Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions

• Jun-Xian Gou,
• Yang Luo,
• Xi-Nan Yang,
• Wei Zhang,
• Ji-Hong Lu,
• Zhu Tao and
• Xin Xiao

Beilstein J. Org. Chem. 2021, 17, 2950–2958, doi:10.3762/bjoc.17.204

• : cucurbiturils; melamine; Schiff base; silver ion; Introduction Schiff bases [1] are usually synthesized by the condensation of amines and active carbonyl compounds, endowing them both nitrogen and oxygen donor atoms [2][3][4][5]. Schiff bases are not only easy to coordinate with various transition metal ions

One hundred years of benzotropone chemistry

• Arif Dastan,
• Haydar Kilic and
• Nurullah Saracoglu

Beilstein J. Org. Chem. 2018, 14, 1120–1180, doi:10.3762/bjoc.14.98

• method for the synthesis of 2-bromobenzotropone 26 starting from dihydronaphthalene (322) was also realized by Balci’s group (Scheme 54) [188]. After addition of dibromocarbene to 322, the obtained dibromocyclopropane 323 was submitted to silver ion-catalyzed ring expansion/hydrolysis in aqueous acetone

Encapsulation of biocides by cyclodextrins: toward synergistic effects against pathogens

• Véronique Nardello-Rataj and
• Loïc Leclercq

Beilstein J. Org. Chem. 2014, 10, 2603–2622, doi:10.3762/bjoc.10.273

• -CD concentration delay bacterial growth, the authors proposed a Trojan horse mechanism enhancing silver ion absorption inside the bacterial cell (Scheme 9). In 2010, George et al. reduced silver acetate with dodecylamine to obtain silver nanoparticles which were subsequently transferred from the

Synthesis and in silico screening of a library of β-carboline-containing compounds

• Kay M. Brummond,
• John R. Goodell,
• Matthew G. LaPorte,
• Lirong Wang and
• Xiang-Qun Xie

Beilstein J. Org. Chem. 2012, 8, 1048–1058, doi:10.3762/bjoc.8.117

• these cases, it was assumed that competing coordination of the heteroatom to the silver ion was an issue; however, attempts were not made to alter the reaction conditions for these substrates. Furthermore, conversion of the naphthalene-containing analogues 1{14} and 1{15} to their corresponding

Functionalization of anthracene: A selective route to brominated 1,4-anthraquinones

• Kiymet Berkil Akar,
• Osman Cakmak,
• Orhan Büyükgüngör and
• Ertan Sahin

Beilstein J. Org. Chem. 2011, 7, 1036–1045, doi:10.3762/bjoc.7.118

• Art and Science, Atatürk University, 25240, Erzurum, Turkey 10.3762/bjoc.7.118 Abstract Efficient and stereoselective syntheses are described for the preparation of 2,3,9,10-tetrabromo-1,4-dimethoxy-1,2,3,4-tetrahydroanthracenes 7, 8 and the corresponding 1,4-diol 17 by silver ion-assisted solvolysis

• hexabromides 2 and 3 (Scheme 1) [1]. These studies revealed that hexabromides 2 and 3 are good precursors for the preparation of anthracene oxides and methoxyanthracene derivatives by silver ion-induced substitution. Our previous studies revealed that aromatization of hexabromides 2 and 3 showed complete

• Br3 in compounds 7 and 8 induces E2 elimination to give compound 14 (Figure 1). For further functionalization of the anthracene skeleton, hexabromide 6 was subjected to silver ion-assisted hydrolysis in aqueous acetone. Interestingly, the substitution resulted in the stereoselective formation of

Donor-acceptor substituted phenylethynyltriphenylenes – excited state intramolecular charge transfer, solvatochromic absorption and fluorescence emission

• Ritesh Nandy and
• Sethuraman Sankararaman

Beilstein J. Org. Chem. 2010, 6, 992–1001, doi:10.3762/bjoc.6.112

• , 128.5, 128.4, 127.59, 127.58, 127.4, 127.3, 126.8, 123.5, 123.43, 123.41, 123.36, 123.31, 121.9, 90.2, 89.9 ppm; The mass spectrum was recorded as the silver ion adduct of 1a by adding silver triflate to a solution of 1a in acetonitrile prior to measurement. ESI Q-TOF MS m/z 435 [M + Ag]+ along with the

Anthracene coupled adenine for the selective sensing of copper ions

• Kumaresh Ghosh and
• Tanushree Sen

Beilstein J. Org. Chem. 2010, 6, No. 44, doi:10.3762/bjoc.6.44

• of the substituent at N9 position of adenine, a preferential coordination of Cu2+ ion at N7 over N1 or N3 is found to occur for bisadenine ligands [27]. Smaller substituents lead to simultaneous binding of silver ion at all the three centers. However, in this paper we wish to report that introduction

Synthesis and properties of calix[4]arene telluropodant ethers as Ag⁺ selective sensors and Ag⁺, Hg²⁺ extractants

• Yang Lu,
• Yuanyuan Li,
• Song He,
• Yan Lu,
• Changying Liu,
• Xianshun Zeng and
• Langxing Chen

Beilstein J. Org. Chem. 2009, 5, No. 59, doi:10.3762/bjoc.5.59

• concentration of silver ion is varied while that of the interfering ions such as Na+, K+, NH4+, Ca2+, Mg2+ are 0.1 M; Zn2+, Cu2+, Ni2+, Cd2+, Pb2+, Hg2+ are 0.01 M. According to this method, the potentiometric selectivity coefficients, K, can be evaluated from the potential measurements on solutions containing