A review of carbon-based and non-carbon-based catalyst supports for the selective catalytic reduction of nitric oxide

• Shahreen Binti Izwan Anthonysamy,
• Syahidah Binti Afandi,
• Mehrnoush Khavarian and
• Abdul Rahman Bin Mohamed

Beilstein J. Nanotechnol. 2018, 9, 740–761, doi:10.3762/bjnano.9.68

• following [49]. In particular, the catalyst active phases before and after SCR-NH3 reaction are typically characterised by: atomic absorption spectroscopy (AAS) X-ray fluorescence spectroscopy (XRF) electron paramagnetic resonance (EPR) X-ray photoelectron spectroscopy (XPS) temperature-programmed reduction

Mechanistic insights into plasmonic photocatalysts in utilizing visible light

• Kah Hon Leong,
• Azrina Abd Aziz,
• Lan Ching Sim,
• Pichiah Saravanan,
• Min Jang and
• Detlef Bahnemann

Beilstein J. Nanotechnol. 2018, 9, 628–648, doi:10.3762/bjnano.9.59

• excitation and electron injection into the semiconductor are still unclear. The verification that plasmon-excited electrons in Au NPs possess sufficient energy to overcome the Schottky junction to be injected into TiO2 was confirmed using high-resolution X-ray absorption spectroscopy (HR-XAS) [105]. The

• adopted experimental setup is depicted in Figure 10. The significant spectral variations observed by X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) suggest that electrons injected from Au NPs upon LSPR excitation could survive longer and become trapped at a Ti site near

• [6], copyright 2013 IOP Publishing. High-resolution X-ray absorption spectroscopy (HR-XAS) experiment used to determine the changes in the Au LIII-edge induced by 100 mW continuous wave laser excitation of the localized surface plasmon at 532 nm. Reprinted with permission from [105], copyright 2013

Synthesis and characterization of electrospun molybdenum dioxide–carbon nanofibers as sulfur matrix additives for rechargeable lithium–sulfur battery applications

• Ruiyuan Zhuang,
• Shanshan Yao,
• Maoxiang Jing,
• Xiangqian Shen,
• Jun Xiang,
• Tianbao Li,
• Kesong Xiao and
• Shibiao Qin

Beilstein J. Nanotechnol. 2018, 9, 262–270, doi:10.3762/bjnano.9.28

• further evaluate the interaction between MoO2–CNFs and polysulfides, the as-prepared MoO2–CNFs were added into Li2S6 solution. In the optical photo of Figure 3c, the original yellow-brown solution turned lighter, indicating a strong adsorption. Meanwhile, UV-visible absorption spectroscopy was used to

Response under low-energy electron irradiation of a thin film of a potential copper precursor for focused electron beam induced deposition (FEBID)

• Leo Sala,
• Iwona B. Szymańska,
• Céline Dablemont,
• Anne Lafosse and
• Lionel Amiaud

Beilstein J. Nanotechnol. 2018, 9, 57–65, doi:10.3762/bjnano.9.8

• finally estimated. Results and Discussion Stability of the EtNH2 ligands Figure 2 shows the vibrational spectra of the two products recorded by different instruments: at ambient pressure by attenuated total reflection (ATR) infrared absorption spectroscopy (both in Poland and in France) and under vacuum

Inelastic electron tunneling spectroscopy of difurylethene-based photochromic single-molecule junctions

• Youngsang Kim,
• Safa G. Bahoosh,
• Dmytro Sysoiev,
• Thomas Huhn,
• Fabian Pauly and
• Elke Scheer

Beilstein J. Nanotechnol. 2017, 8, 2606–2614, doi:10.3762/bjnano.8.261

• consistently larger gap for the open form as compared to the closed one is in agreement with the conclusions from the absorption spectroscopy in Figure 1b. Considering the shape of the transmission functions in both molecular forms in Figure 2b, it is clear that τ(EF) cannot simply be described by

Optical contrast and refractive index of natural van der Waals heterostructure nanosheets of franckeite

• Patricia Gant,
• Foad Ghasemi,
• David Maeso,
• Carmen Munuera,
• Elena López-Elvira,
• Riccardo Frisenda,
• David Pérez De Lara,
• Gabino Rubio-Bollinger,
• Mar Garcia-Hernandez and
• Andres Castellanos-Gomez

Beilstein J. Nanotechnol. 2017, 8, 2357–2362, doi:10.3762/bjnano.8.235

• /spectroscopy, transmission electron microscopy, X-ray diffraction, X-ray photoemission, UV–vis–IR absorption spectroscopy and Raman spectroscopy. More details about this characterization can be found in [15]. The flakes are firstly exfoliated onto a polydimethylsiloxane (Gelfilm, with 150 µm of thickness, by

Hydrothermal synthesis of ZnO quantum dot/KNb₃O₈ nanosheet photocatalysts for reducing carbon dioxide to methanol

