Defects and defect-mediated engineering of two-dimensional materials: challenges and open questions

• Arkady V. Krasheninnikov,
• Matthias Batzill,
• Anouar-Akacha Delenda,
• Marija Drndić,
• Chris Ewels,
• Katharina J. Franke,
• Mahdi Ghorbani-Asl,
• Alexander Holleitner,
• Ado Jorio,
• Ute Kaiser,
• Daria Kieczka,
• Hannu-Pekka Komsa,
• Jani Kotakoski,
• Manuel Längle,
• David Lamprecht,
• Yun Liu,
• Steven G. Louie,
• Janina Maultzsch,
• Thomas Michely,
• Katherine Milton,
• Anna Niggas,
• Hanako Okuno,
• Joshua A. Robinson,
• Marika Schleberger,
• Bruno Schuler,
• Alexander Shluger,
• Kazu Suenaga,
• Kristian S. Thygesen,
• Richard A. Wilhelm,
• E. Harriet Åhlgren and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2026, 17, 454–488, doi:10.3762/bjnano.17.31

First-principles study on elastic properties of Cu, (Cu_1−x,Ni_x)₃Sn and interfacial mechanical properties of (Cu_1−x,Ni_x)₃Sn/Cu in the lead-free solder joint

• Guomin Hua

Beilstein J. Nanotechnol. 2026, 17, 428–439, doi:10.3762/bjnano.17.29

• AU of Cu is 2.77. It indicates that Cu is intrinsically anisotropic, although Cu has a FCC structure. In contrast to the anisotropy of Cu, the AU of orthorhombic Cu3Sn is 0.052. This implies that Cu3Sn is locally elastically isotropic. After Ni alloying, the AU of (Cu0.9Ni0.1)3Sn increases to 0.160

Beam shaping techniques for pulsed laser ablation in liquids: Unlocking tunable control of nanoparticle synthesis in liquids

• Sergio Molina-Prados,
• Nadezhda M. Bulgakova,
• Alexander V. Bulgakov,
• Jesus Lancis,
• Gladys Mínguez Vega and
• Carlos Doñate-Buendia

Beilstein J. Nanotechnol. 2026, 17, 309–342, doi:10.3762/bjnano.17.22

• structures. Second, the cavitation bubble generated during ablation and its subsequent oscillations play a critical role. Under cylindrical focusing, the cavitation bubble adopts an elongated shape that differs from the typical spherical morphology observed with circular beams [144]. This anisotropic

• geometry alters the internal pressure distribution and collapse dynamics, affecting the interaction between the plasma plume, shock waves, and the surrounding liquid. Consequently, both the light-induced welding and the anisotropic cavitation bubble dynamics are key factors determining the formation of the

• ], while doughnut-shaped beams suppress aggregation of Au NPs, yielding diameters of ca. 30 nm versus broad, high-tail distributions under Gaussian irradiation [158]. Cylindrical focusing further enables anisotropic structures such as Ag nanoribbons up to 0.6–1.0 µm in length [140]. Altogether, these

Advancing nanolithography: a comprehensive review of materials for local anodic oxidation with AFM

• Matteo Lorenzoni

Beilstein J. Nanotechnol. 2026, 17, 275–291, doi:10.3762/bjnano.17.19

• such pattering capabilities is reported in Figure 6 showing a 35 nm constriction fabricated on few-layer WSe2, before and after etching in water. Additionally, the environmental sensitivity of TMDs, such as the anisotropic oxidation of 1T′ MoTe2 under humid conditions, has been exploited to achieve

• complexities and might reduce dependency on trial-and-error methodologies. For example, numerical simulations can be employed to explore complex reaction mechanisms involved in nanomanufacturing processes at the nanoscale. This approach has recently been used to clarify the anisotropic effects observed during

Multilayered hyperbolic Au/TiO₂ nanostructures for enhancing the nonlinear response around the epsilon-near-zero point

• Fernando Arturo Araiza-Sixtos,
• Mauricio Gomez-Robles,
• Rafael Salas-Montiel and
• Raúl Rangel-Rojo

Beilstein J. Nanotechnol. 2026, 17, 251–261, doi:10.3762/bjnano.17.17

• available materials in nature that present hyperbolic dispersion, such as bismuth and 2D graphene sheets [2], indium tin oxide (ITO) [3], and aluminum-doped zinc oxide (AZO) [4]. HMMs are highly anisotropic and exhibit some interesting properties, including strong enhancement of spontaneous emission

Micro- and nanoscale effects in biological and bioinspired materials and surfaces

• Thies H. Büscher,
• Rhainer Guillermo Ferreira,
• Manuela Rebora and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2026, 17, 214–217, doi:10.3762/bjnano.17.14

