Titanium-mediated reductive cross-coupling reactions of imines with terminal alkynes: An efficient route for the synthesis of stereodefined allylic amines

• Kebin Mao,
• Guoqin Fan,
• Yuanhong Liu,
• Shi Li,
• Xu You and
• Dan Liu

Beilstein J. Org. Chem. 2013, 9, 621–627, doi:10.3762/bjoc.9.69

• Kebin Mao Guoqin Fan Yuanhong Liu Shi Li Xu You Dan Liu State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, People’s Republic of China College of Chemical Engineering, Shenyang University of

Alkyne hydroarylation with Au N-heterocyclic carbene catalysts

• Cristina Tubaro,
• Marco Baron,
• Andrea Biffis and
• Marino Basato

Beilstein J. Org. Chem. 2013, 9, 246–253, doi:10.3762/bjoc.9.29

• reaction [12][13][14]. Recently, we have extended our interest in the organometallic chemistry of such ligands to group 11 metals, in particular gold(I) and gold(III) centers [54][55][56]. In the present contribution we would like to assess the catalytic efficiency of such gold complexes with NHC ligands

Modulating the activity of short arginine-tryptophan containing antibacterial peptides with N-terminal metallocenoyl groups

• H. Bauke Albada,
• Alina-Iulia Chiriac,
• Michaela Wenzel,
• Maya Penkova,
• Julia E. Bandow,
• Hans-Georg Sahl and
• Nils Metzler-Nolte

Beilstein J. Org. Chem. 2012, 8, 1753–1764, doi:10.3762/bjoc.8.200

• ; medicinal organometallic chemistry; metallocenoyl; peptides; tryptophan; Introduction New antibacterial agents need to be discovered since established antibiotics are increasingly losing ground against resistant bacteria and at the same time the pipeline that is supposed to produce new antibiotics is

Synthesis of conformationally restricted glutamate and glutamine derivatives from carbonylation of orthopalladated phenylglycine derivatives

• Esteban P. Urriolabeitia,
• Eduardo Laga and
• Carlos Cativiela

Beilstein J. Org. Chem. 2012, 8, 1569–1575, doi:10.3762/bjoc.8.179

• selective functionalization of organic molecules is, at the present time, one of the most developed areas of organic and organometallic chemistry. Several factors have contributed to this spectacular growth. The main one is the use of transition metals, such as Rh, Ru, Pd, Pt or Au, with the capability of

Chiral multifunctional thiourea-phosphine catalyzed asymmetric [3 + 2] annulation of Morita–Baylis–Hillman carbonates with maleimides

• Hong-Ping Deng,
• De Wang,
• Yin Wei and
• Min Shi

Beilstein J. Org. Chem. 2012, 8, 1098–1104, doi:10.3762/bjoc.8.121

• Hong-Ping Deng De Wang Yin Wei Min Shi State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, People’s Republic of China Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School

Synthesis of axially chiral oxazoline–carbene ligands with an N-naphthyl framework and a study of their coordination with AuCl·SMe₂

• Feijun Wang,
• Shengke Li,
• Mingliang Qu,
• Mei-Xin Zhao,
• Lian-Jun Liu and
• Min Shi

Beilstein J. Org. Chem. 2012, 8, 726–731, doi:10.3762/bjoc.8.81

• Feijun Wang Shengke Li Mingliang Qu Mei-Xin Zhao Lian-Jun Liu Min Shi Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 MeiLong Road, Shanghai 200237, P. R. China State Key Laboratory of Organometallic Chemistry, Shanghai

Sonogashira–Hagihara reactions of halogenated glycals

• Dennis C. Koester and
• Daniel B. Werz

Beilstein J. Org. Chem. 2012, 8, 675–682, doi:10.3762/bjoc.8.75

• investigations with respect to the Sonogashira–Hagihara coupling complement the rich organometallic chemistry that has already been performed with borylated, stannylated and phosphorylated glycals. Different strategies to access C-glycosides starting from 1-substituted glycals. Sonogashira–Hagihara reaction of 1

