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Beilstein J. Org. Chem. 2025, 21, 146–154, doi:10.3762/bjoc.21.8
Graphical Abstract
Scheme 1: C–F bond activation through β-fluorine elimination via metalacyclopropanes.
Scheme 2: Synthesis of 2-arylbenzofurans 3 via the coupling of 1 with 2. Isolated yields are given. aNi(cod)2...
Scheme 3: Synthesis of 2-phenylbenzothiophene (5).
Scheme 4: Orthogonal approach to 2,5-diarylbenzofuran 3fa.
Scheme 5: Possible mechanisms.
Scheme 6: Formation of nickelacyclopropane Eb in a stoichiometric reaction.