Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• , including pore size manipulation, post-synthetic modifications, and composite formation. Finally, the extant challenges and anticipated prospects pertaining to the development of MOF-based nanomaterials for CO2 storage are described. Keywords: CO2 storage; metal-organic frameworks; nanomaterials; open

• amount of absorbed CO2 was significantly improved. Notably, the optimal Mg-MOF-74/graphene-based composite yielded a high CO2 adsorption capacity of 8.4 mmol·g−1 at 298 K and 1 bar. Grand canonical Monte Carlo simulation for CO2 storage prediction Grand canonical Monte Carlo (GCMC) simulation is an

A wearable nanoscale heart sound sensor based on P(VDF-TrFE)/ZnO/GR and its application in cardiac disease detection

• Yi Luo,
• Jian Liu,
• Jiachang Zhang,
• Yu Xiao,
• Ying Wu and
• Zhidong Zhao

Beilstein J. Nanotechnol. 2023, 14, 819–833, doi:10.3762/bjnano.14.67

• University, Hangzhou 310018, China School of Cyberspace Security, Hangzhou DIANZI University, Hangzhou 310018, China 10.3762/bjnano.14.67 Abstract This paper describes a method for preparing flexible composite piezoelectric nanofilms of P(VDF-TrFE)/ZnO/graphene using a high-voltage electrospinning method

• . Composition and β-phase content of the piezoelectric composite films were analyzed using X-ray diffraction. The morphology of the composite film fibers was observed through scanning electron microscopy. Finally, the P(VDF-TrFE)/ZnO/graphene composite film was encapsulated in a sandwich-structure heart sound

• system designed in this paper can collect heart sound signals in real time and predict whether the heart sounds are normal or abnormal, providing a new solution for the diagnosis of heart diseases. Keywords: composite piezoelectric nanofilm; electrospinning; heart sound classification algorithm; heart

Silver nanoparticles loaded on lactose/alginate: in situ synthesis, catalytic degradation, and pH-dependent antibacterial activity

• Nguyen Thi Thanh Tu,
• T. Lan-Anh Vo,
• T. Thu-Trang Ho,
• Kim-Phuong T. Dang,
• Van-Dung Le,
• Phan Nhat Minh,
• Chi-Hien Dang,
• Vinh-Thien Tran,
• Van-Su Dang,
• Tran Thi Kim Chi,
• Hieu Vu-Quang,
• Radek Fajgar,
• Thi-Lan-Huong Nguyen,
• Van-Dat Doan and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2023, 14, 781–792, doi:10.3762/bjnano.14.64

• release of silver ions or electrostatic interaction between AgNPs and microbial cells, have been proposed [21][22]. The AgNPs might release silver ions capable of binding to nucleic acids, thereby, exhibiting antibacterial activity [23][24]. Consequently, any silver-containing composite material with

• loaded onto the nanocomposite [37][39], followed by reduction using plant extract [36][38]. In the present work, we have developed an in situ synthesis method for AgNPs using an alginate composite with lactose as reducing sugar. This method involves the use of lactose as a negatively charged compound

• additives. The formation of AgNPs was confirmed by a change in the color of the colloidal solution. To find the optimal reaction conditions, the synthesis of the nanocomposite was carried out while varying the reaction conditions, such as temperature, reaction time, and ratio of Ag+ to blank composite

In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• /bjnano.14.62 Abstract Metallothermic, especially magnesiothermic, solid-state reactions have been widely applied to synthesize various materials. However, further investigations regarding the use of this method for composite syntheses are needed because of the high reactivity of magnesium. Herein, we

• report an in situ magnesiothermic reduction to synthesize a composite of Ge@C as an anode material for lithium-ion batteries. The obtained electrode delivered a specific capacity of 454.2 mAh·g−1 after 200 cycles at a specific current of 1000 mA·g−1. The stable electrochemical performance and good rate

• robustness, for example, a higher resistance to pulverization than Si, the durability of Ge-based anode is not sufficient for practical applications [14]. To overcome this limitation, nanoscale control and composite design are two effective strategies [15][16][17][18][19]. In addition to various Ge

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• improved electrochemical performance [63][67]. In a recent study, Tang et al. [29] used an ultrasonication and reduction process to combine nanostructured Ag nanoparticles with a MOF (ZIF-67) to fabricate nanopinna-based composite electrochemical sensors for acetaminophen detection. The results showed a

Carbon nanotube-cellulose ink for rapid solvent identification

• Tiago Amarante,
• Thiago H. R. Cunha,
• Claudio Laudares,
• Ana P. M. Barboza,
• Ana Carolina dos Santos,
• Cíntia L. Pereira,
• Vinicius Ornelas,
• Bernardo R. A. Neves,
• André S. Ferlauto and
• Rodrigo G. Lacerda