• Xiao Shao,
• Weiyue Xin and
• Xiaohong Yin

Beilstein J. Nanotechnol. 2017, 8, 2264–2270, doi:10.3762/bjnano.8.226

• . The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UV–vis absorption spectroscopy (UV–vis). The photocatalytic activity of the

Bi-layer sandwich film for antibacterial catheters

• Gerhard Franz,
• Florian Schamberger,
• Hamideh Heidari Zare,
• Sara Felicitas Bröskamp and
• Dieter Jocham

Beilstein J. Nanotechnol. 2017, 8, 1982–2001, doi:10.3762/bjnano.8.199

• traces are inductively coupled plasma optical emission spectroscopy (ICP-OES), cyclic voltammetry, and atomic absorption spectroscopy (AAS). The former two methods have been extensively used and are described in [19][40][41]. The biological methods are the determination of the zone of inhibition around a

• spot of the subjected material, and the measurement of the optical density as a function of the time, i.e., absorption spectroscopy at a fixed wavelength (mostly used OD600). After having exposed a colony of bacteria with a certain starting density against solutions of Ag+ of known concentration or

Charge transfer from and to manganese phthalocyanine: bulk materials and interfaces

• Florian Rückerl,
• Daniel Waas,
• Bernd Büchner,
• Martin Knupfer,
• Dietrich R. T. Zahn,
• Francisc Haidu,
• Torsten Hahn and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 1601–1615, doi:10.3762/bjnano.8.160

• photoemission spectroscopy (IPES), electron energy-loss spectroscopy (EELS), spectroscopic ellipsometry and X-ray absorption spectroscopy (XAS). Here, we only briefly mention the kind of information that is provided by these methods, and we refer the reader to comprehensive literature for detailed information

• revealed by polarization dependent X-ray absorption spectroscopy (XAS) studies [127]. In Figure 12 we present corresponding N 1s absorption spectra for pure MnPc and two different film thicknesses of an F16CoPc overlayer, deposited on a gold single crystal. Different light polarizations with respect to the

• represents the changes of the work function. Panel (b) focusses on the energy region close to the Fermi level. N 1s excitation spectra as obtained using X-ray absorption spectroscopy (adapted from [127]). Corresponding data for (c) a 2.0 nm thick MnPc film on Au(100), (b) an additional 0.6 nm thick F16CoPc

ZnO nanoparticles sensitized by CuInZn_xS_2+x quantum dots as highly efficient solar light driven photocatalysts

• Florian Donat,
• Serge Corbel,
• Halima Alem,
• Steve Pontvianne,
• Lavinia Balan,
• Ghouti Medjahdi and
• Raphaël Schneider

Beilstein J. Nanotechnol. 2017, 8, 1080–1093, doi:10.3762/bjnano.8.110

• nanoparticles by a thermal treatment at 400 °C for 15 min. The ZnO/ZCIS composite was characterized by TEM, SEM, XRD, XPS and UV–vis absorption spectroscopy. ZCIS QDs, with an average diameter of ≈4.5 nm, were found to be homogeneously distributed at the surface of ZnO nanoparticles. ZCIS-sensitized ZnO

Triptycene-terminated thiolate and selenolate monolayers on Au(111)

• Jinxuan Liu,
• Martin Kind,
• Björn Schüpbach,
• Daniel Käfer,
• Stefanie Winkler,
• Wenhua Zhang,
• Andreas Terfort and
• Christof Wöll

Beilstein J. Nanotechnol. 2017, 8, 892–905, doi:10.3762/bjnano.8.91

• comprehensively studied using ultra-high vacuum infrared reflection absorption spectroscopy, X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy and thermal desorption spectroscopy. Due to packing effects, the molecules in all monolayers are substantially tilted. In the

• out of ethanolic solution onto Au(111) surfaces. The resulting films were investigated using a complementary set of spectroscopic methods, namely ultra-high vacuum (UHV) infrared reflection–absorption spectroscopy (IRRAS), X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine

Relationships between chemical structure, mechanical properties and materials processing in nanopatterned organosilicate fins

• Gheorghe Stan,
• Richard S. Gates,
• Qichi Hu,
• Kevin Kjoller,
• Craig Prater,
• Kanwal Jit Singh,
• Ebony Mays and
• Sean W. King

Beilstein J. Nanotechnol. 2017, 8, 863–871, doi:10.3762/bjnano.8.88

• ][23]. However, the Abbe diffraction constraints prohibit direct spatial resolution of light-based spectroscopy techniques, such as infrared (IR) absorption spectroscopy, in the nanometer range [24]. Fortunately, these limitations have been recently overcome via combining optical spectroscopy with

Uptake of the proteins HTRA1 and HTRA2 by cells mediated by calcium phosphate nanoparticles

