Fabrication of metal complex phthalocyanine and porphyrin nanoparticle aqueous colloids by pulsed laser fragmentation in liquid and their potential application to a photosensitizer for photodynamic therapy

• Taisei Himeda,
• Risako Kunitomi,
• Ryosuke Nabeya,
• Tamotsu Zako and
• Tsuyoshi Asahi

Beilstein J. Nanotechnol. 2025, 16, 1088–1096, doi:10.3762/bjnano.16.80

• suspended in a poor solvent is fragmented into nanoparticles by intense pulsed laser irradiation, and the sample suspension is directly converted in to a colloidal dispersion without any chemical additives in one step. It has been demonstrated that several hydrophobic dyes such as metal complex Pcs (MPcs

• spectrometer, and the sample was irradiated with laser pulses until the absorption spectrum stopped changing. The sample was muddy blue, and most of the AlClPc precipitated to the bottom of the cuvette before laser irradiation. After irradiation with nanosecond laser pulses for 40 min (Figure 2a), the sample

• turned to deep clear blue. A broad absorption with peaks at 620 and 800 nm appeared and increased with laser irradiation time; the absorbance stopped changing after around 30 min irradiation as shown in Figure 2b. The two peaks that appeared at short and long wavelengths relative to the isolated

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

A calix[4]arene-based supramolecular nanoassembly targeting cancer cells and triggering the release of nitric oxide with green light

• Cristina Parisi,
• Loredana Ferreri,
• Tassia J. Martins,
• Francesca Laneri,
• Samantha Sollima,
• Antonina Azzolina,
• Antonella Cusimano,
• Nicola D’Antona,
• Grazia M. L. Consoli and
• Salvatore Sortino

Beilstein J. Nanotechnol. 2025, 16, 1003–1013, doi:10.3762/bjnano.16.75

• methanol/water (1:1) and, for comparison, that of its non-nitrosated derivative 2b. Both compounds exhibit similar molar absorptivity, but the absorption maximum of 2 is by almost 100 nm blue-shifted due to the loss of the push−pull character of the nitroaniline chromophore. Irradiation of 2 with blue

• does not absorb green light (see Figure 3A) and, therefore, is unreactive to this excitation wavelength. However, irradiation of the 1·2 supramolecular complex leads to a photochemical transformation characterized by the increase of the typical absorption of the non-nitrosated derivative 2b (Figure 5A

• amperometric detection of this radical species through an ultrasensitive NO electrode while alternating cycles of light/dark. Figure 5C shows that the NO generation is achieved exclusively upon green light excitation of the nanoassembly and stops once the irradiation source is switched off. The quantum yield

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74

• reactions that span from atomic to macroscopic length scales. Consequently, it is paramount to understand the complex cascades that follow laser irradiation of condensed matter. Of particular importance here is the processing in the presence of liquids surrounding the irradiated material, but also

• , it is important to understand and quantify such processes that may occur concomitantly and will affect each other. First, we develop a basic hypothesis of how laser irradiation with significant energy deposition into the system of interest (for example an aqueous colloid or solid surface in contact

Structural and magnetic properties of microwave-synthesized reduced graphene oxide/VO₂/Fe₂O₃ nanocomposite

• Sumanta Sahoo,
• Ankur Sood and
• Sung Soo Han

Beilstein J. Nanotechnol. 2025, 16, 921–932, doi:10.3762/bjnano.16.70

• gained considerable research attention. In this context, the current work demonstrates a facile rGO-supported solid-state MW synthetic route for fabricating a ternary nanocomposite of VO2, Fe2O3, and rGO. Here, the MW irradiation for 90 s was found to be suitable for the reduction and exfoliation of

• . Keywords: Fe2O3; magnetism; microwave irradiation; reduced graphene oxide; VO2; Introduction Graphene-based materials have been significantly explored in various fields of materials science due to their unique physical and chemical characteristics [1][2][3][4]. The special arrangement of carbon materials