• characterization of functional plant tissues [19] integrating experiments and finite element models, and animal tissues [20] incorporating molecular dynamics and finite element methods. Investigating the anisotropic hygroscopic behavior of the involved materials in bending in pine cone scales, Ulrich et al. [19

Structure-dependent thermochromism of PAZO thin films: theory and experiment

• Georgi Mateev,
• Dean Dimov,
• Nataliya Berberova-Buhova,
• Nikoleta Kircheva,
• Todor Dudev,
• Ludmila Nikolova,
• Elena Stoykova,
• Keehoon Hong,
• Dimana Nazarova,
• Silvia Angelova and
• Lian Nedelchev

Beilstein J. Nanotechnol. 2026, 17, 186–199, doi:10.3762/bjnano.17.12

• had a 45° linear polarization. The pump beam is partially absorbed by the polymer film and provokes reorientation of PAZO molecules perpendicular to the vertical polarization of the light, so the isotropic films become anisotropic. Using the polarimeter, we tracked the changes in polarization of the

Improving magnetic properties of Mn- and Zn-doped core–shell iron oxide nanoparticles by tuning their size

• Dounia Louaguef,
• Ghouti Medjahdi,
• Sébastien Diliberto,
• Klaus M. Seemann,
• Thomas Gries,
• Joelle Bizeau,
• Damien Mertz,
• Eric Gaffet and
• Halima Alem

Beilstein J. Nanotechnol. 2025, 16, 2285–2295, doi:10.3762/bjnano.16.157

• applications. The improved magnetic hyperthermia performance observed in the Zn0.4Fe2.6O4@MnFe2O4 core–shell nanoparticles can be attributed to a combination of factors, including the increased particle size, enhanced magnetic moment, and the presence of a moderately anisotropic MnFe2O4 shell. It is important

Chiral plasmonic nanostructures fabricated with circularly polarized light

• Tian Qiao and
• Ming Lee Tang

Beilstein J. Nanotechnol. 2025, 16, 2245–2264, doi:10.3762/bjnano.16.154

• photochemical reactions. This tip-preferred growth aligns with the colloidal synthesis of anisotropic Ag NCs from pentagonal seeds in the presence of CTAB/CTAC [104][105]. Growth of the hook at the tips of the AgNR nanostructures leads to a larger EM field enhancement near the tips and EM field dissymmetry on

Molecular and mechanical insights into gecko seta adhesion: multiscale simulations combining molecular dynamics and the finite element method

• Yash Jain,
• Saeed Norouzi,
• Tobias Materzok,
• Stanislav N. Gorb and
• Florian Müller-Plathe

Beilstein J. Nanotechnol. 2025, 16, 2055–2076, doi:10.3762/bjnano.16.141

• structure similar to a fiber-reinforced elastomer, with a fibrillar nature that leads to anisotropic mechanical properties [40][41][42]. Rather than explicitly resolving individual fibers and the surrounding amorphous matrix, we represented the spatula with a coarse-grained bead network whose anisotropic

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• probes with free rotation are characterized by a spectrum with three narrow lines [36][37]. Anisotropic broadening of the spectrum is indicative for retardation of rotation due to additional intermolecular interactions. The hyperfine coupling of the electron spin with the nuclear spin of 15N provides

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• of their impact on the conditions for anisotropic NP formation and growth. The description of the methods developed for the control over nanomaterial morphology is summarized by the vision of the current challenges and development routes of laser ablation in liquids. Keywords: laser ablation in

• achieved. Despite recent advances, there is still a gap in understanding the routes for shape control of the forming nanomaterials hindered by the limited information about the mechanisms of laser ablation process in liquids. The demand for anisotropic nanomaterials is growing, associated with the rapid

• sustainability of the approach due to the introduction of purification steps. In PLAL, the conditions created during laser ablation synthesis are favouring the formation and growth of near-spherical NPs. To date, much less research is performed regarding shape-controlled formation of anisotropic materials. For

Quantum circuits with SINIS structures

• Mikhail Tarasov,
• Mikhail Fominskii,
• Aleksandra Gunbina,
• Artem Krasilnikov,
• Maria Mansfeld,
• Dmitrii Kukushkin,
• Andrei Maruhno,
• Valeria Ievleva,
• Mikhail Strelkov,
• Daniil Zhogov,
• Konstantin Arutyunov,
• Vyacheslav Vdovin,
• Vladislav Stolyarov and
• Valerian Edelman

Beilstein J. Nanotechnol. 2025, 16, 1931–1941, doi:10.3762/bjnano.16.134

• deposition plants with thermal or e-beam evaporation. A much more available and simple deposition equipment is magnetron sputtering, but it provides only isotropic deposition, which is incompatible with anisotropic shadow evaporation. The practical solution for a magnetron sputtering is selective etching of

