Fabrication and testing of polymer microneedles for transdermal drug delivery

• Vahid Ebrahiminejad,
• Zahra Faraji Rad,
• Philip D. Prewett and
• Graham J. Davies

Beilstein J. Nanotechnol. 2022, 13, 629–640, doi:10.3762/bjnano.13.55

• photoresist was drop cast onto an indium tin oxide (ITO) glass substrate prior to starting the printing process. A dip-in laser lithography (DiLL) objective (25× magnification, NA = 0.8) was used for printing, after which the MN array was washed in propylene glycol methyl ether acetate (PGMEA) for 10 minutes

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• disulfide (MoS2) was prepared on substrates coated with fluorine-doped tin oxide (FTO) to substitute the platinum counter electrode (CE) for dye-sensitized solar cells (DSSCs). Herein, we synthesized layered and honeycomb-like MoS2 thin films via the cyclic voltammetry (CV) route. Thickness and morphology

• , 25 μm), 18NR-T transparent titania paste (particle size of 20 nm), 18NR-AO active opaque titania paste (particle sizes of 20 and 450 nm), fluorine-doped tin oxide (FTO, TEC8 glass plates, 8 Ω·cm−2, 2.2 mm thickness), and N719 industry standard dye (N719) were purchased from Dyesol (Australia). All

Selected properties of Al_xZn_yO thin films prepared by reactive pulsed magnetron sputtering using a two-element Zn/Al target

• Witold Posadowski,
• Artur Wiatrowski,
• Jarosław Domaradzki and
• Michał Mazur

Beilstein J. Nanotechnol. 2022, 13, 344–354, doi:10.3762/bjnano.13.29

• : aluminium zinc oxide; magnetron sputtering; thin film; transparent conducting oxide; transparent electronics; Introduction Aluminium-doped zinc oxide (AZO) is a potential alternative to indium tin oxide (ITO) for transparent conducting oxide (TCO) electrodes in transparent electronic and photovoltaic

Investigation of a memory effect in a Au/(Ti–Cu)Ox-gradient thin film/TiAlV structure

• Damian Wojcieszak,
• Jarosław Domaradzki,
• Michał Mazur,
• Tomasz Kotwica and
• Danuta Kaczmarek

Beilstein J. Nanotechnol. 2022, 13, 265–273, doi:10.3762/bjnano.13.21

• ]. The most commonly used material in resistive switching devices is TiO2−x [33][34][35][36][37][38]. In addition to the oxide layers, the material used for metal electrodes plays another crucial role in the resistive switching mechanism. Usually, materials such as Au, Ag, Ni, Ti, W, TiN, or ITO are used

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• , titanium nitride (TiN) coating has been licensed by the FDA to be used in titanium alloy components for enhancing durability and corrosion resistance in surgical steel, orthodontics, hip prostheses, and cardiovascular biomaterials [69]. A titania/glass ceramic (TiGC) scaffold was fabricated and coated with

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

Tin dioxide nanomaterial-based photocatalysts for nitrogen oxide oxidation: a review

• Viet Van Pham,
• Hong-Huy Tran,
• Thao Kim Truong and
• Thi Minh Cao

Beilstein J. Nanotechnol. 2022, 13, 96–113, doi:10.3762/bjnano.13.7

• ] (see Equations 1–10). Recently, research on tin dioxide (SnO2) materials has increased significantly, which expresses the potential of SnO2 materials for the scientific community (Figure 2a). SnO2 is one of the most extensively investigated n-type semiconductors. It is known as tin(VI) oxide or stannic

• oxide (not to be confused with stannous oxide with tin in the oxidation state of 2+ [13], also known as cassiterite [14]. SnO2 materials have many interesting properties. For instance, the structure and electronic structure can be manipulated easily due to the highly tunable valence state and oxygen

• is the most common surface, and it is also thermodynamically the most stable [48]. In the rutile phase of SnO2 in Figure 4b, the (110) plane contains all surface bridging oxygens (1), bridging OVs (2), and oxygen coordinated three- or fivefold (3, 4) with surface tin atoms (Sn 5f). The dual valency

