Beilstein J. Nanotechnol.2011,2, 734–739, doi:10.3762/bjnano.2.80
, this allows us to tackle the lower size limit of catalyst particles necessary for CNT growth. The smallest CNT diameter realized so far is 0.4 nm, which was found to be stable only in a template environment, either of a double walled CNT [4][5], or the interior of a porous zeolite AlPO4-5 single
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Figure 1:
Time-of-flight mass spectrum of the selected cluster size distribution showing a pure iron cluster ...
Beilstein J. Nanotechnol.2010,1, 60–70, doi:10.3762/bjnano.1.8
, and that the synthesis can be carried out solvothermally. MOFs are commercially available, and the scale up of production is continuing. Since the discovery of MOFs, many other crystalline frameworks have been synthesized using reticular chemistry, such as Metal-Organic Polyhedra (MOP) [5], Zeolite
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Figure 1:
The connector (I–IV) and linker (a–e) units considered in this work. The same nomenclature is used ...