Beilstein J. Nanotechnol. 2023, 14, 535–543, doi:10.3762/bjnano.14.44

• sensing, as electromagnetic shielding, and as thermoelectric material [32][33][34][35][36][37][38]. Also, Qi et al. reported a liquid-water sensor based on carbon nanotube–cellulose composite films, and, more recently, Goodman et al. reported the scalable manufacturing of nanocomposites for liquid sensing

• [39][40]. Besides, graphene films deposited on cellulose paper and a graphene/cellulose composite were also reported as a solvent sensor material [30][33]. However, most of these works rely on cellulose as a paper substrate or as a thick composite film that cannot be readily employed for large-scale

• composite MWCNTs were mixed with DI water (1% w/v) and sonicated in an ultrasonic bath for 2 h. The obtained suspension was centrifuged for 5 min at 2500 rpm, and the supernatant (0.6% w/v) was reserved. MFC was dispersed in DI water (0.5% w/v) using a Silverson homogenizer (10,000 rpm) for 10 min and then

Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• an environmental SEM equipment at different magnifications. (C) Top: Composite image of the silica gel matrix with embedded yeast yolk–shell structures obtained by superimposing the various images of the elements distribution mapping (smaller pictures at the bottom). Schematic representation of the

Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• ][49][50]. In 2021, Zou et al. developed a biodegradable and sustainable bilayer composite for highly efficient solar evaporation based on a photothermally enhanced arginine-doped polydopamine (APDA) and raw wood [47]. In this study, APDA coatings with enhanced photothermal effects were prepared by

• composite in the 250–2500 nm range. The solar spectrum is also shown for comparison. Figure 8 was reprinted from [47], Polymer, vol. 217, by Y. Zou; P. Yang; L. Yang; N. Li; G. Duan; X. Liu; Y. Li, “Boosting solar steam generation by photothermal enhanced polydopamine/wood composites“, article no. 123464

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• studies that used undoped/non-composite Bi-based nanostructured photocatalysts to degrade textile dyes and antibiotics. Even though different Bi-based photocatalysts have demonstrated impressive photocatalytic performance, pristine and bulk Bi-based photocatalysts still have some drawbacks such as limited

• band, effectively separating the photogenerated carriers [162]. According to Chae et al. [163], a heterojunction WO3-BiVO4 composite demonstrated excellent photocatalytic activity with optical properties that were more effective than those of the pure individual components. Li et al. [164] also created

• efficiencies for both ciprofloxacin and ofloxacin were recorded at a highly basic pH [187] using a magnetic Bi2WO6-biochar composite with a pHpzc of 6.75. The best performance was at pH 7. Since both antibiotics and photocatalyst were negatively charged at a basic pH, electrostatic repulsion between them was

Nanotechnology – a robust tool for fighting the challenges of drug resistance in non-small cell lung cancer

• Filip Gorachinov,
• Fatima Mraiche,
• Diala Alhaj Moustafa,
• Ola Hishari,
• Yomna Ismail,
• Jensa Joseph,
• Maja Simonoska Crcarevska,
• Marija Glavas Dodov,
• Nikola Geskovski and
• Katerina Goracinova

Beilstein J. Nanotechnol. 2023, 14, 240–261, doi:10.3762/bjnano.14.23

• , intratumoral dissemination, and infiltration into the tumor parenchyma [123][124][125]. RVPNs decorated with a composite of an anti-EGFR single-domain antibody and iRGD provided long circulation time, improved extravasation and tumor localization, enhanced parenchymal penetration, as well as increased

Cyclodextrins as eminent constituents in nanoarchitectonics for drug delivery systems

• Makoto Komiyama

Beilstein J. Nanotechnol. 2023, 14, 218–232, doi:10.3762/bjnano.14.21

• with appropriate carriers to fulfill several requirements. First, the composite needs be sufficiently stable in the body and successfully reach the target site without being trapped. Second, the composites must be efficiently internalized to the target tissues and cells. Finally, the drugs must be

• complex with β-CyD bound to the silica nanoparticles and seals the pores of nanoparticles in which drugs are encapsulated. Under these conditions, the composite is stable, because azobenzene is accommodated in the cavity of β-CyD, and sterically protects the disulfide linkage from reductive cleavage by

• abundantly expressed. In the positively charged dendrimer the siRNA is stably protected from enzymatic digestion. The composite easily escapes from the endosome through the proton sponge effect of the dendrimer. Furthermore, inclusion complex formation of α-CyD with phospholipids facilitates the release of

Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine

• Zoran M. Marković,
• Milica D. Budimir,
• Martin Danko,
• Dušan D. Milivojević,
• Pavel Kubat,
• Danica Z. Zmejkoski,
• Vladimir B. Pavlović,
• Marija M. Mojsin,
• Milena J. Stevanović and
• Biljana M. Todorović Marković