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• reported in [56] where zinc (Zn) and tin/copper (Sn/Cu) targets are both co-sputtered in a reactive H2S/Ar reactive plasma for the synthesis of Cu2ZnSnS4 (CZTS) coatings. In the case of reactive sputtering, MFCs manage the flow (usually expressed in standard cubic centimeters per minute, sccm). This is a

• publications, besides Ti+, molecules such as TiN+ or TiO+ and TiO2+ but also reactive gas molecules, atoms, and ions (N2, N2+, N+) were detected in the gas phase. Interestingly, AuO molecules were observed when sputtering Au in an Ar/O2 mixture [65], highlighting the rich gas-phase chemistry of sputtering

Enhancement of the piezoelectric coefficient in PVDF-TrFe/CoFe₂O₄ nanocomposites through DC magnetic poling

• Marco Fortunato,
• Alessio Tamburrano,
• Maria Paola Bracciale,
• Maria Laura Santarelli and
• Maria Sabrina Sarto

Beilstein J. Nanotechnol. 2021, 12, 1262–1270, doi:10.3762/bjnano.12.93

• for 30 min and then spin coated (30 s with a spin speed of 2000 rpm) onto polyethylene terephthalate/indium tin oxide (PET/ITO, Sigma-Aldrich, Rs = 60 Ω/sq). The obtained melt was cured in the oven at 120 °C for 2 h. After curing, the nanostructured thin film was placed over a heated mat reaching 65

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• to some excellent articles on hierarchical gas sensors that address such geometries [8][30][33][37]. Tin oxide-based fractals Yin et al. reported SnO2 nanoparticles with and without platinum (Pt) decoration synthesized using a sol–gel hydrothermal technique for gas sensing applications [63]. Figure

• pits. The self-organization of structures was attributed to tin chloride, which led to a larger size of the pits, while copper oxide led to the formation of hillocks in the film. The D values of the samples were in the range of 2.00–2.24. For the Sn/Cu = 6 ratio, the fractal dimension was 2.0, and the

• . Gracheva and co-workers prepared gas-sensitive fractal structures based on SnO2 and silicon dioxide (SiO2) by a sol–gel technique [57][69][70]. The evolution of fractal aggregates of tin and silicon dioxides resulted in the formation of spherical, labyrinth, and percolation network structures. The

First-principles study of the structural, optoelectronic and thermophysical properties of the π-SnSe for thermoelectric applications

• Muhammad Atif Sattar,
• Najwa Al Bouzieh,
• Maamar Benkraouda and
• Noureddine Amrane

Beilstein J. Nanotechnol. 2021, 12, 1101–1114, doi:10.3762/bjnano.12.82

• Abstract Tin selenide (SnSe) has thermoelectric (TE) and photovoltaic (PV) applications due to its exceptional advantages, such as the remarkable figure of merit (ZT ≈ 2.6 at 923 K) and excellent optoelectronic properties. In addition, SnSe is nontoxic, inexpensive, and relatively abundant. These aspects

• make SnSe of great practical importance for the next generation of thermoelectric devices. Here, we report structural, optoelectronic, thermodynamic, and thermoelectric properties of the recently experimentally identified binary phase of tin monoselenide (π-SnSe) by using the density functional theory

• is exceptionally promising for the next generation of photovoltaic and thermoelectric devices at room and high temperatures. Keywords: density functional theory (DFT); electronic properties; lattice thermal conductivity; optical properties; thermodynamic properties; thermoelectric properties; tin

Assessment of the optical and electrical properties of light-emitting diodes containing carbon-based nanostructures and plasmonic nanoparticles: a review

• Keshav Nagpal,
• Erwan Rauwel,
• Frédérique Ducroquet and
• Protima Rauwel

Beilstein J. Nanotechnol. 2021, 12, 1078–1092, doi:10.3762/bjnano.12.80

• a large scale. For this purpose, transparent conducting oxides (TCO), such as thin films of In2O3, SnO2, ZnO, and their mixtures have been extensively studied [30][31][32][33][34]. The most widely studied TCO is indium tin oxide (ITO), which possesses good physical properties, such as high optical

