Beilstein J. Org. Chem.2025,21, 155–178, doi:10.3762/bjoc.21.9
-arylenamines and annulation.
Scheme and proposed mechanism for Cu-catalyzed electrochemicalhalogenation.
Scheme and proposed mechanism for Cu-catalyzed asymmetric cyanophosphinoylation of vinylarenes.
Scheme and proposed mechanism for Cu/Co dual-catalyzed asymmetric hydrocyanation of alkenes.
Scheme and
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Graphical Abstract
Figure 1:
General mechanisms of traditional and radical-mediated cross-coupling reactions.
Beilstein J. Org. Chem.2015,11, 392–402, doi:10.3762/bjoc.11.45
affords different products depending on the reaction conditions.
Keywords: allylic oxidation; cholesterol; electrochemicalhalogenation; electrochemical oxidation; Introduction
Cholesterol is the most common steroid in the mammalian body. It is necessary to ensure a proper membrane permeability and
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Graphical Abstract
Figure 1:
Preferential sites of cholesterol electrooxidation.