On the photoluminescence in triarylmethyl-centered mono-, di-, and multiradicals

• Daniel Straub,
• Markus Gross,
• Mona E. Arnold,
• Julia Zolg and
• Alexander J. C. Kuehne

Beilstein J. Org. Chem. 2025, 21, 964–998, doi:10.3762/bjoc.21.80

Advances in radical peroxidation with hydroperoxides

• Oleg V. Bityukov,
• Pavel Yu. Serdyuchenko,
• Andrey S. Kirillov,
• Gennady I. Nikishin,
• Vera A. Vil’ and
• Alexander O. Terent’ev

Beilstein J. Org. Chem. 2024, 20, 2959–3006, doi:10.3762/bjoc.20.249

• copper catalysis the complex Cu(II)OO-t-Bu was proposed [122]. The difunctionalization of styrenes 175 with trifluoromethyl and peroxy groups was carried out using Togni reagent II (176) as a CF3-group precursor and the metal organic framework Cu3(BTC)2 as a heterogeneous catalyst (Scheme 54) [123]. The

A comprehensive review of flow chemistry techniques tailored to the flavours and fragrances industries

• Guido Gambacorta,
• James S. Sharley and
• Ian R. Baxendale

Beilstein J. Org. Chem. 2021, 17, 1181–1312, doi:10.3762/bjoc.17.90

Heterogeneous photocatalysis in flow chemical reactors

• Christopher G. Thomson,
• Ai-Lan Lee and
• Filipe Vilela

Beilstein J. Org. Chem. 2020, 16, 1495–1549, doi:10.3762/bjoc.16.125

• charge–transfer transitions [95]. These transitions are commonly observed in metal–organic framework (MOF) HPCats, discussed more in Section 2.5. Dye-sensitised semiconductor photocatalysts have organic photosensitiser molecules immobilised to their surface. This strategy is typically used to activate a

Recent advances on the transition-metal-catalyzed synthesis of imidazopyridines: an updated coverage

• Gagandeep Kour Reen,
• Ashok Kumar and
• Pratibha Sharma

Beilstein J. Org. Chem. 2019, 15, 1612–1704, doi:10.3762/bjoc.15.165

• -benzenedicarboxylate), Puthiaraj and co-workers have unprecedently discovered the catalytic activity of this metal-organic framework (MOF) for the synthesis of imidazo[1,2-a]pyridines [100]. The three-component, one-pot reaction between 1, 3 and nitromethane (10, Scheme 5) involved an intermolecular aza-Michael

Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks

• Sebastian Hamer,
• Fynn Röhricht,
• Marius Jakoby,
• Ian A. Howard,
• Xianghui Zhang,
• Christian Näther and
• Rainer Herges

Beilstein J. Org. Chem. 2019, 15, 1331–1338, doi:10.3762/bjoc.15.132

• linkers in MOFs with potential applications as ferroelectric materials and for optical signal processing. Keywords: benzothiadiazole; dipolar rotor; fluorescence; large dipole moment; metal organic framework linker; Introduction Rotors are among the fundamental functional units in engineering in our

Determining the predominant tautomeric structure of iodine-based group-transfer reagents by ¹⁷O NMR spectroscopy

• Nico Santschi,
• Cody Ross Pitts,
• Benson J. Jelier and
• René Verel

Beilstein J. Org. Chem. 2018, 14, 2289–2294, doi:10.3762/bjoc.14.203

• corroboration came about by successfully encapsulating 5b, an oil under ambient conditions, in a metal-organic framework (5b@MOF). This non-trivial protocol rendered it amenable to X-ray diffraction studies confirming the aforementioned structural reassignment. From a theoretical standpoint, acyclic isomer 5b

Tetrathiafulvalene – a redox-switchable building block to control motion in mechanically interlocked molecules

• Hendrik V. Schröder and
• Christoph A. Schalley

Beilstein J. Org. Chem. 2018, 14, 2163–2185, doi:10.3762/bjoc.14.190

• this single compound. 6.2. Switchable catenanes in ordered arrays Besides ordered arrays on surfaces, on nanoparticles or in Langmuir–Blodgett films, a possibility to arrange bistable catenanes in an ordered fashion is to incorporate them into the rigid scaffold of a metal-organic framework (MOF) [107

Fluorogenic PNA probes

• Tirayut Vilaivan

Beilstein J. Org. Chem. 2018, 14, 253–281, doi:10.3762/bjoc.14.17

• restoration of the fluorescence in pretty much the same way as GO. Likewise, carbon nitride nanosheets [148] and a zirconium-based nano metal-organic framework (UiO-66) [149] behaved similarly. In addition, they have been successfully used in combination with PNA for monitoring of miRNA inside living cells

Phosphonic acid: preparation and applications

• Charlotte M. Sevrain,
• Mathieu Berchel,
• Hélène Couthon and
• Paul-Alain Jaffrès

Beilstein J. Org. Chem. 2017, 13, 2186–2213, doi:10.3762/bjoc.13.219

• identified as metal organic framework (MOF) or coordination polymers that are synthesized by reaction with a metallic salts (e.g., copper [65], lanthanides [66]) under hydrothermal conditions [67][68] or by insertion of phosphonic acid in low dimensional inorganic materials like layered double hydroxide (LDH

Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I)

• Sem Raj Tamang and
• James D. Hoefelmeyer

Beilstein J. Org. Chem. 2016, 12, 2757–2762, doi:10.3762/bjoc.12.272

• ], and Cu [34][35][36][37]) or an aluminum-based metal-organic framework [38], and there are several reports of metal-free direct arylation reactions in which the reaction is promoted with 2–3 equivalents KO(t-Bu) and (typically) 10–30 mol % of an additive [39][40][41][42][43][44][45][46][47][48]. The

Hydroxy-functionalized hyper-cross-linked ultra-microporous organic polymers for selective CO₂ capture at room temperature

• Partha Samanta,
• Priyanshu Chandra and
• Sujit K. Ghosh

Beilstein J. Org. Chem. 2016, 12, 1981–1986, doi:10.3762/bjoc.12.185

• , H2 and O2 at room temperature. A high isosteric heat of adsorption (Qst) has been obtained for both materials because of strong interactions between polar –OH groups and CO2 molecules. Keywords: carbon dioxide capture; hyper-cross-linked polymer; metal-organic framework; microporous organic polymer

Cross-dehydrogenative coupling for the intermolecular C–O bond formation

• Igor B. Krylov,
• Vera A. Vil’ and
• Alexander O. Terent’ev

Beilstein J. Org. Chem. 2015, 11, 92–146, doi:10.3762/bjoc.11.13

• ]. The coupling of aldehydes and formamides with 2-substituted phenols was carried out in the presence of heterogeneous catalysts, such as CuO on α-Fe2O3-modified carbon nanotubes (a magnetically separable catalyst) [158] and the metal-organic framework Cu2(4,4’-biphenyldicarboxylate)2(4,4’-bipyridine