 6: (a) Crosslinking reaction of PVC-N3 (x = 0.11) with compound 5. (b,c) Strain-stress curves of PVC-N3...