Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• was possible to identify different types of interactions between Pt NPs and cerium oxide surfaces including electron transfer from Pt NPs to CeO2 and transport of oxygen atoms from ceria to Pt NPs, the latter occurring only when the ceria support surface is nanostructured [26]. In addition, thanks to

• rationalized the observed high activity of the material in direct methanol fuel cells [37]. Regarding the Ni-CeO2−x(111) system, a study of the methanol reaction revealed that the strong metal–support interactions between Ni and CeO2 determines the high selectivity for CO2 production, instead of the formation

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• spacing of 0.62 nm and weak van der Waals interactions between them. At a sodium ion intercalation potential of about 1.4 V vs Na/Na+, the thermodynamically preferred 2H-MoS2 phase transforms into the metastable 1T-MoS2 phase [3][4]. With further increase in the intercalated sodium concentration

Synthesis and magnetic transitions of rare-earth-free Fe–Mn–Ni–Si-based compositionally complex alloys at bulk and nanoscale

• Shabbir Tahir,
• Tatiana Smoliarova,
• Carlos Doñate-Buendía,
• Michael Farle,
• Natalia Shkodich and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 823–836, doi:10.3762/bjnano.16.62

• combinations that control the configurational entropy of mixing, phase, and free energy of the material. Consequently, the magnetic phase transition of CCAs can be tuned by altering their chemical composition because of the different elemental interactions [17]. A significant advantage of using CCAs is their

• higher transition temperature compared to the Ge-based CCA implies stronger magnetic interactions in the Al-based CCA, which are able to persist even at higher temperatures. The broader dip in the dM/dT–T curve, compared to the sharper drop seen in the Ge-based CCA, suggests that the magnetic ordering in

Supramolecular hydration structure of graphene-based hydrogels: density functional theory, green chemistry and interface application

• Hon Nhien Le,
• Duy Khanh Nguyen,
• Minh Triet Dang,
• Huyen Trinh Nguyen,
• Thi Bang Tam Dao,
• Trung Do Nguyen,
• Chi Nhan Ha Thuc and
• Van Hieu Le

Beilstein J. Nanotechnol. 2025, 16, 806–822, doi:10.3762/bjnano.16.61

• plays an important role in the stability and functionality of nanoscale structures. Van der Waals forces are supramolecular intermolecular interactions that govern the agglomeration of nanomaterials. Carbon nanostructures with π-conjugated systems (fullerene, carbon nanotube, and graphene) have π–π

• interactions, a type of van der Waals force, for supramolecular attraction [9]. Particularly, graphene sheets with a large surface area and π-conjugated network are likely to stack together through hydrophobic agglomeration and π–π interaction. Although π–π interactions are generally weaker than hydrogen

• , leading to facile brush coating on plastic films of polylactide (PLA). Dehydrated GO-SG-ZH coating is adhered to the PLA substrate through interfacial interactions. Furthermore, antibacterial activities, coating stability, and mechanical properties of the nanocomposite materials were investigated and

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• the as-prepared films is given in Supporting Information File 1, Figure S4. These differences are likely attributed to variations in solvent properties and particle interactions during deposition. The morphologies of the FeS2 thin films vary depending on the different synthesis and fabrication

• interactions with the material (FeS2 in this case) play a significant role in morphology. From the results obtained, it can be concluded that high-polarity solvents (e.g., methanol, ethanol) tend to promote faster nucleation and growth, leading to larger NPs (≈26 nm), whereas low-viscosity and highly volatile

Changes of structural, magnetic and spectroscopic properties of microencapsulated iron sucrose nanoparticles in saline

• Sabina Lewińska,
• Pavlo Aleshkevych,
• Roman Minikayev,
• Anna Bajorek,
• Mateusz Dulski,
• Krystian Prusik,
• Tomasz Wojciechowski and
• Anna Ślawska-Waniewska