• with graphene by applying MW irradiation for certain time intervals. In this context, Zhang et al. reported the synthesis of Ni-Co sulfide/graphene NC through MW irradiation at a power of 1000 W for 60 s [12]. As a supercapacitor (SC) electrode, the MW-synthesized NC displayed a specific capacitance of

Characterization of ion track-etched conical nanopores in thermal and PECVD SiO₂ using small angle X-ray scattering

• Shankar Dutt,
• Rudradeep Chakraborty,
• Christian Notthoff,
• Pablo Mota-Santiago,
• Christina Trautmann and
• Patrick Kluth

Beilstein J. Nanotechnol. 2025, 16, 899–909, doi:10.3762/bjnano.16.68

• nanopores in different materials, which is essential for optimizing membrane performance in applications that require precise pore geometry. Keywords: etched ion tracks; SiO2; small angle X-ray scattering (SAXS); swift heavy ion irradiation; track-etched nanopores; Introduction Solid-state nanopores have

• and a wider size distribution. Results and Discussions Figure 1 shows plan-view scanning electron microscopy (SEM) images of nanopores fabricated in thermal (Figure 1a) and PECVD (Figure 1b) SiO2 by etching ion tracks produced with 1.6 GeV Au ion irradiation (see Experimental and Theory section for

• typically differ in morphology, density, and stoichiometry compared to thermally grown SiO2. The electronic energy loss (Se) in the thermal and PECVD SiO2 layers was calculated using the SRIM2008 code [49]. The average Se values for thermal SiO2 for 1.6 GeV, 185 MeV, and 89 MeV Au irradiation are 21.1, 16.6

Ar⁺ implantation-induced tailoring of RF-sputtered ZnO films: structural, morphological, and optical properties

• Manu Bura,
• Divya Gupta,
• Arun Kumar and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 872–886, doi:10.3762/bjnano.16.66

• with 30 keV Ar+ ions. The energy used here was a low energy; also, argon is lighter than zinc. Because of this, the irradiation did not cause a significant shift in peak positions with increasing ion fluence, but it is observable. The shift in peak position and the variation in peak intensity of the

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• -ray irradiation. The observed effect was identified as responsible for the enhanced catalytic activity of mixed ceria–zirconia materials in the applications [39]. Photoemission is a technique with a sensitivity limited to the topmost surface layers. In typical resonant photoemission experiments on

Synthesis and magnetic transitions of rare-earth-free Fe–Mn–Ni–Si-based compositionally complex alloys at bulk and nanoscale

• Shabbir Tahir,
• Tatiana Smoliarova,
• Carlos Doñate-Buendía,
• Michael Farle,
• Natalia Shkodich and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 823–836, doi:10.3762/bjnano.16.62

• irradiation of the target material submerged in a liquid environment. This makes PLAL a safe, scalable and environmentally friendly approach [46][47][48]. Research on the synthesis of CoCrFeMnNi Cantor alloy NPs by PLAL demonstrated that this method consistently produces NPs with near-equiatomic compositions

Thickness dependent oxidation in CrCl₃: a scanning X-ray photoemission and Kelvin probe microscopies study

• Shafaq Kazim,
• Rahul Parmar,
• Maryam Azizinia,
• Matteo Amati,
• Muhammad Rauf,
• Andrea Di Cicco,
• Seyed Javid Rezvani,
• Dario Mastrippolito,
• Luca Ottaviano,
• Tomasz Klimczuk,
• Luca Gregoratti and
• Roberto Gunnella

Beilstein J. Nanotechnol. 2025, 16, 749–761, doi:10.3762/bjnano.16.58

• processes and the lower number of defects present per unit volume that can be exploited in the process. These numbers are increased under beam irradiation, when damages occurs as shown by the light blue area in Figure 5. These results are consistent with previous studies on bulk samples cleaved in vacuum

• silicon oxide substrate would help the determination of flakes thickness, we used also a more conductive substrate to measure photoemission under X-ray irradiation, that is, 1 nm thick native oxide Si substrates. Another convenient substrate for SPEM was 190 nm thick indium-doped tin oxide on glass