• Olga Rotan,
• Katharina N. Severin,
• Simon Pöpsel,
• Alexander Peetsch,
• Melisa Merdanovic,
• Michael Ehrmann and
• Matthias Epple

Beilstein J. Nanotechnol. 2017, 8, 381–393, doi:10.3762/bjnano.8.40

• determined by atomic absorption spectroscopy (AAS) with an M-Series AA spectrometer (Thermo Electron Corporation, Schwerte). The amount of fluorescently labelled protein on the nanoparticles was determined by quantitative UV spectroscopy, using previously measured calibration curves at λ = 496 nm for BSA

Selective photodissociation of tailored molecular tags as a tool for quantum optics

• Ugur Sezer,
• Philipp Geyer,
• Moritz Kriegleder,
• Maxime Debiossac,
• Armin Shayeghi,
• Markus Arndt,
• Lukas Felix and
• Marcel Mayor

Beilstein J. Nanotechnol. 2017, 8, 325–333, doi:10.3762/bjnano.8.35

• . We therefore analysed its photoresponse using UV absorption spectroscopy. Figure 3 displays the decay of the UV absorption of the trimer 1 in CH2Cl2 upon illumination by UV light at 254 nm and 365 nm respectively. The UV cuvette was exposed to a UV-lamp (8 W, 230 V, 50 Hz) at a constant distance of

Ferromagnetic behaviour of ZnO: the role of grain boundaries

• Boris B. Straumal,
• Svetlana G. Protasova,
• Andrei A. Mazilkin,
• Eberhard Goering,
• Gisela Schütz,
• Petr B. Straumal and
• Brigitte Baretzky

Beilstein J. Nanotechnol. 2016, 7, 1936–1947, doi:10.3762/bjnano.7.185

• transmission electron microscopy) were dense (i.e., pore free) and contained equiaxial grains with sizes of about 20 nm (Figure 2). The films were transparent and slightly greenish. The composition of the films was controlled by atomic absorption spectroscopy in a Perkin-Elmer spectrometer and by electron

Monolayer graphene/SiC Schottky barrier diodes with improved barrier height uniformity as a sensing platform for the detection of heavy metals

• Ivan Shtepliuk,
• Jens Eriksson,
• Volodymyr Khranovskyy,
• Tihomir Iakimov,
• Anita Lloyd Spetz and
• Rositsa Yakimova

Beilstein J. Nanotechnol. 2016, 7, 1800–1814, doi:10.3762/bjnano.7.173

• properties. It is also important to note that the most popular approaches to detect heavy metals are mainly based on complicated chromatography principles [3], photometric methods [4], atomic absorption spectroscopy [5], mass spectrometry [6] and total reflection X-Ray fluorimetry [7]. These techniques

Hydrophilic silver nanoparticles with tunable optical properties: application for the detection of heavy metals in water

• Paolo Prosposito,
• Federico Mochi,
• Erica Ciotta,
• Mauro Casalboni,
• Fabio De Matteis,
• Iole Venditti,
• Laura Fontana,
• Giovanna Testa and
• Ilaria Fratoddi

Beilstein J. Nanotechnol. 2016, 7, 1654–1661, doi:10.3762/bjnano.7.157

• of the nanoparticles occurred. Metal ion detection We investigated the optical sensing properties of the AgNP-3MPS material via absorption spectroscopy. Each solution of AgNP-3MPS/ion was prepared in spectroscopic cuvettes that were carefully cleaned to avoid contamination. To a specific amount of

• . SPR absorption spectroscopy of the AgNP-3MPS solution (synthesis b) taken immediately after the synthesis and after 15 days, indicating good long term stability. Absorption spectra of the AgNP-3MPS (synthesis b) solution with 1 ppm ion concentration. a) Absorption spectra of the AgNP-3MPS system

Scanning probe microscopy studies on the adsorption of selected molecular dyes on titania

• Jakub S. Prauzner-Bechcicki,
• Lukasz Zajac,
• Piotr Olszowski,
• Res Jöhr,
• Antoine Hinaut,
• Thilo Glatzel,
• Bartosz Such,
• Ernst Meyer and
• Marek Szymonski

Beilstein J. Nanotechnol. 2016, 7, 1642–1653, doi:10.3762/bjnano.7.156

• (PES) and the near-edge X-ray absorption spectroscopy (NEXAFS) to investigate the ZnPc/TiO2 system. They conclude that molecules in the first layer bind with the molecular plane 30° from the surface and the tilt angle increases to 33° at higher coverage [51]. However, already the authors suggest

An efficient recyclable magnetic material for the selective removal of organic pollutants