Bromine–lithium exchange: An efficient tool in the modular construction of biaryl ligands

• Laurence Bonnafoux,
• Frédéric R. Leroux and
• Françoise Colobert

Beilstein J. Org. Chem. 2011, 7, 1278–1287, doi:10.3762/bjoc.7.148

• organometallic chemistry [33][34][35] allows the performance of highly selective reactions. Therefore, it seemed to us the ideal tool to reaching this goal. In this context, we recently developed a novel transition metal-free aryl–aryl coupling protocol, the "ARYNE-coupling", which allows the preparation of di

• . Catalytic studies as well as the control of biaryl axial chirality are currently underway and will be reported in due course. Modular synthesis of bis(diarylphosphino)-, bis(dialkylphosphino)- and dialkyl(diaryl)phosphinobiphenyls as well as monophosphinobiphenyls by means of polar organometallic chemistry

Au(I)/Au(III)-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions

• Deyun Qian and
• Junliang Zhang

Beilstein J. Org. Chem. 2011, 7, 808–812, doi:10.3762/bjoc.7.92

• Deyun Qian Junliang Zhang Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai 200062 (P. R. China) State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry

Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis

• Lian-jun Liu,
• Feijun Wang,
• Wenfeng Wang,
• Mei-xin Zhao and
• Min Shi

Beilstein J. Org. Chem. 2011, 7, 555–564, doi:10.3762/bjoc.7.64

• Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, People’s Republic of China, Fax: 86-21-64166128 10.3762/bjoc.7.64 Abstract Axially chiral mono(NHC)–Pd(II) and mono(NHC)–Au(I) complexes with one side shaped 1,1

CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands

• Shuxu Gao,
• Yu Liu and
• Shengming Ma

Beilstein J. Org. Chem. 2011, 7, 396–403, doi:10.3762/bjoc.7.51

• Shuxu Gao Yu Liu Shengming Ma Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry

Olefin metathesis in nano-sized systems

• Didier Astruc,
• Abdou K. Diallo,
• Sylvain Gatard,
• Liyuan Liang,
• Cátia Ornelas,
• Victor Martinez,
• Denise Méry and
• Jaime Ruiz

Beilstein J. Org. Chem. 2011, 7, 94–103, doi:10.3762/bjoc.7.13

• as possible and that polluting classic organic solvents be replaced by “greener” solvents such as water or super-critical carbon dioxide. Therefore during the last decade, we have attempted to make progress in this field with dendrimers using nano-organometallic chemistry [10]. There are several ways

• group showed distorted square pyramidal geometry and the classic geometric features of a Ru=C double bond. The oxygen atom of the isopropyl aryl ether group is not coordinated unlike in Hoveyda’s complex 1. The fundamental organometallic chemistry of this monomeric model complex was also original [24

Recent advances in the development of alkyne metathesis catalysts

• Xian Wu and
• Matthias Tamm

Beilstein J. Org. Chem. 2011, 7, 82–93, doi:10.3762/bjoc.7.12

• towards early transition metals or metals in a higher oxidation state [53][54][55]. In recent years, our group has significantly expanded the use of these 2σ,4π-electron donor ligands in organometallic chemistry and homogeneous catalysis [56][57][58][59][60][61][62][63][64][65][66][67]. Their synthesis

Trifluoromethyl ethers – synthesis and properties of an unusual substituent

• Frédéric R. Leroux,
• Baptiste Manteau,
• Jean-Pierre Vors and
• Sergiy Pazenok

Beilstein J. Org. Chem. 2008, 4, No. 13, doi:10.3762/bjoc.4.13

• aromatics is based on the synthesis-oriented organometallic chemistry. The metal is introduced into a substrate in general by either one of two favorite methods, the permutational interconversion of halogen against metal or hydrogen against metal and subsequently replaced by an electrophile [69][70]. The