Efficiency of single-pulse laser fragmentation of organic nutraceutical dispersions in a circular jet flow-through reactor

• Tina Friedenauer,
• Maximilian Spellauge,
• Alexander Sommereyns,
• Verena Labenski,
• Tuba Esatbeyoglu,
• Christoph Rehbock,
• Heinz P. Huber and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2025, 16, 711–727, doi:10.3762/bjnano.16.55

• phthalocyanines (VOPc and CuPc) in deionized water and other pure solvents but also influences the size and crystal phase via the chosen laser parameters [21][33]. Furthermore, spectroscopic analyses successfully demonstrated that an extinction enhancement occurs with increasing irradiation time and higher

• fenofibrate [42] by LFL is possible; however, depending on the applied power and irradiation time, an inversely proportional relationship between particle size and the portion of degradation products was reported. Previous studies using naproxen and fenofibrate as model drugs showed that using nanosecond

• the melting temperature range, which is why the melting temperature roughly corresponds to the degradation temperature [53][54][55][56]. Another potential mechanism would be photochemical degradation. It has been reported that upon irradiation the curcumin molecule dissociates primarily at its central

The impact of tris(pentafluorophenyl)borane hole transport layer doping on interfacial charge extraction and recombination

• Konstantinos Bidinakis and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 678–689, doi:10.3762/bjnano.16.52

• the HTL with BCF, we initially characterized the photovoltaic performance of each of the four solar cell batches with a solar simulator under 1 Sun irradiation (1000 W/m2). The corresponding parameters are reported in Table 1 and they refer to a statistical analysis of backward scans from ten devices

Focused ion and electron beams for synthesis and characterization of nanomaterials

• Aleksandra Szkudlarek

Beilstein J. Nanotechnol. 2025, 16, 613–616, doi:10.3762/bjnano.16.47

• focused electron beam-induced etching (FEBIE), can effectively control edge profiles, supported by continuum modeling [12]. Additionally, using alternative precursors such as Pt(CO)2Cl2 and Pt(CO)2Br2 with low-energy ion irradiation enables the fabrication of high-purity Pt deposits. This process involves

Retrieval of B1 phase from high-pressure B2 phase for CdO nanoparticles by electronic excitations in Cd_xZn_1−xO composite thin films

• Arkaprava Das,
• Marcin Zając and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2025, 16, 551–560, doi:10.3762/bjnano.16.43

• as an effective tool. Exposure to 120 MeV silver ion irradiation results in the complete amorphization of the B2 phase in CdO nanoparticles, while the crystalline hexagonal wurtzite phase of zinc oxide (ZnO) remains intact. In contrast, 80 MeV oxygen ion irradiation preserves the B2 phase and

• facilitates the reemergence of the B1 phase. The partial damage caused by electronic energy loss during oxygen ion irradiation in the willemite Zn2SiO4 phase is identified as a trigger for the B1 to B2 phase transformation in CdO nanoparticles, enabling the recovery of the B1 phase. The diminishing local

• pressure exerted by the Zn2SiO4 phase on CdO nanoparticles during oxygen ion irradiation leads to the coexistence of both B1 and B2 phases. X-ray absorption near-edge spectra (XANES) reveal minimal changes in the intensity of the spike-like Zn L3,2 pre-edge feature associated with the Zn2SiO4 phase under

Electron beam-based direct writing of nanostructures using a palladium β-ketoesterate complex

• Chinmai Sai Jureddy,
• Krzysztof Maćkosz,
• Aleksandra Butrymowicz-Kubiak,
• Iwona B. Szymańska,
• Patrik Hoffmann and
• Ivo Utke