• Clément Monteil,
• Nathalie Bar,
• Agnès Bee and
• Didier Villemin

Beilstein J. Nanotechnol. 2016, 7, 1447–1453, doi:10.3762/bjnano.7.136

• atomic absorption spectroscopy in the supernatant. The decreasing of effectiveness is already under study. Conclusion The modulation of positive and negative charges of phosphonated polyethylenimine, through the controlled insertion of phosphonate groups on polyethylenimine, can be considered as an

Photocurrent generation in carbon nanotube/cubic-phase HfO₂ nanoparticle hybrid nanocomposites

• Protima Rauwel,
• Augustinas Galeckas,
• Martin Salumaa,
• Frédérique Ducroquet and
• Erwan Rauwel

Beilstein J. Nanotechnol. 2016, 7, 1075–1085, doi:10.3762/bjnano.7.101

• electronic structure of the C K-edge in the nanocomposites was probed by electron energy loss spectroscopy, highlighting the key role of the MWCNT growth defects in anchoring HfO2 NPs. A combined optical emission and absorption spectroscopy approach illustrated that, in contrast to HfO2 NPs, the metallic

• is manifested as a broad hump starting above 288 eV and extending up to 305 eV, corresponding to the C 1s → σ* transition for disordered carbon–carbon bonds. On a similar note, other noticeable features are usually observed via X-ray absorption spectroscopy (XAS) in the region between π* and σ

Optical absorption signature of a self-assembled dye monolayer on graphene

• Tessnim Sghaier,
• Sylvain Le Liepvre,
• Céline Fiorini,
• Ludovic Douillard and
• Fabrice Charra

Beilstein J. Nanotechnol. 2016, 7, 862–868, doi:10.3762/bjnano.7.78

• strengths of the vibronic structures are preserved. These changes are attributed to non-resonant interactions with the graphene layer and the neighbouring molecules. Keywords: absorption spectroscopy; dye aggregates; graphene; molecular monolayer; optical spectroscopy; perylene-3,4,9,10-tetracarboxylic

• (0.45 molecule per nm2). This target concentration evaluates to about 1.5 × 10−5 mol·L−1 and was adjusted with absorption spectroscopy applying the Beer–Lambert law with a molar absorptivity of ε = 87000 L·mol−1·cm−1 for various alkylated PTCDI [34]. For dip-coating experiments, the samples were

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• were characterized by XPS, Fourier transform infrared absorption spectroscopy (FT-IRRAS), near-edge X-ray absorption fine structure spectroscopy (NEXAFS), and a scanning tunneling microscopy (STM) analysis. As revealed by XPS and NEXAFS analysis, the monolayers derived from the thiol-terminated

Influence of calcium on ceramide-1-phosphate monolayers

• Joana S. L. Oliveira,
• Gerald Brezesinski,
• Alexandra Hill and
• Arne Gericke

Beilstein J. Nanotechnol. 2016, 7, 236–245, doi:10.3762/bjnano.7.22

• techniques as Brewster angle microscopy (BAM), infrared reflection–absorption spectroscopy (IRRAS) and grazing incidence X-ray diffraction (GIXD). The isotherms indicate that C1P monolayers are in a condensed state in the presence of calcium ions, regardless of the pH. At higher pH without calcium ions, the

• measured at 30 °C is clearly shifted to smaller area values, most probably due to a slightly increased solubility of C1P in this subphase. Infrared reflection–absorption spectroscopy (IRRAS) has been used to determine the phase state of the aliphatic chains on the different subphases. For this purpose, the

• constant at the desired value with an accuracy of ±0.1 °C. Infrared reflection–absorption spectroscopy (IRRAS) Infrared reflection–absorption spectra were recorded on a Vertex 70 FTIR spectrometer (Bruker, Ettlingen, Germany). The setup includes a MCT detector cooled with liquid nitrogen and coupled to a

Characterisation of thin films of graphene–surfactant composites produced through a novel semi-automated method

• Nik J. Walch,
• Alexei Nabok,
• Frank Davis and
• Séamus P. J. Higson

Beilstein J. Nanotechnol. 2016, 7, 209–219, doi:10.3762/bjnano.7.19

• LbL deposition of graphene(−)SDS alternated with polyethyleneimine (PEI). The optical study of graphene thin films deposited on different substrates was carried out using UV–vis absorption spectroscopy and spectroscopic ellipsometry. A particular focus was on studying graphene layers deposited on gold

Linear and nonlinear optical properties of hybrid metallic–dielectric plasmonic nanoantennas

• Mario Hentschel,
• Bernd Metzger,
• Bastian Knabe,
• Karsten Buse and
• Harald Giessen

Beilstein J. Nanotechnol. 2016, 7, 111–120, doi:10.3762/bjnano.7.13

• itself is not the source of the signal, but rather an optically active species is responsible and the antenna is “dark”. This observation is in particular true for surface-enhanced Raman scattering (SERS) [45][46][47] and for experiments on surface-enhanced infrared absorption spectroscopy (SEIRA) [48