Beilstein J. Nanotechnol. 2023, 14, 165–174, doi:10.3762/bjnano.14.17

• (QDs) of nanometer scale, the CQD edges influence the electronic structure of the conjugated sp2 domains [35][36]. Figure 2 shows FTIR, UV–vis and PL spectra of CQDs/PU composite samples. It is obvious from Figure 2a that there are some additional peaks in the CQDs/PU FTIR spectrum compared to that of

• and 1015 cm−1 stem from C=C bending vibrations [30]. All other peaks identified in both neat PU and CQDs/PU composite samples originate from PU. Figure 2b shows a UV–vis spectrum of the CQDs/PU composite sample. The first peak at 317 nm is due to the π–π* transition of C=C. A peak at 350 nm is due to

• of CQDs with polymer chains. Figure 2c shows the PL intensity of the CQDs/PU composite sample. The PL intensity depends on the excitation wavelength while the PL intensity of neat CQDs showed wavelength-independent behavior. After encapsulation of the CQDs into a polymer matrix, PL emission spectra

Batch preparation of nanofibers containing nanoparticles by an electrospinning device with multiple air inlets

• Dong Wei,
• Chengwei Ye,
• Adnan Ahmed and
• Lan Xu

Beilstein J. Nanotechnol. 2023, 14, 141–150, doi:10.3762/bjnano.14.15

• nanofibers in batches. It was found that the distribution of ZnO nanoparticles in the composite nanofibers obtained by EMAI was more uniform than that by SSFSE. This was because the air flow through multiple pores enabled the ZnO nanoparticles in the spinning solution to maintain uniform dispersion in the

The influence of structure and local structural defects on the magnetic properties of cobalt nanofilms

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Olesya Severyukhina and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2023, 14, 23–33, doi:10.3762/bjnano.14.3

• properties of the nanomaterial were investigated in this work using a promising nanocomposite formed by alternating layers of cobalt and niobium. The proposed composite has potentially promising functional properties and can be used in magnetic systems with controlled effective energy exchange in Josephson

• complex multistage process. The general scheme of the problem-oriented analysis of a multilayer composite of niobium and cobalt is presented in Figure 1. At the preparation stage of the conceptual model, the expected requirements to the main properties of the predicted material are formulated, a

Photoelectrochemical water oxidation over TiO₂ nanotubes modified with MoS₂ and g-C₃N₄

• Phuong Hoang Nguyen,
• Thi Minh Cao,
• Tho Truong Nguyen,
• Hien Duy Tong and
• Viet Van Pham

Beilstein J. Nanotechnol. 2022, 13, 1541–1550, doi:10.3762/bjnano.13.127

• explain clearly the difference between these composite materials Experimental Materials and chemicals Chemicals and materials for the synthesis and characterization include Ti foil (1 cm × 2 cm), hydrochloric acid (HCl), sodium hydroxide (NaOH), DI water, acetone ((CH3)2CO), ethanol (C2H5OH), ammonium

• the MoS2 phase in the composite from the XRD pattern of MoS2/TNAs. The (002) plane indicates the multilayer structure of MoS2 materials, the (001) plane indicates a monolayer structure of MoS2 [37][46]. Therefore, the disappearing (002) reflection and the remaining (001) reflection show that the

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• electrodes [38]. The results reveal a significant improvement in the electrical conductivity for the TiO2@MWCNTs electrode. The result agrees well with a previous study on TiO2@graphene composite electrodes [37]. Among the electrodes, the EDL capacitance (C2) at the TiO2 electrode surface is the lowest (1.32

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• proposal is consistent with Rhim et al. [42], who stated that the increased thermal stability of the agar/AgNPs composite films is due to metallic silver being more thermally stable. On the other hand, throughout the thermal test, no evidence of decomposition of the AgNO3 precursor salt (decomposition

Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects

• Olga Shikimaka,
• Mihaela Bivol,
• Bogdan A. Sava,
• Marius Dumitru,
• Christu Tardei,
• Beatrice G. Sbarcea,
• Daria Grabco,
• Constantin Pyrtsac,
• Daria Topal,
• Andrian Prisacaru,
• Vitalie Cobzac and
• Viorel Nacu

Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123

• composites The composite samples were obtained from hydroxyapatite prepared by a precipitation method (HAP) or by a sol–gel method (HAG) combined with a bioglass of definite composition. For the preparation of HAP powder we used the method described in a previous work [35] with small modifications, according

• composites with 10% of bioglass exhibit the full decomposition of HA into TCP regardless of the sintering temperature (1200 or 1250 °C) and type of HA used (HAP or HAG). As an example, Figure 2 shows the XRD pattern for the HAG-10BG-1200 composite. All other patterns for composites with 10% BG, not shown