Beyond the bilayer: multilayered hygroscopic actuation in pine cone scales

• Kim Ulrich,
• Max David Mylo,
• Tom Masselter,
• Fabian Scheckenbach,
• Sophia Fischerbauer,
• Martin Nopens,
• Silja Flenner,
• Imke Greving,
• Linnea Hesse and
• Thomas Speck

Beilstein J. Nanotechnol. 2025, 16, 1695–1710, doi:10.3762/bjnano.16.119

• Thünen Institute of Wood Research, Hamburg, Germany Institute of Materials Physics, Helmholtz-Zentrum Hereon, Geesthacht, Germany 10.3762/bjnano.16.119 Abstract The anisotropic hygroscopic behavior of pine cone scales and its effect on bending motion, with implications for bioinspired actuation, is

• representing the deformation from one state to the other. Using this displacement field allows for the calculation of a strain tensor field, which describes the axis-dependent hygroscopic expansion [29]. Incorporating the anisotropic swelling and shrinkage behavior into in silico models of the pine cone scale

• tissue involved and their arrangement, are very limited. The aim of this work is to characterize the anisotropic hygroscopic behavior of pine cone scale tissues and its effect on the bending motion. To this end, we first characterize their sorption behavior using gravimetric water uptake measurements

Bioinspired polypropylene-based functionally graded materials and metamaterials modeling the mistletoe–host interface

• Lina M. Rojas González,
• Naeim Ghavidelnia,
• Christoph Eberl and
• Max D. Mylo

Beilstein J. Nanotechnol. 2025, 16, 1592–1606, doi:10.3762/bjnano.16.113

• the data sheet values were obtained by testing injection-molded test specimens, whereas our specimens were produced by hot pressing. Each method has an effect on the direction of the glass fibers; injection molding results in an anisotropic orientation of the fibers, whereas hot pressing results in

• isotropic orientations [48]. An anisotropic fiber orientation along the direction of tensile testing increases the Young’s modulus compared to an isotropic alignment [49], which also explains why the difference between the pure PP and the glass fiber-reinforced polymer was rather small in our specimens. The

Photochemical synthesis of silver nanoprisms via green LED irradiation and evaluation of SERS activity

• Tuan Anh Mai-Ngoc,
• Nhi Kieu Vo,
• Cong Danh Nguyen,
• Thi Kim Xuan Nguyen and
• Thanh Sinh Do

Beilstein J. Nanotechnol. 2025, 16, 1417–1427, doi:10.3762/bjnano.16.103

• applications. Keywords: light-emitting diodes (LEDs); photochemical synthesis; silver nanoprisms; surface-enhanced Raman scattering (SERS); trisodium citrate; Introduction Anisotropic silver nanoparticles (ASNPs) have attracted increasing attention from research groups worldwide due to their potential

• step of the entire process [3]. During this stage, small silver nanoparticles (seeds) can combine and evolve into anisotropic nanostructures through a chemical process in the presence of hydrogen peroxide (H2O2) and sodium borohydride, commonly referred to as the Mirkin method [4]. Recently

• –vis spectrum exhibited a single absorption peak at 402 nm, characteristic of the in-plane dipole (IPD) resonance of spherical silver nanoparticles. The solution retained its yellow color, indicating that the seed morphology remained largely unchanged and that no formation of anisotropic silver

Electronic and optical properties of chloropicrin adsorbed ZnS nanotubes: first principle analysis

• Prakash Yadav,
• Boddepalli SanthiBhushan and
• Anurag Srivastava

Beilstein J. Nanotechnol. 2025, 16, 1184–1196, doi:10.3762/bjnano.16.87

• than strong charge transfer or dipole interactions [73]. The anisotropic nature of ZnS NTs plays a significant role in the observed orientation-dependent optical responses. Adsorption along orientations such as A induces stronger dipole interactions and greater charge transfer, leading to more

• pronounced bandgap narrowing and enhanced visible light absorption. This anisotropic behavior is consistent with theoretical and experimental studies on nanotube systems, where adsorption-induced optical changes are highly dependent on molecular orientation and the local electronic environment [74]. The

• ), indicating weaker interaction. Orientation C shows multiple peaks across the ultraviolet and visible ranges, suggesting complex adsorption behavior. Orientation D exhibits negligible shifts, dominated by van der Waals forces. These findings demonstrate the anisotropic optical behavior of ZnS NTs, with

Crystalline and amorphous structure selectivity of ignoble high-entropy alloy nanoparticles during laser ablation in organic liquids is set by pulse duration