Beilstein J. Nanotechnol. 2025, 16, 530–539, doi:10.3762/bjnano.16.41

• fragments such as CO, CH3CHO, and also CO2. These findings suggest that during FEB irradiation, the adsorbed [Pd(tbaoac)2] molecules may lose four carbon atoms per one (CH3)2CCH2 volatile molecular fragment, while the remaining carbon atoms may be removed as CO or CO2, hydrocarbons CHx, and other volatile

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• ][20][21]. Ahmed et al. [13] investigated the effect of helium ion irradiation on the structural and electrical properties of Mo thin films. They noted that α-particles create defects that reduce charge carrier mobility, and the hardness increased from low to high ion fluence. Hoffman et al. [14

• accelerating voltage. At grazing incidence, the observed stress is either minimal or slightly tensile and is mostly unaffected by the accelerating voltage. Tripathi et al. [18] examined the temperature-dependent surface alterations in Mo films induced by He+ ion irradiation within the 773–1073 K range as a

• prospective substitute for tungsten in plasma-facing components of fusion devices. Klaver et al. [19] investigated the impact of irradiation with low-energy helium ions on the physical properties of molybdenum thin films. Ono et al. [20] studied the degradation of the optical characteristics of single- and

Performance optimization of a microwave-coupled plasma-based ultralow-energy ECR ion source for silicon nanostructuring

• Joy Mukherjee,
• Safiul Alam Mollick,
• Tanmoy Basu and
• Tapobrata Som

Beilstein J. Nanotechnol. 2025, 16, 484–494, doi:10.3762/bjnano.16.37

• power, and extraction grid voltage is documented for different ion energies. Additionally, the manuscript establishes the relationship between ion beam current and ion energy. Irradiation of p-type single crystal Si(100) surfaces at off-normal angles (60° and 72.5°) with 450 eV Ar ions results in the

• formation of well-defined nanoscale ripple patterns. The prominence of ripple structures increases with prolonged irradiation time, while bombardment at 72.5° with the same ion beam parameters leads to the coarsening of nanostructures. Cross-sectional transmission electron microscopy (TEM) measurements

• beam current, and the corresponding ion fluence is expressed in terms of irradiation time. The sample holder located in a UHV chamber is connected to a five-axes (x, y, z, θ, φ) manipulator (PREVAC Technologies) system, offering movement and rotation in all possible directions. The sample is

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• of nanoparticles in large quantities for practical use. In this study, we investigated improvements of the synthesis efficiency of nanoparticles in LRL by adding scavengers, such as isopropyl alcohol (IPA) and glycerin, for oxidative radicals formed by laser irradiation to the solution and converting

• practical use. In this study, we attempted to improve the synthesis efficiency of nanoparticles using LRL by controlling the reaction environment of the solution during laser irradiation. Results and Discussion Increasing the synthesis efficiency of nanoparticles via laser-induced reduction by adding

• radical scavengers In laser-induced reduction, laser irradiation breaks down water molecules to produce various radical species. The standard electrode potentials of solvated electrons (e−aq) and hydrogen radicals (H•) are E0 = −2.77 V and E0 = −2.1 V, respectively [33]. It has been reported that solvated

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• synthesized using a middle-class 6 ps, 1030 nm Yb:KGW laser PHAROS (Light Conversion, Vilnius, Lithuania) and a ScanCube IV galvanometric scanner (Scanlab, Pichheim, Germany) equipped with a 163 mm focal length lens. The irradiation conditions were 50–250 µJ pulse energy range, 10 kHz pulse repetition rate

• , 40 min irradiation time, 2 m·s−1 beam scanning speed, and 4 × 4 mm2 ablated area with a zig-zag scan pattern. To generate donut-shaped laser pulses from the initial Gaussian profile, an S-waveplate convertor (Workshop of Photonics, Vilnius, Lithuania) was used (Figure 1a). A half-waveplate retarder

• materials is intended to clarify the effect of the donut-shaped beam on NP size and to approve whether factors such as phase and composition can be disregarded. For example, the inertness of gold minimizes its oxidation by laser irradiation, whereas the HEA is composed of elements prone to oxidation