Beilstein J. Nanotechnol. 2025, 16, 762–784, doi:10.3762/bjnano.16.59

• coupling between Fe ions, (iii) the analysis of interactions between the magnetic core and the sucrose shell and their impact on core surface magnetic moments, (iv) the impact of the core surface and nonmagnetic additives on the saturation magnetization of the investigated compound [19], and (v) the

• consequences of the dissolution process in terms of microstructural changes and interactions between iron ions. The paper is organized as follows: the “Result and Discussion” section is divided into subsections relating to the individual measurement technique used, presenting measurement results and their

• the microcapsule as a magnetic system, it is expected that the sucrose shell will prevent or significantly diminish interactions between nanoparticles, also probably modifies the surface state of the core. To understand the low-temperature magnetic state of the FS0 sample, the zero field cooled

Serum heat inactivation diminishes ApoE-mediated uptake of D-Lin-MC3-DMA lipid nanoparticles

• Demian van Straten,
• Luuk van de Schepop,
• Rowan Frunt,
• Pieter Vader and
• Raymond M. Schiffelers

Beilstein J. Nanotechnol. 2025, 16, 740–748, doi:10.3762/bjnano.16.57

• surface of nanoparticles after administration has garnered substantial attention due to the significant effects it has on their performance. Lipid nanoparticles (LNPs) depend on protein corona formation to mediate their targeting. Such protein–nanoparticle interactions are often initially studied using in

• subsequent cell-nanoparticle interactions remains unclear. Here, the effect of FCS heat inactivation on the in vitro behavior of the clinically applied and most studied D-Lin-MC3-DMA (MC3) LNPs was investigated and compared to LNPs containing a different ionizable lipid, C12-200 (C12). Moreover, mechanisms

• by which FCS heat inactivation could affect cellular interactions with LNPs were studied in detail. Materials and Methods Buffers, reagents, materials Phosphate buffered saline (PBS), bovine serum albumin (BSA), thioflavin T (ThT), cholesterol and distearoylphosphatidylcholine (DSPC) were purchased

Synthesis of a multicomponent cellulose-based adsorbent for tetracycline removal from aquaculture water

• Uyen Bao Tran,
• Ngoc Thanh Vo-Tran,
• Khai The Truong,
• Dat Anh Nguyen,
• Quang Nhat Tran,
• Huu-Quang Nguyen,
• Jaebeom Lee and
• Hai Son Truong-Lam

Beilstein J. Nanotechnol. 2025, 16, 728–739, doi:10.3762/bjnano.16.56

• were characterized, and the TC adsorption efficiency of PGC was assessed using high-performance liquid chromatography–mass spectroscopy (HPLC-MS). Elemental analysis of PGC identified four key mechanisms governing its endothermic TC adsorption mechanism: surface complexation, electrostatic interactions

• , hydrogen bonding, and CH–π interactions, with surface complexation between Ca2+ and TCs being dominant. Batch adsorption experiments conducted to examine the factors influencing adsorption capacity revealed that PGC achieved up to 70% TC removal efficiency at an adsorbent dosage of 40 mg and an initial TC

• spectrum, the sample matrix, and the radiation intensity. Activated carbon is a conventional approach [10][11], however, a major drawback of activated carbon is its incomplete recovery after adsorption. Because adsorption primarily relies on physical interactions such as hydrogen bonding interactions

Nanostructured materials characterized by scanning photoelectron spectromicroscopy

• Matteo Amati,
• Alexey S. Shkvarin,
• Alexander I. Merentsov,
• Alexander N. Titov,
• María Taeño,
• David Maestre,
• Sarah R. McKibbin,
• Zygmunt Milosz,
• Ana Cremades,
• Rainer Timm and
• Luca Gregoratti

Beilstein J. Nanotechnol. 2025, 16, 700–710, doi:10.3762/bjnano.16.54

• surfaces. The characterization of the building blocks is of paramount importance to deeply understand their functionalities and mutual interactions when they are part of a nanostructured body. The building blocks may differ in their atomic structure, crystallographic orientation, chemical composition, and

High-temperature epitaxial growth of tantalum nitride thin films on MgO: structural evolution and potential for SQUID applications