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• safely in intermetallic anodes, from which Na ions are reversibly released during discharging and charging processes. Among the most common alloying elements in SiBs are tin [74], antimony [75], and to a lesser degree phosphorous [76]. These elements can be either directly sodiated to form Na alloys or

• anode delivered 625 mAh·g−1 [26]. Also, silicon itself is also another promising material for sodium alloy anodes as its theoretical Na storage capacity of 954 mAh·g−1 (NaSi phase) even exceeds the one of tin (847 mAh·g−1) [26]. The low electrochemical reactivity and structural stability of crystalline

9.1% efficient zinc oxide/silicon solar cells on a 50 μm thick Si absorber

• Rafal Pietruszka,
• Bartlomiej S. Witkowski,
• Monika Ozga,
• Katarzyna Gwozdz,
• Ewa Placzek-Popko and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 766–774, doi:10.3762/bjnano.12.60

• inexpensive alternatives for indium tin oxide (ITO) [9]. In this work, we used ALD to deposit zinc oxide nanoseeds, magnesium-doped zinc oxide (MZO) layers and aluminium-doped zinc oxide films. We thus continue our interest on photovoltaic structures based on thin films of ZnO. Recently, there have been

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope

• Frances I. Allen

Beilstein J. Nanotechnol. 2021, 12, 633–664, doi:10.3762/bjnano.12.52

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• flexibility after the ink coating. The maximum transmittance value of as-prepared PET films in the visible region was estimated to be about 92.5% with a sheet resistance value of ca. 20 Ω/sq. This makes the films a potential substitute to commonly used expensive indium tin oxide (ITO) in the field of flexible

• electrodes made of sputtered indium tin oxide (ITO) films [1][2][3]. These films are widely used because of their high transmittance, low sheet resistance, and high electrical conductivity. Yet, they still have some major drawbacks such as high cost, intrinsic brittleness due to the ceramic nature [4], and

Boosting of photocatalytic hydrogen evolution via chlorine doping of polymeric carbon nitride

• Malgorzata Aleksandrzak,
• Michalina Kijaczko,
• Wojciech Kukulka,
• Daria Baranowska,
• Martyna Baca,
• Beata Zielinska and
• Ewa Mijowska

Beilstein J. Nanotechnol. 2021, 12, 473–484, doi:10.3762/bjnano.12.38

• potentiostat in a three-electrode test cell with a platinum wire as the counter electrode and the saturated calomel electrode (SCE) as the reference. The working electrode was a fluorine-doped tin oxide (FTO) glass with the analyzed material drop-casted from a 0.2% ethanol/Nafion solution. A 0.5 M sodium

Solution combustion synthesis of a nanometer-scale Co₃O₄ anode material for Li-ion batteries

• Monika Michalska,
• Huajun Xu,
• Qingmin Shan,
• Shiqiang Zhang,
• Yohan Dall'Agnese,
• Yu Gao,
• Amrita Jain and
• Marcin Krajewski

Beilstein J. Nanotechnol. 2021, 12, 424–431, doi:10.3762/bjnano.12.34

• sites). Crystalline Co3O4 exhibits the space group Fd3m (227) [5]. It also can reversibly store eight lithium ions according to the following conversion reaction: This redox reaction corresponds to a theoretical capacity of about 890 mAh·g−1 [1][2][3][4]. However, similarly to silicon and tin materials

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

• rheological additives [103]. AgNW-coated conductive films have been considered as a promising alternative over conventional indium tin oxide (ITO)-coated conductive films [89]. The synthesis of silver nanostructures, and generally all types of nanostructures, can be categorized as one of two approaches [104

Fusion of purple membranes triggered by immobilization on carbon nanomembranes

• René Riedel,
• Natalie Frese,
• Fang Yang,
• Martin Wortmann,
• Raphael Dalpke,
• Daniel Rhinow,
• Norbert Hampp and
• Armin Gölzhäuser

Beilstein J. Nanotechnol. 2021, 12, 93–101, doi:10.3762/bjnano.12.8

• consisting of the CNM substrate as the upper and an indium tin oxide (ITO) as the lower capacitor plate. A sample drop was placed between the two electrodes. For electrostatic experiments (drop was in contact with substrate plate only) the plate separation distance was held constant at 10 mm, while it was