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• nanoparticles with their surface attachment and solves longstanding nanoparticle adhesion and electrical contact issues. Irradiation of hydrophilic carbon fiber paper submerged in aqueous HAuCl4 solution by nanosecond laser pulses produced composites with uniform distribution of gold nanoparticles on carbon

• the reported specific surface area of the carbon fiber paper used here [24]. Pulsed laser grafting produced integrated gold nanoparticle–carbon fiber paper composites (Figure 2B), using aqueous 1.0 M HAuCl4 solution, hydrophilic carbon fiber paper, and unfocused Nd:YAG laser irradiation with 10 Hz, 8

• that our laser fluence did not enable carbon sublimation. Stable gold colloids have been produced by reactive nanosecond laser irradiation of aqueous [AuCl4]– solutions [29][30]. Colloidal gold nanoparticle formation occurred by nucleation of reduced (metallic) gold atoms [25][31][32]. As in pulsed

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• effectively and precisely break down and neutralize antibiotic compounds with high efficiency and selectivity by utilizing a complex interaction between radical reactive oxygen species and non-radical equivalents under light irradiation. Although photocatalysts have certain drawbacks, such as a limited

• light exposure. To be specific g-C3N4-based ternary photocatalysts exhibited more than 90% degradation of tetracycline and sulfamethazine antibiotics within one hour of irradiation. This study addresses the antibiotic degradation efficiency during photocatalytic processes and suggests new approaches to

• Fe2O3 promoted the electron–holes segregation rate and reduced the rate of recombination. A TiO2/GO/chitosan photocatalyst was synthesized by Erim et al. [73] for the degradation of CFX under UV-A irradiation. Under optimized conditions (catalyst dose of 0.327 g/L, CFX concentration of 20.29 mg/L, pH

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• phase preference could be a difference in post-irradiation behavior due to the use of a batch process. For example, it has been shown that the laser ablation of copper in ethylene glycol leads to nanoparticle diameters ranging from 2.5 to 4.8 nm [61]. Further research needs to investigate the

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• physicochemical characterization, including the formulations exposed to irradiation under the same conditions. For physicochemical characterization of the formulations, different techniques were used by which successful functionalization of the CNs and TMZ loading were confirmed and visualized; no significant

• changes in the structure of the CNs and TMZ after irradiation were observed. With single and dual functionalization, formulations with relatively high TMZ loading efficiency and drug content were prepared. They exhibited homogeneous particle size distributions and mean particle sizes and surface charges

• surface on a larger scale. For the irradiated CNs, lower values for particle size, more positive values for surface charge, and accelerated TMZ release were observed, which could be explained by changes in the physicochemical characteristics of the prepared formulations upon irradiation. Significant

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• heats the photothermal nanomaterials embedded in these hydrogels, causing them to soften reversibly and release the encapsulated drug. The rate of drug release can be finely tuned by adjusting the concentration of the hydrogel and photothermal nanomaterial, as well as the irradiation conditions [132

• vesicle leakage, bacterial endophthalmitis, and ocular hypotonia. Wang et al. developed a polyvinyl alcohol (PVA) hydrogel with enhanced photothermal, antimicrobial, and drug-delivery capabilities (PVA@rGO-Ag/5-Fu) [71]. Under NIR irradiation, the rGO-Ag component in the hydrogel effectively targets and

• vitro antibacterial experiments, the minimum inhibitory concentrations of AuAgCu2O NS (808 nm, 0.75 W·cm−2, 10 min) and AgCu2O-EDTA (808 nm, 0.25 W·cm−2, 5 min) were similar. However, AgCu2O-EDTA required a lower laser energy density and shorter irradiation times, resulting in a milder photothermal

A review of metal-organic frameworks and polymers in mixed matrix membranes for CO₂ capture

• Charlotte Skjold Qvist Christensen,
• Nicholas Hansen,
• Mahboubeh Motadayen,
• Nina Lock,
• Martin Lahn Henriksen and
• Jonathan Quinson

Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14