• Michelle Cedillo Rosillo,
• Oscar Contreras López,
• Jesús Antonio Díaz,
• Agustín Conde Gallardo and
• Harvi A. Castillo Cuero

Beilstein J. Nanotechnol. 2025, 16, 690–699, doi:10.3762/bjnano.16.53

• the displacement of O2, effectively reducing the incorporation of O₂ within the thin films. The interaction between a laser-generated plume and the surrounding background gas is a dynamic and complex process significantly influenced by the background gas pressure. Understanding these interactions is

• interactions and a relatively unperturbed plume expansion. As the background pressure increases, the collision frequency between plume particles and background gas molecules rises. This leads to more pronounced interactions, including increased scattering, energy transfer, and chemical reactions. In the

The impact of tris(pentafluorophenyl)borane hole transport layer doping on interfacial charge extraction and recombination

• Konstantinos Bidinakis and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 678–689, doi:10.3762/bjnano.16.52

• charge extraction takes place might be affected by factors such as ion accumulation. In a previous study, we demonstrated that the position of the potential drop can be significantly shifted into the transport layers, due to ionic interactions [15]. In the case of the cells incorporating spiro-OMeTAD

Colloidal few layered graphene–tannic acid preserves the biocompatibility of periodontal ligament cells

• Teissir Ben Ammar,
• Naji Kharouf,
• Dominique Vautier,
• Housseinou Ba,
• Nivedita Sudheer,
• Philippe Lavalle and
• Vincent Ball

Beilstein J. Nanotechnol. 2025, 16, 664–677, doi:10.3762/bjnano.16.51

• employed to determine structure and surface functionalities. Second, by employing TA, we aim to develop graphene layers rich in polyphenols to serve as a bioactive interface for cellular interactions. Given that TA possesses potential antioxidant properties, we assessed the in vitro free radical scavenging

• , characterized by numerous hydroxy groups, is proposed to potentially form non-covalent interactions, such as π–π stacking, with the carbon network and oxygen atoms of graphite [16][20]. This interaction could exfoliate graphite, resulting in a stable colloidal dispersion of functionalized graphene sheets. The

• groups into the graphene structure. In our scenario, the integration of mixing and ultrasonication greatly aided the homogenization process and improved the interactions at the molecular level between the functional groups of tannic acid and the carbon layers of graphene, resulting in defects mainly

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• frequencies and beyond. Our results show a significant reduction of signal background from long-range electrostatic interactions, resulting in highly localized measurements. Combined with refined tip–sample capacitance models, MFH-EFM will enhance the precision of quantitative studies on dielectric effects in

• of the long-range interactions from tip cone and cantilever in the C′ signal. Thus, the overall impact of the local surface dielectric properties under the tip apex is reduced as compared to the impact of the dielectric properties probed by tip cone and cantilever (see Figure 3). Imaging C′ versus C

• leads to a significant reduction of signal background, which results in higher locality of the measurements with less cross talk. This is due to the fact that the second capacitance gradient is less affected by long-range interactions, such as those from tip cone and lever. We demonstrate the reliable

Focused ion and electron beams for synthesis and characterization of nanomaterials

• Aleksandra Szkudlarek

Beilstein J. Nanotechnol. 2025, 16, 613–616, doi:10.3762/bjnano.16.47

• deposition techniques, this thematic issue includes studies on low-energy electron interactions with metal(II) bis(acetylacetonate) complexes [5]. Another molecule investigated for its gas-phase fragmentation mechanism via dissociative ionization and dissociative electron attachment is [Au(CH3)2Cl]2. Studies

• ion beam interactions [15]. In addition, the extension of the continuum model has proven useful in predicting the outcomes of ion beam milling processes in multilayered systems, as demonstrated in the case of the Si/SiO2/Pt system [16]. To identify the current state of the technology and routes

• , Aleksandra Szkudlarek Krakow, April 2025 Complexity of interactions among electrons, ions, and precursor molecules behind fabrication of functional 3D nanostructures.