• Figure 1c–f, an electrical field was applied to the drop. The substrate itself served as a positively charged capacitor plate whereas the negatively charged plate consisted of indium tin oxide. As the electric field is attenuated in areas that have already been covered by PM patches, subsequently

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• used, for example, in water purification, as electrochemical actuators, as transparent conductive electrodes, and as biosensors [21][22][28]. To enhance the performance of MXene supercapacitors, a variety of materials, such as graphene and carbon nanotubes (CNTs), tin(IV) oxide (SnO2), and iron(III

Atomic layer deposited films of Al₂O₃ on fluorine-doped tin oxide electrodes: stability and barrier properties

• Hana Krýsová,
• Michael Neumann-Spallart,
• Hana Tarábková,
• Pavel Janda,
• Ladislav Kavan and
• Josef Krýsa

Beilstein J. Nanotechnol. 2021, 12, 24–34, doi:10.3762/bjnano.12.2

• , Technická 5, 166 28 Prague 6, Czech Republic 10.3762/bjnano.12.2 Abstract Al2O3 layers were deposited onto electrodes by atomic layer deposition. Solubility and electron-transport blocking were tested. Films deposited onto fluorine-doped tin oxide (FTO, F:SnO2/glass) substrates blocked electron transfer to

• alumina coatings was ascribed to its capability of passivating semiconductor/electrolyte interfaces, thus reducing photogenerated charge-carrier recombination (e.g., on BiVO4 [16]). In this work, Al2O3 films were deposited via ALD on thermally grown SiO2 on silicon or on fluorine-doped tin oxide (FTO

• grade. 0.1 M sodium phosphate buffer solution, pH 7.2, was obtained from Fluka. Triply distilled water was used for the preparation of solutions. Fluorine-doped tin oxide-coated 2 mm thick glass (TEC-7, 7 Ω/□, Sigma-Aldrich), was ultrasonically pre-cleaned with isopropanol, treated with acetone, ethanol

Piezotronic effect in AlGaN/AlN/GaN heterojunction nanowires used as a flexible strain sensor

• Jianqi Dong,
• Liang Chen,
• Yuqing Yang and
• Xingfu Wang

Beilstein J. Nanotechnol. 2020, 11, 1847–1853, doi:10.3762/bjnano.11.166

• synthesize AlGaN/AlN/GaN heterojunction NWs with controllable size. A single NW is transferred to a flexible poly(ethylene terephthalate) substrate and fixed by indium tin oxide electrodes to form an ohmic contact for the strain sensor. An external mechanical stress is introduced to study the performance of

• (EC) wet etching, to prepare AlGaN/AlN/GaN heterojunction NWs with a controllable size. After the lift-off, a single NW is transferred to a flexible poly(ethylene terephthalate) (PET) substrate and is fixed by indium tin oxide (ITO) electrodes to form an ohmic contact for the strain sensor. Under

Amorphized length and variability in phase-change memory line cells

• Nafisa Noor,
• Sadid Muneer,
• Raihan Sayeed Khan,
• Anna Gorbenko and
• Helena Silva

Beilstein J. Nanotechnol. 2020, 11, 1644–1654, doi:10.3762/bjnano.11.147

• -switching process and not to the permanent and detrimental electrical breakdown failure that occurs in any dielectric material. Experimental The patterned GST-225 line cells used for this study were deposited on silicon dioxide (SiO2), had bottom metal contact pads (tungsten with Ti/TiN liner), and were

Triboelectric nanogenerator based on Teflon/vitamin B1 powder for self-powered humidity sensing

• Liangyi Zhang,
• Huan Li,
• Yiyuan Xie,
• Jing Guo and
• Zhiyuan Zhu

Beilstein J. Nanotechnol. 2020, 11, 1394–1401, doi:10.3762/bjnano.11.123

• -free humidity sensors by using biocompatible collagen nanofibrils [43]. More recently, Zhang et al. developed a TENG-driven self-powered flexible humidity sensor based on a tin disulfide nanoflower/reduced graphene oxide (SnS2/rGO) hybrid nanomaterial [44]. However, the large-scale application of TENGs