Palladium-catalyzed substitution of (coumarinyl)methyl acetates with C-, N-, and S-nucleophiles

• Kalicharan Chattopadhyay,
• Erik Fenster,
• Alexander J. Grenning and
• Jon A. Tunge

Beilstein J. Org. Chem. 2012, 8, 1200–1207, doi:10.3762/bjoc.8.133

• acetate and aryl sulfinate coupling reaction. Scope of the coumarinyl acetate and amine coupling reaction. Reaction development for the coupling of in situ generated enolates and coumarin π-benzyl complexes. Palladium-catalyzed coupling of coumarinyl acetate and phenylboronic acid. Supporting Information

A concise synthesis of 3-(1-alkenyl)isoindolin-1-ones and 5-(1-alkenyl)pyrrol-2-ones by the intermolecular coupling reactions of N-acyliminium ions with unactivated olefins

• Nianhong Lu,
• Lihong Wang,
• Zhanshan Li and
• Wei Zhang

Beilstein J. Org. Chem. 2012, 8, 192–200, doi:10.3762/bjoc.8.21

• -1-one derivatives. One was, as mentioned above, by the Cp2ZrCl2 catalyzed coupling of N-acyliminium ions with in situ generated dimethyl 1-alkenylalanes [24], another was performed by the palladium-catalyzed coupling of 2-iodobenzoyl chloride with aldimines and subsequent cyclization [34]. The

Amines as key building blocks in Pd-assisted multicomponent processes

• Didier Bouyssi,
• Nuno Monteiro and
• Geneviève Balme

Beilstein J. Org. Chem. 2011, 7, 1387–1406, doi:10.3762/bjoc.7.163

• indole derivatives have been reported because they occur in numerous natural products and bioactive compounds. Among these different strategies, those involving a palladium-catalyzed coupling reaction have received much attention [25] and one of the most commonly used procedures involves a one-pot two

Conjugated polymers containing diketopyrrolopyrrole units in the main chain

• Bernd Tieke,
• A. Raman Rabindranath,
• Kai Zhang and
• Yu Zhu

Beilstein J. Org. Chem. 2010, 6, 830–845, doi:10.3762/bjoc.6.92

• arylamine. The bromination of aryl units is important for the subsequent palladium-catalyzed coupling reaction. If the aryl unit is thiophene, direct bromination with N-bromosuccinimide is possible to yield monomer M-3 [16]. For the preparation of conjugated DPP-based polymers, palladium-catalyzed

Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF₂

• Lukas J. Gooßen,
• Bettina Zimmermann and
• Thomas Knauber

Beilstein J. Org. Chem. 2010, 6, No. 43, doi:10.3762/bjoc.6.43

• arenes in good yields. Keywords: carboxylic acids; copper; decarboxylation; Heck vinylation; palladium; Introduction The palladium-catalyzed coupling of olefins with aryl or vinyl substrates, developed by Mizoroki [1] and Heck [2][3] in the 1970s, is one of the most important, reliable and generally

Preparation of pyridine-3,4-diols, their crystal packing and their use as precursors for palladium-catalyzed cross-coupling reactions

• Tilman Lechel,
• Irene Brüdgam and
• Hans-Ulrich Reissig

Beilstein J. Org. Chem. 2010, 6, No. 42, doi:10.3762/bjoc.6.42

• palladium-catalyzed coupling reactions. Fluorescence measurements of the biscoupled products showed a maximum of emission in the violet region of the spectrum. Keywords: bisnonaflates; fluorescence; palladium catalysis; pyridine-3,4-diols; pyridines; Introduction Pyridine scaffolds have been found in

• pyridindiols and hydroxypyridinones will be thoroughly investigated in the solid state as well as in solution. Furthermore, subsequent transformations into bistriflate or bisnonaflate derivatives will be described, followed by palladium-catalyzed coupling reactions. The resulting biscoupling products are

• extended π-systems using palladium-catalyzed coupling reactions. Moreover, compounds 4b–c show interesting photophysical properties that might be thoroughly investigated in the future. The 3,4-dialkynyl-pyridine derivatives 4 or 5 are also candidates for Bergman cyclizations [34][35] which may establish a