Polyurethane/silk fibroin-based electrospun membranes for wound healing and skin substitute applications

• Iqra Zainab,
• Zohra Naseem,
• Syeda Rubab Batool,
• Muhammad Waqas,
• Ahsan Nazir and
• Muhammad Anwaar Nazeer

Beilstein J. Nanotechnol. 2025, 16, 591–612, doi:10.3762/bjnano.16.46

• the body [67]. Yildiz et al. used polycaprolactone (PCL)/SF to develop nanofibers as an improved skin substitute for treating chronic wounds or burns. The addition of SF increased tensile strength and Young’s modulus through intermolecular interactions. Results showed that the PCL/SF nanofibers had

• for tissue engineering, particularly for bone, ligaments, tendons, blood vessels, and cartilage, where mechanical properties and biological interactions are crucial. SF can be fabricated into foams, films, fibers, meshes, and hydrogels, as shown in Figure 4 [97]. Films made of fibroin and collagen

• surgery [113]. Polyurethane The biocompatibility of polyurethane (PU) makes it well suited for interactions with biological fluids and tissues [114]. Its ability to imitate the mechanical characteristics of natural tissues further enhances its appeal in biomedical applications [115]. The surface of PU can

Feasibility analysis of carbon nanofiber synthesis and morphology control using a LPG premixed flame

• Iftikhar Rahman Bishal,
• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Faizuan Bin Abdullah,
• I Putu Tedy Indrayana and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2025, 16, 581–590, doi:10.3762/bjnano.16.45

• sidewalls, while the G′ peak at 2500–2900 cm−1 represents photon–phonon interactions [22]. To the best of our knowledge, the present study describes the first flame synthesis using a LPG premixed flame and a spherical substrate for CNF growth. The characteristics of the LPG premixed flame are studied with

Nanomaterials in targeting amyloid-β oligomers: current advances and future directions for Alzheimer's disease diagnosis and therapy

• Shiwani Randhawa,
• Trilok Chand Saini,
• Manik Bathla,
• Rahul Bhardwaj,
• Rubina Dhiman and
• Amitabha Acharya

Beilstein J. Nanotechnol. 2025, 16, 561–580, doi:10.3762/bjnano.16.44

• emphasized the importance of accurately identifying AβOs in patient samples, enhancing the potential for timely intervention. In recent years, nanomaterials (NMs) have emerged as promising agents for addressing AβOs regarding their multivalent interactions, which can more effectively detect and inhibit AβO

• interactions between n-mers (oligomers formed from a defined number of monomers), or from non-specific interactions, akin to micelles. The precise mechanisms underlying the formation of AβOs during the growth of AβFs remain elusive. However, researchers have identified three main pathways to explain this

• . employed a combination of experimental and computational approaches to investigate the interaction between PEGylated NPs and Aβ monomers. Their findings revealed that surface interactions between NPs and Aβ monomers effectively inhibited the formation of AβOs [59]. Building upon their previous research

Retrieval of B1 phase from high-pressure B2 phase for CdO nanoparticles by electronic excitations in Cd_xZn_1−xO composite thin films

• Arkaprava Das,
• Marcin Zając and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2025, 16, 551–560, doi:10.3762/bjnano.16.43

• transfer to the electronic system occurs through electron–electron interactions, followed by transference to the lattice atomic system via electron–phonon correlation [20][21]. Along the ion trajectory, a cylindrical region is generated, characterized by temperature exceeding the melting point of the

Zeolite materials with Ni and Co: synthesis and catalytic potential in the selective hydrogenation of citral

• Inocente Rodríguez-Iznaga,
• Yailen Costa Marrero,
• Tania Farias Piñeira,
• Céline Fontaine,
• Lexane Paget,
• Beatriz Concepción Rosabal,
• Arbelio Penton Madrigal,
• Vitalii Petranovskii and
• Gwendoline Lafaye

