Search results

Search for "cycloaddition reactions" in Full Text gives 179 result(s) in Beilstein Journal of Organic Chemistry.

Synthesis and Diels–Alder cycloaddition reaction of norbornadiene and benzonorbornadiene dimers

  • Bilal Nişancı,
  • Erdin Dalkılıç,
  • Murat Güney and
  • Arif Daştan

Beilstein J. Org. Chem. 2009, 5, No. 39, doi:10.3762/bjoc.5.39

Graphical Abstract
  • indistinguishable. To determine which is which, cycloaddition reactions of dimers are more informative. Dimers 7 and 16 give symmetric addition products 11, 12 and 18, 19, whereas the reaction of dimers 8 and 17 resulted in the formation of unsymmetrical products 13, 14 and 20, 21. For the symmetric addition
  • ). Numbering of carbon atoms and description of possible structures for dimers 11–14 and 18–21. Synthesis of starting materials 4 and 5. Synthesis and Diels–Alder cycloaddition reactions of dimers 7 and 8. Synthesis and Diels–Alder cycloaddition reactions of dimers 16 and 17. Acknowledgments This work has
PDF
Album
Full Research Paper
Published 11 Aug 2009

Aroylketene dithioacetal chemistry: facile synthesis of 4-aroyl- 3-methylsulfanyl- 2-tosylpyrroles from aroylketene dithioacetals and TosMIC

  • H. Surya Prakash Rao and
  • S. Sivakumar

Beilstein J. Org. Chem. 2007, 3, No. 31, doi:10.1186/1860-5397-3-31

Graphical Abstract
  • heterocyclic systems, examples of their participation in the cycloaddition reactions are rare. In continuation of our interest on ketene acetals [5][6][7] we considered that 1,3-dipolar cycloaddition of the anion generated from the von Leusen's reagent (p-tolylsulfonyl)methyl isocyanide (TosMIC) 2 to AKDTAs 1
PDF
Album
Supp Info
Full Research Paper
Published 28 Sep 2007

The use of silicon- based tethers for the Pauson- Khand reaction

  • Adrian P. Dobbs,
  • Ian J. Miller and
  • Saša Martinović

Beilstein J. Org. Chem. 2007, 3, No. 21, doi:10.1186/1860-5397-3-21

Graphical Abstract
  • has shown that for cycloaddition reactions to occur, the non-reactive substituents around the silicon centre must be more bulky than the Me or Ph groups employed in these studies. Denmark's work demonstrated that the angles at the silicon centre between the two 'arms' of the silyl ether can be up to
PDF
Album
Supp Info
Preliminary Communication
Published 06 Jul 2007

High stereoselectivity on low temperature Diels- Alder reactions

  • Luiz Carlos da Silva Filho,
  • Valdemar Lacerda Júnior,
  • Mauricio Gomes Constantino,
  • Gil Valdo José da Silva and
  • Paulo Roberto Invernize

Beilstein J. Org. Chem. 2005, 1, No. 14, doi:10.1186/1860-5397-1-14

Graphical Abstract
  • , usually AlCl3, could be used to enhance the reactivity of these poor dienophiles. [1][2][3][4] Particularly the cycloenones are desirable dienophiles, because their cycloaddition reactions are a remarkable tool for the synthesis of octalones and related bicyclic olefinic ketones (e.g., decaline-based
  • attack. The resulting lowering of the activation energy usually leads to an enhancement of stereo- and regioselectivity [7]. It was also soon realized that the modifications in the cycloaddition reactions parameters should depend on the Lewis acids used, and a number of authors have performed comparison
PDF
Album
Supp Info
Full Research Paper
Published 09 Dec 2005
Other Beilstein-Institut Open Science Activities