• type of hydroxyapatite (HAP or HAG), glass content (5 or 10%), or sintering temperature (1200 or 1250°C) on the pH value of SBF was observed. The change of the surrounding physiologic environment to alkaline conditions was caused by the dissolution of the composite in SBF, and it is considered to be

Rapid and sensitive detection of box turtles using an electrochemical DNA biosensor based on a gold/graphene nanocomposite

• Abu Hashem,
• M. A. Motalib Hossain,
• Ab Rahman Marlinda,
• Mohammad Al Mamun,
• Khanom Simarani and
• Mohd Rafie Johan

Beilstein J. Nanotechnol. 2022, 13, 1458–1472, doi:10.3762/bjnano.13.120

• composite. The weight and atomic contribution of each of these elements in the nanocomposite were given with their corresponding EDX spectrum. The use of AuNPs–Gr as a DNA immobilisation matrix enhances the active surface area of the modified SPCE, allowing for a stronger DNA hybridisation detection signal

• . UV–vis spectra were used to determine the presence of Gr and AuNPs/Gr in the composite. From the image (Figure 2e), Gr has a peak at 262 nm, which has been shifted to 256 nm (Figure 2e) in the composite, possibly due to interactions between AuNPs and Gr. Additionally, the distinct peak at 516 nm in

• the composite (Figure 2f) indicated the presence of AuNPs. Fourier-transform infrared spectroscopy (FTIR) was used to investigate the vibrational spectrum of the functional groups present in the nanoparticles and their composites. The FTIR spectra of Gr, AuNPs, and DNA/AuNPs/Gr were fused in Figure 2g

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• (λ > 420 nm), photoelectrochemical studies demonstrated that the RhB photodegradation effectiveness and photocurrent density of the BiIO4/Bi2MoO6 hybrid composite is much higher than that of the pure components. Because of the successful construction of the BiIO4/Bi2MoO6 hybrid, the photocatalytic

• semiconductor surface. SPRs can potentially boost quantum yield by broadening the spectral response range of semiconductors. Fe, Au, Co, Ag, Ni, Bi, Al, and other metallic elements are often deposited and doped. For example, a nanostructure composite based on plasmonic Ag metal nanoclusters and monoclinic BiVO4

• observed that a Bi-Bi2WO6 composite successfully degraded RhB and 4-chlorophenol under visible light [87]. They reported that the formed heterojunction yielded a two times higher RhB photodegradation and a three times higher 4-chlorophenol photodegradation than bare Bi2WO6. Using nonmetal doping, doping

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• the tip's high spreading ratio and exceptional sharpness. This technique can be applied to other types of metal nanowire probes, and with further development, composite nanowire probes can be generated by different precursor gases. The tungsten nanowire probes have a diameter of about 5–10 nm and

• aspect ratios. The imaging results showed higher spatial resolution and prominent tips with CNTs with aspect ratios greater than 10 compared to standard AFM probes. Using such CNT probes for scanning complex nanostructures could solve the long-standing problem of mapping complex nanostructures. Composite

• probe Manufacturing nanoprobes that meet the requirements for cutting-edge mechanical properties, dimensions, and morphology is practically challenging. Modern technology has made it possible to produce macroscopic materials with certain functions by combining several components into composite materials

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• catalytic and photocatalytic properties [46] porous TiO2 frameworks formed by the annealing of titanicone films may serve as catalytic supports [47]. Titanicone films can also be pyrolyzed under Ar to yield conducting TiO2/carbon composite films with important electrochemical applications as electrodes for

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• odor molecules with 96% accuracy. Besides regulating the porous structure and functionalities of MOFs, it may also improve the chiral sensing performance by controlling the orientation growth of MOFs to the assembled composite films on the QCM surfaces. Wöll and Fischer et al. reported the construction

• of chiral MOF-based films by layer-by-layer (LBL) liquid-phase epitaxial (LPE) growth of [{Zn2((+)cam)2(dabco)}n] ((+)cam = (1R,3S)-(+)-camphoric acid, dabco = 1,4-diazabicyclo[2.2.2]octane) [104]. Through using SAMs with carboxylate and pyridyl groups, composite films (SURMOFs) with the enantiopure

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• biocompatibility and plasticity. Nanoarchitectonics for MEGs can be constructed using organic or inorganic materials alone, or organic–inorganic composite nanomaterials [29][30][31]. The energy-harvesting component can gather significant amounts of energy for daily use by employing suitable nanomaterials and an

• . Lv; S.-X. Li; B. Han; Q. Guo; Q. Shi; Y.-S. Wang; H.-B. Sun, “Actuator and generator based on moisture-responsive PEDOT: PSS/PVDF composite film“, pages 1415-1421, Copyright Elsevier (2018). This content is not subject to CC BY 4.0. (o) Schematic diagram of a light-coordinated MEG and (p) output