Beilstein J. Nanotechnol. 2025, 16, 520–529, doi:10.3762/bjnano.16.40

• Ni2+ isolated cations, attributed to synergistic interactions that weakened the cation–framework binding. Catalytic activity tests showed that nickel species were primarily responsible for citronellal formation. Among all materials, the bimetallic CoNiIE catalyst, prepared by IE, was the only one to

• produce unsaturated alcohols, suggesting that synergistic Ni–Co interactions played a role in their formation. Keywords: citral hydrogenation; cobalt–nickel mixture; impregnation; ion exchange; natural zeolite; Introduction Numerous publications in the literature highlight zeolites modified with

Water in nanoporous hexagonal boron nitride nanosheets: a first-principles study

• Juliana A. Gonçalves,
• Ronaldo J. C. Batista and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2025, 16, 510–519, doi:10.3762/bjnano.16.39

• graphene membranes interacting with water, where wrinkles significantly impact the mechanical response of the membranes when filled with water on a platform. Conclusion Our investigation of pores in a free-standing hexagonal boron nitride monolayer sheds light on the intricate interactions between 2D

• type of pore can alter the hydrophobicity of h-BN and influence the flow of water through it. Moreover, the formation of a hydrogen bond with the N–H-terminated surface in rhombic pores, which is absent in interactions with the B–N-terminated surface, may lead to asymmetries in water flow through the

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• the target material. This balance highlights the importance of electronic and nuclear interactions in the energy transfer processes during ion implantation. Furthermore, of the total energy of 15 keV from a single nitrogen ion, 8.5 keV produce ionization, while 6.2 keV generate phonons, and 0.29 keV

• create damage within the target material, as demonstrated in Figure 1C. These findings highlight the significant interactions between the nitrogen ions and the molybdenum target material during the implantation process, providing valuable insights into the mechanisms that govern ion implantation and the

• of the as-deposited and N2+-implanted Mo films increases from 13.22 to 15.24 nm and from 11.92 to 14.42 nm with an increase in thickness from 150 to 300 nm, respectively. This variation may relate to several factors involving film growth and substrate interactions. Thicker films (i.e., 250 and 300 nm

Impact of adsorbate–substrate interaction on nanostructured thin films growth during low-pressure condensation

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2025, 16, 473–483, doi:10.3762/bjnano.16.36

• elastic adsorbate–substrate interactions in processes of nanostructuring of thin films during low-pressure condensation in the framework of theoretical approaches and numerical simulations. It will be shown that an increase in the elastic interaction strength induces first-order transitions and pattern

• formation. We simulate deposition on one- and multicomponent substrates with different strengths of adsorbate–substrate interactions. We will show that an increase in the strength of adsorbate–substrate interactions stimulates the formation of stable surface structures during deposition, which leads to an

• increase in its coverage and the formation of a smaller number of adsorbate islands of larger size. At elevated adsorption rates, an increase in adsorbate–substrate interactions results in the transformation of the surface morphology and the formation of percolating adsorbate structures. Deposition onto

Synthetic-polymer-assisted antisense oligonucleotide delivery: targeted approaches for precision disease treatment

• Ana Cubillo Alvarez,
• Dylan Maguire and
• Ruairí P. Brannigan

Beilstein J. Nanotechnol. 2025, 16, 435–463, doi:10.3762/bjnano.16.34

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• . Electrochemical techniques comparatively offer quick, portable, sensitive, and inexpensive basic equipment for heavy metal detection. The interactions between Ag@ZnO NRs and lead were studied using electrochemical methods. The prepared lead sensor using Ag@ZnO NRs show a very low detection limit and a very high

Biomimetics and bioinspired surfaces: from nature to theory and applications

• Rhainer Guillermo Ferreira,
• Thies H. Büscher,
• Manuela Rebora,
• Poramate Manoonpong,
• Zhendong Dai and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2025, 16, 418–421, doi:10.3762/bjnano.16.32

• environmental pressures. Such pressures involve intricate interactions between surface structures and the environment across different scales, including nano-, micro-, and macroscales. Biomimetics aims at making use of understanding how these adaptations and the particular material properties of these surfaces