• Robert Stuckert,
• Felix Pohl,
• Oleg Prymak,
• Ulrich Schürmann,
• Christoph Rehbock,
• Lorenz Kienle and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 1141–1159, doi:10.3762/bjnano.16.84

• amorphous particles [34]. Additionally, a few sharper reflections from unknown phases, having crystallite sizes between 40 to 50 nm (after anisotropic refinement) could be detected (marked by red arrows in Figure 2B), but due to their weak intensity, an identification was not possible. The presence of those

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

• liquid crystal semiconductors that exhibit anisotropic conduction of electronic charge carriers. The efficient transport of electronic carriers has been confirmed in nematic, chiral nematic, smectic, and columnar phases. It has been demonstrated that liquid crystals comprising extended π-conjugated units

• system reverts to its original state. It was demonstrated that the gold nanorods are capable of significant lateral diffusion, exhibiting a considerable distance of movement. Hybrid materials comprising anisotropic nanoparticles and polymer brushes were designed and subjected to dynamic control

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74

• conventional TTM that describes energy transfer between electrons and the lattice. Although the dynamics of photoexcited hot electrons were expected to uniformly affect the entire specimen within a few picoseconds, the experiment instead observed inhomogeneous and laser-polarization-dependent anisotropic

• key contributors to the observed anisotropic melting behavior. These findings, corroborated by MD simulations that incorporate the TTM (TTM-MD), suggest that energy accumulation in localized hotspots drives anisotropic melting. Nevertheless, direct experimental evidence linking electronic and ionic

Characterization of ion track-etched conical nanopores in thermal and PECVD SiO₂ using small angle X-ray scattering

• Shankar Dutt,
• Rudradeep Chakraborty,
• Christian Notthoff,
• Pablo Mota-Santiago,
• Christina Trautmann and
• Patrick Kluth

Beilstein J. Nanotechnol. 2025, 16, 899–909, doi:10.3762/bjnano.16.68

• analyzing the complex highly anisotropic two-dimensional SAXS patterns of the pores by reducing the analysis to two orthogonal one-dimensional slices of the data. The simultaneous fit of the data enables an accurate determination of the pore geometry and size distribution. The analysis reveals substantial

Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• the dangling bonds and producing the sp2 carbon on the free diamond surface, or diffuse into the Ni bulk, feeding the graphite formation from the side of the catalytic particle [19]. Comparing the morphology of Ni-coated SCDs annealed under similar conditions revealed the anisotropic nature of both

• ). In particular, on the rectangular (110) faces, nickel particles are flatter and more evenly distributed than those on the triangular (111) face. Previous studies showed that the etching of diamond through the reaction with Ni during annealing is an anisotropic process [19][35][36]. In particular, the

• (111) surface, indicating anisotropic diamond etching during heating. Despite these differences, the Raman spectra recorded from the different faces of the annealed microcrystallites were similar, indicating that the carbon coating consisted of graphitic multilayers with a similar structure. The (110

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• hybrid anodes based on MoS2. The diffusion of sodium ions in layered MoS2 is highly anisotropic. It is fast along the basal planes and is not possible through defect-free layers [3]. Thus, when the interlayer channels coincide with the Na+ movement paths, the diffusion distance is shortened, resulting in

Performance optimization of a microwave-coupled plasma-based ultralow-energy ECR ion source for silicon nanostructuring

• Joy Mukherjee,
• Safiul Alam Mollick,
• Tanmoy Basu and
• Tapobrata Som

Beilstein J. Nanotechnol. 2025, 16, 484–494, doi:10.3762/bjnano.16.37

• the increase in bombardment time, more silicon and oxygen atoms are sputtered. Due to the presence of the ripples, the surface becomes anisotropic. The consequence of such an anisotropic nature of the surface is investigated and discussed in the upcoming section. Application of nanopatterned Si

Vortex lattices of layered HTSCs at different vortex–vortex interaction potentials

• Valerii P. Lenkov,
• Anastasia N. Maksimova,
• Anna N. Moroz and
• Vladimir A. Kashurnikov

Beilstein J. Nanotechnol. 2025, 16, 362–370, doi:10.3762/bjnano.16.27

• interaction potential of which is identical in shape to the interaction potential in ferromagnetic superconductors. The modeling results can also be useful for analyzing vortex configurations in a layered anisotropic HTSC in an inclined magnetic field. Methods Calculations were performed using the Monte Carlo

• method within the framework of a two-dimensional model of a layered HTSC [24][25][26]. Most of the HTSCs applicable in practice are strongly anisotropic substances characterized by the anisotropy parameter γ > 10. Examples of such HTSCs are YBa2Cu3O7−δ (γ ≈ 10) and Bi2Sr2CaCu2O8−δ (γ ≈ 200) [1]. Such